Spontaneous symmetry breaking in the formation of a dinuclear gadolinium semiquinonato complex: Synthesis, high-field EPR studies, and magnetic properties

Chemistry - A European Journal

Volumn 6, Issue 24, 2000, Pages 4580-4586

  Dei, Andrea ^a   Gatteschi, Dante ^a   Massa, Carlo A ^b   Pardi, Luca A ^b   Poussereau, Sandrine ^a   Sorace, Lorenzo ^a  

^a UNIVERSITY OF FLORENCE   (Italy)

^b Ist Fis Atomica e Molec CNR   (Italy)

Author keywords

EPR spectroscopy; Gadolinium; Lanthanides; Magnetic properties; N ligands; Semiquinones

Indexed keywords

GADOLINIUM; QUINONE DERIVATIVE;

ARTICLE; COMPLEX FORMATION; CRYSTAL STRUCTURE; ELECTRON SPIN RESONANCE; MAGNETISM; REACTION ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

EID: 0034671181     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3765(20001215)6:24<4580::AID-CHEM4580>3.0.CO;2-B     Document Type: Article

References (36)

1. A. Dei, D. Gatteschi, Inorg. Chim. Acta 1992, 198-200, 813.
2. C. J. O'Connor, Research Frontiers in Magnetochemistry (Ed: C. J. O'Connor), World Scientific, Singapore, 1993.
3. O. Kahn, Molecular Magnetism, VCH, New York, 1993.
4. Magnetic Molecular Materials (Eds: D. Gatteschi, O. Kahn, J. S. Miller, F. Palacio), Kluwer Academic, Dordrecht, 1991.
5. O. Kahn, Y. Pei, Y. Journaux in Inorganic Materials (Eds: D. W. Bruce, D. O'Hare), Wiley, New York, 1996.
6. R. Sessoli, H. L. Tsai, A. R. Schake, S. Y. Wang, J. B. Vincent, K. Folting, D. Gatteschi, G. Christou, D. N. Hendrickson, J. Am. Chem. Soc. 1993, 115, 1804.
7. D. P. Goldberg, A. Caneschi, S. J. Lippard, J. Am. Chem. Soc. 1993, 115, 9299.
8. J. S. Miller, A. J. Epstein, Angew. Chem. 1994, 106, 399; Angew. Chem. Int. Ed. Engl. 1994, 33, 385.
9. J. S. Miller, A. J. Epstein, Angew. Chem. 1994, 106, 399; Angew. Chem. Int. Ed. Engl. 1994, 33, 385.
10. H. O. Stumpf, L. Ouahab, Y. Pei, P. Bergerat, O. Kahn, J. Am. Chem. Soc. 1994, 116, 3866.
11. J. K. McCusker, C. A. Christmas, P. M. Hagen, R. K. Chadha, D. F. Harvey, D. N. Hendrickson, J. Am. Chem. Soc. 1991, 113, 6114.
12. E. Libby, J. K. McCusker, E. A. Schmitt, K. Folting, D. N. Hendrickson, G. Christou, Inorg. Chem. 1991, 30, 3486.
13. C. A. Christmas, H. L. Tsai, L. Pardi, J. M. Kesselman, P. K. Gantzel, R. K. Chadha, D. Gatteschi, D. F. Harvey, D. N. Hendrickson, J. Am. Chem. Soc. 1993, 115, 12483.
14. C. Lescop, D. Luneau, E. Beloritzky, P. Fries, M. Guillot, P. Rey, Inorg. Chem. 1999, 38, 5472.
15. J. K. McCusker, H. G. Jang, S. Wang, G. Christou, D. N. Hendrickson, Inorg. Chem. 1992, 31, 1874.
16. a) C. G. Pierpont, C. W. Lange, Prog. Inorg. Chem. 1994, 41, 331;
17. b) C. G. Pierpont, R. M. Buchanan, Coord. Chem. Rev. 1981, 38, 45.
18. A. Dei, D. Gatteschi, L. Pardi, A. L. Barra, L. C. Brunel, Chem. Phys. Lett. 1990, 175, 589.
19. A. Caneschi, A. Dei, D. Gatteschi, L. Sorace, K. Vostrikova, Angew. Chem. 2000, 112, 252; Angew. Chem. Int. Ed. Engl. 2000, 39, 246.
20. A. Caneschi, A. Dei, D. Gatteschi, L. Sorace, K. Vostrikova, Angew. Chem. 2000, 112, 252; Angew. Chem. Int. Ed. Engl. 2000, 39, 246.
21. C. Benelli, A. Dei, D. Gatteschi, L. Pardi, Inorg. Chem. 1989, 28, 3089.
22. S. Liu, L. Gelmini, S. J. Rettig, R. C. Thompson, C. Orvig, J. Am. Chem. Soc. 1992, 114, 6081.
23. A. Panagiotopoulos, T. F. Zafiropoulos, S. P. Perlepes, E. Bakalbassis, I. Masson-Ramade, O. Kahn, A. Terzis, C. P. Raptopoulou, Inorg. Chem. 1995, 34, 4918.
24. I. A. Setyawati, S. Liu, S. J. Rettig, C. Orvig, Inorg. Chem. 2000, 39, 496.
25. A. L. Barra, D. Gatteschi, R. Sessoli, Chem. Eur. J. 2000, 6, 1608.
26. A. L. Barra, L.-C. Brunel, D. Gatteschi, L. Pardi, R. Sessoli, Acc. Chem. Res. 1998, 31, (8), 460.
27. A. L. Barra, A. Caneschi, D. Gatteschi, R. Sessoli, J. Am. Chem. Soc. 1995, 117, 8855.
28. C. J. H. Jacobsen, E. Pedersen, J. Villadsen, H. Weihe, Inorg. Chem. 1993, 1216.
29. J. H. Van Vleck, The Theory of Magnetic and Electric Susceptibilities, Oxford University Press, London, 1932.
30. C. J. O'Connor, Prog. Inorg. Chem. 1982, 29, 203.
31. a) C. Benelli, A. Caneschi, D. Gatteschi, L. Pardi, P. Rey, Inorg. Chem. 1990, 29, 4223;
32. b) C. Benelli, D. Gatteschi, R. Sessoli, A. Rettori, M. G. Pini, F. Bartolomé, J. Bartolomé, J. Magn. Magn. Mat. 1995, 140-144, 1649.
33. M. Andruh, I. Ramade, E. Codjovi, O. Guillou, O. Kahn, J. C. Trombe, J. Am. Chem. Soc. 1993, 115, 1822.
34. C. Benelli, A. Caneschi, O. Guillou, L. Pardi, D. Gatteschi, Inorg. Chem. 1990, 29, 1750.
35. A. Altomare, G. Cascarano, C. Giacovazzo, A. Guagliardi, M. C. Burla, G. Polidori, M. Camalli, J. Appl. Chem. 1994, 27, 435.
36. G. M. Sheldrick, SHELXL-93, Program for Crystal Structure Refinement, University of Göttingen, Göttingen (Germany), 1993.