Poly(polyoxometalate) dendrimers: Molecular prototypes of new catalytic materials

Angewandte Chemie - International Edition

Volumn 39, Issue 10, 2000, Pages 1771-1774

  Zeng, Huadong ^a   Newkome, George R ^b   Hill, Craig L ^a  

^a EMORY UNIVERSITY   (United States)

^b UNIVERSITY OF SOUTH FLORIDA   (United States)

Author keywords

Catalysts; Dendrimers; Polyoxometalates; Supramolecular chemistry

Indexed keywords

DENDRIMER; METAL COMPLEX; PEROXIDE; THIOPHENE;

ARTICLE; CATALYST; CHEMICAL MODIFICATION; ESTERIFICATION; MOLECULAR STABILITY; OXIDATION REDUCTION REACTION;

EID: 0034658593     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3773(20000515)39:10<1771::aid-anie1771>3.0.co;2-d     Document Type: Article

References (45)

1. G. R. Newkome, E. He, C. N. Moorefield, Chem. Rev. 1999, 99, 1689-1746.
2. a) A. Miedaner, C. J. Curtis, R. M. Barkley, D. L. Du Bois, Inorg. Chem. 1994, 33, 5482-5490;
3. b) G. van Koten, D. M. Grove, Polym. Mater. Sci. Eng. 1995, 73, 228-229;
4. c) P. Bhyrappa, J. K. Young, J. S. Moore, K. S. Suslick, J. Am. Chem. Soc. 1996, 118, 5708-5711;
5. d) P. Bhyrappa, J. K. Young, J. S. Moore, K. S. Suslick, J. Mol. Catal. A 1996, 113, 109-116;
6. e) K. S. Suslick, P. Bhyrappa, J. Inorg. Biochem. 1997, 67, 234;
7. f) P. B. Rheiner, H. Sellner, D. Seebach, Helv. Chim. Acta 1997, 80, 2027-2032;
8. g) M. T. Reetz, G. Lohmer, R. Schwickardi, Angew. Chem. 1997, 109, 1559-1562; Angew. Chem. Int. Ed. 1997, 36, 1526-1529;
9. g) M. T. Reetz, G. Lohmer, R. Schwickardi, Angew. Chem. 1997, 109, 1559-1562; Angew. Chem. Int. Ed. 1997, 36, 1526-1529;
10. h) H.-F. Chow, C. C. Mak, J. Org. Chem. 1997, 62, 5116-5127;
11. i) C. C. Mak, H.-F. Chow, Macromolecules 1997, 30, 1228-1230;
12. j) R. A. Gossage, L. A. Van De Kuil, G. van Koten, Acc. Chem. Res. 1998, 31, 423-431;
13. k) C. Köllner, B. Pugin, A. Togni, J. Am. Chem. Soc. 1998, 120, 10274-10275;
14. l) R. A. Gossage, J. Jastrzebski, J. van Ameijde, S. J. E. Mulders, A. J. Brouwer, R. M. J. Liskamp, G. van Koten, Tetrahedron Lett. 1999, 40, 1413-1416;
15. m) M. Zhao, R. M. Crooks, Angew. Chem. 1999, 111, 375-377; Angew. Chem. Int. Ed. 1999, 38, 364-366;
16. m) M. Zhao, R. M. Crooks, Angew. Chem. 1999, 111, 375-377; Angew. Chem. Int. Ed. 1999, 38, 364-366;
17. n) M. A. Hearshaw, A. T. Hutton, J. R. Moss, K. J. Naidoo in Advances in Dendritic Macromolecules, Vol. 4 (Ed.: G. R. Newkome), JAI Press, Stamford, CT, 1999, pp. 1-60;
18. o) S. C. Bourque, F. Maltais, W.-J. Xiao, O. Tardif, H. Alper, P. Arya, L. E. Manzer, J. Am. Chem. Soc. 1999, 121, 3035-3038;
19. p) M. Zhao, L. Sun, R. M.Crooks, Polym. Prepr. 1999, 40, 400-401;
20. q) K. Matyjaszewski, Chem. Eur. J. 1999, 5, 3095-3102;
