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Volumn 56, Issue 25, 2000, Pages 4219-4229

Reactions of carbon electrophiles with cobalt-coordinated enynes: Scope and limitations

Author keywords

Carbenium ions; Cobalt and compounds; Enynes; Kinetics; Linear free energy relations

Indexed keywords

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; ENERGY; PRIORITY JOURNAL; STRUCTURE ANALYSIS;

EID: 0034674742     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(00)00347-1     Document Type: Article
Times cited : (30)

References (42)
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    • For a definition of the reactivity parameters E and N (and s), see: (a)
    • For a definition of the reactivity parameters E and N (and s), see: (a) Mayr, H.; Patz, M.; Gotta, M. F.; Ofial, A. R. Pure Appl. Chem. 1998, 70, 1993-2000.
    • (1998) Pure Appl. Chem. , vol.70 , pp. 1993-2000
    • Mayr, H.1    Patz, M.2    Gotta, M.F.3    Ofial, A.R.4
  • 8
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    • (c)
    • (c) Mayr, H.; Patz, M. Angew. Chem. 1994, 106, 990-1010; Angew. Chem., Int. Ed. Engl. 1994, 33, 938-957.
    • (1994) Angew. Chem. , vol.106 , pp. 990-1010
    • Mayr, H.1    Patz, M.2
  • 9
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    • (c) Mayr, H.; Patz, M. Angew. Chem. 1994, 106, 990-1010; Angew. Chem., Int. Ed. Engl. 1994, 33, 938-957.
    • (1994) Angew. Chem., Int. Ed. Engl. , vol.33 , pp. 938-957
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    • Jaffer, H. J.; Pauson, P. L. J. Chem. Res. (S) 1983, 244; J. Chem. Res. (M) 1983, 2201-2218.
    • (1983) J. Chem. Res. (M) , pp. 2201-2218
  • 18
    • 85037953911 scopus 로고    scopus 로고
    • This observation is in accord with Ref. 1, reporting that acylation products of cobalt enyne complexes cannot be trapped with C-nucleophiles when tertiary propargyl cation complexes are involved
    • This observation is in accord with Ref. 1, reporting that acylation products of cobalt enyne complexes cannot be trapped with C-nucleophiles when tertiary propargyl cation complexes are involved.
  • 28
    • 0001139567 scopus 로고
    • Roth, M.; Mayr, H. Angew. Chem. 1995, 107, 2428-2430; Angew., Chem. Int. Ed. Engl. 1995, 34, 2250-2252.
    • (1995) Angew. Chem. , vol.107 , pp. 2428-2430
    • Roth, M.1    Mayr, H.2
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    • Roth, M.; Mayr, H. Angew. Chem. 1995, 107, 2428-2430; Angew., Chem. Int. Ed. Engl. 1995, 34, 2250-2252.
    • (1995) Angew., Chem. Int. Ed. Engl. , vol.34 , pp. 2250-2252
  • 33
    • 85037954504 scopus 로고
    • 4c under mild conditions an electrophilicity parameter of E>3 can be estimated for these cations
    • 4c under mild conditions an electrophilicity parameter of E>3 can be estimated for these cations: Wertyporoch, E. Ber. Dt. Chem. Ges. 1933, 66, 1232-1238.
    • (1933) Ber. Dt. Chem. Ges. , vol.66 , pp. 1232-1238
    • Wertyporoch, E.1
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    • Bychkova, N. A.; Zotchik, N. V.; Rubtsov, I. A. J. Gen. Chem. USSR (Engl. Transl.) 1984, 54, 1400-1404; Zh. Obshch. Khim. 1984, 54, 1574-1578.
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  • 42
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    • Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Center as supplementary publication no. CCDC-142331 for 2d and no. CCDC-142332 for 6e. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (Fax: +44-1223/336-033; e-mail: deposit@ccdc.cam.ac.uk)
    • Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Center as supplementary publication no. CCDC-142331 for 2d and no. CCDC-142332 for 6e. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (Fax: +44-1223/336-033; e-mail: deposit@ccdc.cam.ac.uk).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.