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1 = 0.060 (for 1604 data with I ≥2σ(I)). Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication nos. CCDC-137462 3a and -137463 for 5a. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ. UK (fax: (+ 44) 1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
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