Porphyrin-Fe(III)-hydroperoxide and porphyrin-Fe(III)-peroxide anion as catalytic intermediates in cytochrome P450-catalyzed hydroxylation reactions: A molecular orbital study

Biophysical Chemistry

Volumn 88, Issue 1-3, 2000, Pages 11-34

  Zakharieva, Olga ^a   Trautwein, Alfred X ^a   Veeger, Cees ^b  

^a UNIVERSITY OF LÜBECK   (Germany)

^b WAGENINGEN UNIVERSITY   (Netherlands)

Author keywords

Cytochrome P450; Ferryl oxo cation radical; Hydroxylation; Molecular orbital calculations; Porphyrin Fe(III) (hydro)peroxide anion

Indexed keywords

ANILINE; CYSTEINE DERIVATIVE; CYTOCHROME P450; FERRIC ION; FLUOROBENZENE; HISTIDINE DERIVATIVE; HYDROPEROXIDE; PEROXIDE; PORPHYRIN;

CALCULATION; CATALYSIS; CHEMICAL BOND; CHEMICAL REACTION; ELECTRON; HYDROXYLATION; PRIORITY JOURNAL; REVIEW;

EID: 0034672754     PISSN: 03014622     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0301-4622(00)00194-0     Document Type: Article

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