21. r) G. E. Oosterom, R. J. van Haaren, J. N. H. Reek, P. C. J. Kamer, P. W. N. M. van Leeuwen, Chem. Commum. 1999, 1119-1120.
22. Reviews of POMs and catalytic activity: a) Polyoxometalates, from Platonic Solids to Anti-Retroviral Activity (Eds.: M. T. Pope, A. Müller), Kluwer, 1994;
23. b) C. L. Hill, C. M. Prosser-McCartha, Coord. Chem. Rev. 1995, 143, 407-455;
24. c) "Polyoxometalates in Catalysis": C. L. Hill, J. Mol. Catal. 1996, 114, 1-371;
25. d) T. Okuhara, N. Mizuno, M. Misono, Adv. Catal. 1996, 41, 113-252;
26. e) R. Neumann, Prog. Inorg. Chem. 1998, 47317-370.
27. Polymers with covalently bound POMs: a) D. E. Katsoulis, J. R. Keryk, Mater. Res. Soc. Symp. Proc. 1996, 435, 589-594;
28. b) E. M. Ansonii, Jpn. Kokai Tokkyo Koho 1996, 23;
29. c) P. Judeinstein, J. Sol-Gel Sci. Technol. 1994, 2, 147-151;
30. d) P. Judeinstein, Chem. Mater. 1992, 4, 4-7.
31. Reviews that include such complexes: a) O. Chen, J. Zubieta, Coord. Chem. Rev. 1992, 114, 107-167;
32. b) M. I. Khan, J. Zubieta, Prog. Inorg. Chem. 1995, 43, 1-149;
33. c) J. Zubieta in [3a], pp. 125-156;
34. d) D. Rehder in [3a], pp. 157-166.
35. a) M. I. Khan, Q. Chen, D. P. Goshorn, H. Hope, S. Parkin, J. Zubieta, J. Am. Chem. Soc. 1992, 114, 3341-3346;
36. b) Q. Chen, D. P. Goshorn, C. P. Scholes, X.-I. Tan, J. Zubieta, J. Am. Chem. Soc. 1992, 114, 4667-4681;
37. c) Y. Hou. C. L. Hill, J. Am. Chem. Soc. 1993, 115, 11823-11830;
38. d) D. C. Crans, F. Jiang, J. Chen, O. P. Anderson, M. M. Miller, Inorg. Chem. 1997, 36, 1038-1047;
39. e) D. C. Crans, I. Boukhobza, J. Am. Chem. Soc. 1998, 120, 8069-8078; the following two references address systems with two rather than three V-O-C bonds:
40. f) C. P. Rao, A. Screedhara, P. V. Rao, M. B. Verghese, K. Rissanen, E. Kolehmainen, N. K. Lokanath, M. A. Sridhar, J. S. Prasad, J. Chem. Soc. Dalton Trans. 1998, 2383-2394;
41. g) E. Rakovsky, L. Zurkova, Monogr. Ser. Int. Conf. Coord. Chem. 1999, 4, 465-470.
42. + salt of a polyvanadium-containing POM where the protons were structurally located indicated they were on these oxygen atoms in MeCN, see V. W. Day, W. G. Klemperer, D. J. Maltbie, J. Am. Chem. Soc. 1987, 109, 2991-3002. In consequence, the hydrogen atoms in both formulas and equations of the POMs here have been written to indicate that they are on these POM oxygen atoms.
43. R. G. Finke, B. Rapko, R. J. Saxton, P. J. Domaille, J. Am. Chem. Soc. 1986, 108, 2947-2960.
44. G. R. Newkome, G. R. Baker, S. Arai, M. J. Saunders, P. S. Russo, K. J. Theriol, C. N. Moorefield, L. E. Rogers, J. E. Miller, T. R. Lieux, M. E. Murray, B. Phillips, L. Pascal, J. Am. Chem. Soc. 1990, 112, 8458-8465.
45. G. R. Newkome, C. D. Weis, Org. Prep. Proced. Int. 1996, 28, 242-246.