Synthesis and reactivity of the TlI salts of [TCNE].- and [TCNE] 2-: The structural determination of TlI[TCNE] and [TDAE][TCNE]2 and evidence for a chelated [TCNE].-

Chemistry - A European Journal

Volumn 6, Issue 10, 2000, Pages 1805-1810

  Johnson, Mitchell T ^a   Campana, Charles F ^b   Foxman, Bruce M ^c   Desmarais, William ^c   Vela, Michael J ^c   Miller, Joel S ^a  

^a UNIVERSITY OF UTAH   (United States)

^b BRUKER AXS INC   (United States)

^c BRANDEIS UNIVERSITY   (United States)

Author keywords

Crystal structure; Electron transfer; Magnetic ordering; Thallium

Indexed keywords

THALLIUM;

ARTICLE; CRYSTAL STRUCTURE; ELECTRON TRANSPORT; MOLECULAR INTERACTION; REACTION ANALYSIS; SYNTHESIS;

EID: 0034659832     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3765(20000515)6:10<1805::aid-chem1805>3.0.co;2-l     Document Type: Article

References (41)

1. T. L. Cairns, R. A. Carboni, D. D. Coffman, V. A. Englehardt, R. E. Herkert, E. L. Little, E. G. McGeer, B. C. McKusick, W. J. Middleton, J. Am. Chem. Soc. 1957, 79, 2340.
2. A. J. Fatiadi, Synthesis 1986, 249; A. J. Fatiadi, Synthesis 1987, 959.
3. A. J. Fatiadi, Synthesis 1986, 249; A. J. Fatiadi, Synthesis 1987, 959.
4. a) V. Fares, A. Flamini, N. Poli, J. Am. Chem. Soc. 1995, 117, 11 580;
5. b) M. Decoster, F. Conan, M. Kubicki, Y. Le Mest, P. Richard, L. Toupet, J. Chem. Soc. Perkin Trans. 2 1997, 265;
6. c) J. Zhang, L. M. Liable-Sands, A. L. Rheingold, R. E. Del Sesto, D. C. Gordon, B. M. Burkhart, J. S. Miller, J. Chem. Soc. Chem. Commun. 1998, 1385;
7. d) V. M. Anisimov, A. B. Solotoi, M. Y. Antipin, P. M. Lukin, O. E. Nasakin, Y. T. Struchkov, Mendeleev Commun. 1992, 24.
8. A. Zheludev, A. Grand, E. Ressouche, J. Schweizer, B. Morin, A. J. Epstein, D. A. Dixon, J. S. Miller, J. Am. Chem. Soc. 1994, 116, 7243.
9. O. W. Webster, W. Mahler, R. E. Benson, J. Am. Chem. Soc. 1962, 84, 3678.
10. J. S. Miller, J. C. Calabrese, A. J. Epstein, R. W. Bigelow, J. H. Zhang, W. M. Reiff, J. Chem. Soc. Chem. Commun. 1986, 1026; J. S. Miller, J. C. Calabrese, H. Rommelmann, S. Chittipeddi, A. J. Epstein, J. H. Zhang, W. M. Reiff, J. Am. Chem. Soc. 1987, 109, 769.
11. J. S. Miller, J. C. Calabrese, A. J. Epstein, R. W. Bigelow, J. H. Zhang, W. M. Reiff, J. Chem. Soc. Chem. Commun. 1986, 1026; J. S. Miller, J. C. Calabrese, H. Rommelmann, S. Chittipeddi, A. J. Epstein, J. H. Zhang, W. M. Reiff, J. Am. Chem. Soc. 1987, 109, 769.
12. J. S. Miller, A. J. Epstein, J. Chem. Soc. Chem. Commun. 1998, 1319; J. S. Miller, A. J. Epstein, Angew. Chem. 1994, 106, 399; Angew. Chem. Int. Ed. Engl. 1994, 33, 385.
13. J. S. Miller, A. J. Epstein, J. Chem. Soc. Chem. Commun. 1998, 1319; J. S. Miller, A. J. Epstein, Angew. Chem. 1994, 106, 399; Angew. Chem. Int. Ed. Engl. 1994, 33, 385.
14. J. S. Miller, A. J. Epstein, J. Chem. Soc. Chem. Commun. 1998, 1319; J. S. Miller, A. J. Epstein, Angew. Chem. 1994, 106, 399; Angew. Chem. Int. Ed. Engl. 1994, 33, 385.
15. A. Böhm, C. Vazquez, R. S. McLean, J. C. Calabrese, S. E. Kalm, J. L. Manson, A. J. Epstein, J. S. Miller, Inorg. Chem. 1996, 35, 3083.
16. W. J. Middleton, R. E. Heckert, E. L. Little, C. G. Krespan, J. Am. Chem. Soc. 1958, 80, 2783.
17. R. P. Hughes, D. C. Lindlar, A. L. Rheinhold, G. P. A. Yap, Inorg. Chem. 1997, 36, 1726.
18. CRC Handbook of Chemistry and Physics (Ed.: D. R. Lide), 71st ed., CRC Press, Boston, Massachusetts, 1990, pp. 8-19.
19. 4]I instead of KI.
20. D. A. Dixon, J. S. Miller, J. Am. Chem. Soc. 1987, 109, 3656.
