-
1
-
-
33744643965
-
-
Deutsches Patent Schrift 849.548 (1938/1952), US patent 2.327.066
-
O. Roelen, Deutsches Patent Schrift 849.548 (1938/1952), US patent 2.327.066 (1943).
-
(1943)
-
-
O. Roelen1
-
4
-
-
33744695632
-
-
US patents 3.239.569 and 3.239.570
-
L.H. Slaugh, R.D. Mullineaux, US patents 3.239.569 and 3.239.570 (1969).
-
(1969)
-
-
L.H. Slaugh1
R.D. Mullineaux2
-
9
-
-
33744643963
-
-
Eur. Pat. Appl. 220.767 (1985).
-
(a) E. Drent, Eur. Pat. Appl. 220.767 (1985).
-
-
-
E. Drent1
-
10
-
-
33744590264
-
-
UK Pat. Appl. 2.183.631 (1985).
-
(b) E. Drent, UK Pat. Appl. 2.183.631 (1985).
-
-
-
E. Drent1
-
14
-
-
33744631074
-
-
The term hydro-acylation has also been used to denote the reaction of olefins with aldehydes to produce ketones. Because of the analogy with hydroformylation, however, we prefer to reserve this term for the synthesis of ketones from olefins, carbon monoxide and hydrogen.
-
The term hydro-acylation has also been used to denote the reaction of olefins with aldehydes to produce ketones. Because of the analogy with hydroformylation, however, we prefer to reserve this term for the synthesis of ketones from olefins, carbon monoxide and hydrogen.
-
-
-
-
15
-
-
0000984657
-
-
Dekker G.P.C.M., Elsevier C.J., Vrieze K., van Leeuwen P.W.N.M., Roobeek C.F. J. Organomet. Chem. 430:1992;357.
-
(1992)
J. Organomet. Chem.
, vol.430
, pp. 357
-
-
Dekker, G.P.C.M.1
Elsevier, C.J.2
Vrieze, K.3
Van Leeuwen, P.W.N.M.4
Roobeek, C.F.5
-
17
-
-
0001626460
-
-
An alternative possibility of intermediate Pd(IV)-dihydride species obtained via an oxidative pathway of Pd(II) and dihydrogen, similar to that proposed for hydrogenolysis of Ir(I)-acyl intermediates (P.P. Deutsch, R. Eisenberg, Organometallics 9 (1990) 709), is considered unlikely. The generation of Pd(IV) from Pd(II) species has, however, been demonstrated, but generally requires hard ligands and strong oxidants, such as alkyl iodides (see for example
-
An alternative possibility of intermediate Pd(IV)-dihydride species obtained via an oxidative pathway of Pd(II) and dihydrogen, similar to that proposed for hydrogenolysis of Ir(I)-acyl intermediates (P.P. Deutsch, R. Eisenberg, Organometallics 9 (1990) 709), is considered unlikely. The generation of Pd(IV) from Pd(II) species has, however, been demonstrated, but generally requires hard ligands and strong oxidants, such as alkyl iodides (see for example, P.K. Wong, J.K. Stille, J. Organomet. Chem. 70 (1974) 121).
-
(1974)
J. Organomet. Chem.
, vol.70
, pp. 121
-
-
P.K. Wong1
J.K. Stille2
-
18
-
-
33845561101
-
-
An alternative possibility of intermediate Pd(IV)-dihydride species obtained via an oxidative pathway of Pd(II) and dihydrogen, similar to that proposed for hydrogenolysis of Ir(I)-acyl intermediates (P.P. Deutsch, R. Eisenberg, Organometallics 9 (1990) 709), is considered unlikely. The generation of Pd(IV) from Pd(II) species has, however, been demonstrated, but generally requires hard ligands and strong oxidants, such as alkyl iodides (see for example, P.K. Wong, J.K. Stille, J. Organomet. Chem. 70 (1974) 121). (a) D. Milstein, J.K. Stille, J. Am. Chem Soc. 101 (1972) 4992.
-
(1972)
J. Am. Chem Soc.
, vol.101
, pp. 4992
-
-
D. Milstein1
J.K. