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Volumn 298, Issue 2, 2000, Pages 131-140

Structural and spectroscopic comparisons in two series of cobalt(III)-monodentate phosphine complexes: Trans-[Co(acac)2(PMe(3 - n)Ph(n))(H2O)]PF6 and trans-[Co(acac)2(PMe(3 - n)Ph(n))2]PF6 (acac = pentane-2,4-dionate; n = 0, 1, 2 and 3)

(3) Suzuki, Takayoshi a Kaizaki, Sumio a Kashiwabara, Kazuo b

a OSAKA UNIVERSITY (Japan)

b NAGOYA UNIVERSITY (Japan)

Author keywords

59Co NMR spectroscopy; Cobalt(III) complexes; Crystal structures; Monodentate tertiary phosphines; Spectral parameters; Trans influence

Indexed keywords

BOND LENGTH; CRYSTAL STRUCTURE; CRYSTALS; LIGANDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PARAMETER ESTIMATION; PHOSPHORUS COMPOUNDS; SOLID SOLUTIONS;

COBALT COMPLEXES (III); MONO-DENTATE PHOSPHINE; SPECTRAL PARAMETERS; SPECTROSCOPIC COMPARISON; SPECTROSCOPIC PROPERTY; TERTIARY PHOSPHINES; TRANS INFLUENCE; X RAY CRYSTAL STRUCTURES;

COBALT COMPOUNDS;

COBALT COMPLEX; METHYL GROUP; PHENYL GROUP; PHOSPHINE DERIVATIVE;

ABSORPTION SPECTROSCOPY; ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTAL STRUCTURE; DISSOLUTION; LIGAND BINDING; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SOLID STATE; STEREOSPECIFICITY; TRANS ISOMER; X RAY CRYSTALLOGRAPHY;

EID: 0034651446 PISSN: 00201693 EISSN: None Source Type: Journal
DOI: 10.1016/S0020-1693(99)00399-0 Document Type: Article

Times cited : (11)

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