A mild one-pot deamination of aromatic amines bearing electron- withdrawing groups. Calcium hypophosphite as a dediazonation reagent in nonaqueous media

Tetrahedron Letters

Volumn 41, Issue 29, 2000, Pages 5567-5569

  Mitsuhashi, Hirokazu ^a   Kawakami, Takehiko ^a   Suzuki, Hitomi ^a  

^a KWANSEI GAKUIN UNIVERSITY   (Japan)

Author keywords

Amines; Arenes; Deamination; Diazo compounds; Phosphinous acids and derivatives

Indexed keywords

ACETONITRILE; AROMATIC AMINE; CALCIUM PHOSPHATE; DIAZONIUM COMPOUND; FERROUS SULFATE; METHANOL; NITROGEN DIOXIDE; PHOSPHITE; REAGENT;

ARTICLE; CATALYSIS; CHEMICAL REACTION; DEAMINATION; REACTION ANALYSIS; REDUCTION;

EID: 0034661889     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)00883-2     Document Type: Article

References (4)

1. For a recent review, see: Engel, A. Houben-Weyl Methoden der Organischen Chemie, Vol. E16a/2; Georg Thieme: Stuttgart, 1990; p. 1052.
2. Hypophosphorous acid and its salts are commercially used for electrodeless plating of nickel on metallic parts of electric workpieces.
3. Suzuki, H.; Nonoyama, N. Tetrahedron Lett. 1998, 39, 4533.
4. Holleman, A. F. Recl. Trav. Chim. Pays-Bas 1918, 37, 198.