Probing the cyclic transition state in the reaction O(3P) + alkyl iodides to form HOI: Electronic, steric and thermodynamic factors influencing the reaction pathway

Physical Chemistry Chemical Physics

Volumn 2, Issue 4, 2000, Pages 853-860

  Reid, Jonathan P ^a   Qian, Charles X W ^a,b   Leone, Stephen R ^a  

^a UNIVERSITY OF COLORADO   (United States)

^b UNIVERSITY OF VICTORIA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL GROUP; IODINE DERIVATIVE; PHOSPHORUS DERIVATIVE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION; ENERGY; FOURIER TRANSFORMATION; INFRARED SPECTROSCOPY; THERMODYNAMICS; VIBRATION;

EID: 0034652561     PISSN: 14639076     EISSN: None     Source Type: Journal    
DOI: 10.1039/a907721i     Document Type: Article

References (28)

1. 1 R. D. Levine and R. B. Bernstein, Molecular Reaction Dynamics and Chemical Reactivity, Oxford University Press, Inc., Oxford, 1987.
2. 2 D. J. Donaldson and J. J. Sloan, J. Chem. Phys., 1985, 82, 1873.
3. 3 U. Schwanke, H. Heydtmann and J. J. Sloan, Chem. Phys., 1989, 132, 413.
4. 4 E. Arunan, S. J. Wategaonkar and D. W. Setser, J. Phys. Chem., 1991, 95, 1539.
5. 5 E. Arunan, R. Rengarajan and D. W. Setser, Can. J. Chem., 1994, 72, 568.
6. 6 R. A. Loomis, S. R. Leone and M. K. Gilles, Research on Chemical Intermediates, 1998, 24, 707.
7. 7 P. S. Monks, L. J. Steif, D. W. Tardy, J. F. Liebman, Z. Zhang, S.-C. Kuo and R. B. Klemm, J. Phys. Chem., 1995, 99, 16566.
8. 8 J. J. Klaassen, J. Lindner and S. R. Leone, J. Chem. Phys., 1996, 104, 7403.
9. 9 R. A. Loomis, J. J. Klaassen, J. Lindner, P. G. Christopher and S. R. Leone, J. Chem. Phys., 1997, 106, 3934.
10. 10 J. J. Wang, D. J. Smith and R. Grice, J. Phys. Chem., 1996, 100, 6620.
11. 11 J. J. Wang, D. J. Smith and R. Grice, J. Phys. Chem., 1996, 100, 13603.
12. 12 P. Marshall, A. Misra, W.-J. Yuan and R. J. Berry, Abstracts of Papers - American Chemical Society, American Chemical Society, Dayton, OH, 1996, abstract 91.
13. 13 J. E. Stevens, Q. Cui and K. Morokuma, J. Chem. Phys., 1998, 108, 1544.
14. 14 J. T. Herron and R. E. Huie, J. Phys. Chem., 1969, 73, 1326.
15. 15 M. K. Gilles, A. A. Turnipseed, R. K. Talukdar, Y. Rudich, P. W. Villalta, L. G. Huey, J. B. Burkholder and A. R. Ravishankara, J. Phys. Chem., 1996, 100, 14005.
16. 16 J. T. Herron and R. E. Huie, J. Phys. Chem., 1969, 73, 1326.
17. 17 A. Misra, R. J. Berry and P. Marshall, J. Phys. Chem. A, 1997, 101, 7420.
18. 18 J. J. Wang, D. J. Smith and R. Grice, J. Phys. Chem., 1997, 101, 3293.
19. 19 X. Gao, J. E. Lopresti, S. Munro, M. P. Hall, D. J. Smith and R. Grice, J. Chem. Soc., Faraday Trans., 1997, 93, 4119.
20. 20 S. R. Leone, Acc. Chem. Res., 1989, 22, 139.
21. 21 G. Hancock and D. E. Heard, in Advances in Photochemistry Vol. 18, ed. D. H. Volman, G. S. Hammond and D. C. Neckers, Wiley, New York, 1993, pp. 1-65.
22. 22 S. A. Rogers and S. R. Leone, Appl. Spectrosc., 1993, 47, 1430.
23. 23 H. L. Welsh, E. J. Stansbury, J. Romanko and T. Feldman, J. Opt. Soc. Am., 1955, 45, 338.
24. 24 I. R. Slagle, D. Sarzynski and D. Gutman, J. Phys. Chem., 1987, 91, 4375.
25. 25 M. K. Gilles (private communication).
26. 26 J. Lindner, R. A. Loomis, J. J. Klaassen and S. R. Leone, J. Chem. Phys., 1998, 108, 1944.
27. 27 C. Cohen-Tannoudji, B. Diu and F. Laloe, Quantum Mechanics, Wiley, New York, 1977.
28. 28 D. D. Nelson, Jr., A. Schiffman, D. J. Nesbitt, J. J. Orlando and J. B. Burkholder, J. Chem. Phys., 1990, 93, 7003.