21. J. Zhang, L. M. Liable-Sands, A. L. Rheingold, R. E. Del Sesto, D. C. Gordon, B. M. Burkhart, J. S. Miller, J. Chem. Soc. Chem. Commun. 1998, 1385.
22. a) J. S. Miller, D. M. O'Hare, A. Chackraborty, A. J. Epstein, J. Am. Chem. Soc. 1989, 111, 7853;
23. b) D. A. Lemervoskii, R. A. Stukan, B. N. Tarasevich, T. L. Slovokhotov, M. Y. Antipin, A. E. Kalinin, Y. T. Struchov, Struct. Khim. 1981, 7, 240;
24. c) H. Bock, K. Ruppert, D. Fenske, H. Goesmann, Z. Anorg. Allg. Chem. 1991, 595, 275;
25. d) J. R. Fox, B. M. Foxman, D. Guarrera, J. S. Miller, J. C. Calabrese, A. H. Reis, Jr., J. Mater. Chem. 1996, 6, 1627;
26. e) S. A. Clemente, A. Marzotto, J. Mat. Chem. 1996, 6, 941.
27. A. F. Wells, Structural Inorganic Chemistry, 5th ed., Clarendo Press, Oxford, UK, 1984, p. 289.
28. Calculated from one-half of the average trans-NC⋯CN dihedral angles using CrystalMaker3.
29. J. S. Miller, J. C. Calabrese, R. S. McLean, A. J. Epstein, Adv. Mater. 1992, 4, 498.
30. H. Bock, K. Ruppert, K. Merzweiler, D. Fenske, H. Goesmann, Angew. Chem. 1989, 101, 1715; Angew. Chem. Int. Ed. Engl. 1989, 28, 1684; G. T. Yee, J. C. Calabrese, C. Vazquez, J. S. Miller, Inorg. Chem. 1993, 32, 377.
31. H. Bock, K. Ruppert, K. Merzweiler, D. Fenske, H. Goesmann, Angew. Chem. 1989, 101, 1715; Angew. Chem. Int. Ed. Engl. 1989, 28, 1684; G. T. Yee, J. C. Calabrese, C. Vazquez, J. S. Miller, Inorg. Chem. 1993, 32, 377.
32. H. Bock, K. Ruppert, K. Merzweiler, D. Fenske, H. Goesmann, Angew. Chem. 1989, 101, 1715; Angew. Chem. Int. Ed. Engl. 1989, 28, 1684; G. T. Yee, J. C. Calabrese, C. Vazquez, J. S. Miller, Inorg. Chem. 1993, 32, 377.
33. L. R. Milgrom, Tetrahedron 1983, 39, 3895; A. D. Alder, L. Sklar, F. R. Longo, J. D. Finarelli, M. D. Finarelli, J. Heterocycl. Chem. 1968, 5, 669; A. D. Alder, F. R. Longo, F. Kampus, J. Kim, J. Inorg. Nucl. Chem. 1979, 32, 2443.
34. L. R. Milgrom, Tetrahedron 1983, 39, 3895; A. D. Alder, L. Sklar, F. R. Longo, J. D. Finarelli, M. D. Finarelli, J. Heterocycl. Chem. 1968, 5, 669; A. D. Alder, F. R. Longo, F. Kampus, J. Kim, J. Inorg. Nucl. Chem. 1979, 32, 2443.
35. L. R. Milgrom, Tetrahedron 1983, 39, 3895; A. D. Alder, L. Sklar, F. R. Longo, J. D. Finarelli, M. D. Finarelli, J. Heterocycl. Chem. 1968, 5, 669; A. D. Alder, F. R. Longo, F. Kampus, J. Kim, J. Inorg. Nucl. Chem. 1979, 32, 2443.
36. a) TWINDX, TWROT, TWUTIL, TWHKL; Rotational Twinning Software Package (Version 1.2), R. A. Sparks, Bruker AXS, Inc., 6300 Enterprise Lane, Madison, Wisconsin 53719, 1998;
37. b) SAINT, Area Detector Integration Program (Version 5.02), J. Chambers, M. Pressprich, Bruker AXS, Inc., 6300 Enterprise Lane, Madison, Wisconsin 53719, 1998;
38. c) SHELXTL Programs for Crystal Structure Analysis (Version 5.1), G. M. Sheldrick, Bruker AXS, Inc., 6300 Enterprise Lane, Madison, Wisconsin 53719, 1998;
39. d) SIR92, A program for crvstal structure solution, A. Altomare, G. Cascarano, C. Giacovazzo, A. Guagliardi, J. Appl. Crystallogr. 1993, 26, 343;
40. e) D. J. Watkin, C. K. Prout, J. R. Carruthers, P. W. Betteridge, CRYSTALS Issue 10, Chemical Crystallography Laboratory, University of Oxford, Oxford, 1996; D. J. Watkin, C. K. Prout, L. J. Pearce, CAMERON, Chemical Crystallography Laboratory, University of Oxford, Oxford, 1996.
41. e) D. J. Watkin, C. K. Prout, J. R. Carruthers, P. W. Betteridge, CRYSTALS Issue 10, Chemical Crystallography Laboratory, University of Oxford, Oxford, 1996; D. J. Watkin, C. K. Prout, L. J. Pearce, CAMERON, Chemical Crystallography Laboratory, University of Oxford, Oxford, 1996.