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Volumn 599, Issue 2, 2000, Pages 304-307

Selective P-N bond cleavage in chiral triquinphosphoranes promoted by zirconocene complexes

Author keywords

Chiral phosphanes; Metallocene; Opening reaction; Phosphoranes; Zirconium

Indexed keywords


EID: 0034654720     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(00)00062-0     Document Type: Article
Times cited : (3)

References (23)
  • 11
    • 33947294608 scopus 로고
    • The turnstile mechanism is sometimes alternatively invoked, but for the triquinphosphoranes the pseudo-rotation according Berry is by far the most appropriated in the sense of symmetrical factors and due to the structural dependence of five membered rings:
    • (b) K. Mislow, Acc. Chem. Res. 3 (1970) 321. The turnstile mechanism is sometimes alternatively invoked, but for the triquinphosphoranes the pseudo-rotation according Berry is by far the most appropriated in the sense of symmetrical factors and due to the structural dependence of five membered rings:
    • (1970) Acc. Chem. Res. , vol.3 , pp. 321
    • Mislow, K.1
  • 12
    • 0001052145 scopus 로고
    • The topological equivalence between Berry and turnstile pseudo-rotation has been addressed
    • (c) I. Ugi, D. Marquarding, H. Klusacek, P. Gillespie, F. Ramirez, Acc. Chem. Res. 4 (1971) 288. The topological equivalence between Berry and turnstile pseudo-rotation has been addressed:
    • (1971) Acc. Chem. Res. , vol.4 , pp. 288
    • Ugi, I.1    Marquarding, D.2    Klusacek, H.3    Gillespie, P.4    Ramirez, F.5
  • 14
    • 0001243019 scopus 로고
    • For the nomenclature of chiral pentacoordinated compounds see: The sense of chirality can be specified by viewing the idealized TBP structure along its apical axis in the orientation which places nearer the viewer the apical substituent which has the higher priority rank in the CIP nomenclature scheme. The priority ranking of the equatorial ligands using the CIP conventions results in order decreasing priority which can be recognized by the viewer as being clockwise (R) or counterclokwise (S)
    • For the nomenclature of chiral pentacoordinated compounds see: (a) J.C. Martin, T.M. Balthazor, J. Am. Chem. Soc. 99 (1977) 152. The sense of chirality can be specified by viewing the idealized TBP structure along its apical axis in the orientation which places nearer the viewer the apical substituent which has the higher priority rank in the CIP nomenclature scheme. The priority ranking of the equatorial ligands using the CIP conventions results in order decreasing priority which can be recognized by the viewer as being clockwise (R) or counterclokwise (S).
    • (1977) J. Am. Chem. Soc. , vol.99 , pp. 152
    • Martin, J.C.1    Balthazor, T.M.2
  • 18
    • 85037799324 scopus 로고    scopus 로고
    • have recently obtained an X-ray diffraction structure of the triquinphosphorane deriving from N,N′-bis[(-)-norephedrine]ethylene. In this structure, the phosphorus atom adopts a TBP geometry with a nitrogen atom in apical position and the five membered rings in the apical-equatorial positions
    • (d) Contreras et al. have recently obtained an X-ray diffraction structure of the triquinphosphorane deriving from N,N′-bis[(-)-norephedrine]ethylene. In this structure, the phosphorus atom adopts a TBP geometry with a nitrogen atom in apical position and the five membered rings in the apical-equatorial positions.
    • Contreras1
  • 20
    • 85037790224 scopus 로고    scopus 로고
    • C. Doctoral Thesis no. 96AIX30083, University Aix-Marseille 3, France
    • C. Marchi, C. Doctoral Thesis no. 96AIX30083, University Aix-Marseille 3, France, 1996.
    • (1996)
    • Marchi, C.1
  • 23
    • 84985494070 scopus 로고
    • The place of transition metals in organic synthesis
    • D.W. Slocum (Ed.)
    • (b) M.D. Rausch, W. H. Boon, H. G. Alt, The place of transition metals in organic synthesis, in: D.W. Slocum (Ed.), Annals of the New York Academy of Sciences, vol. 295, 1977, p. 103.
    • (1977) Annals of the New York Academy of Sciences , vol.295 , pp. 103
    • M.D. Rausch1    W. H. Boon2    H. G. Alt3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.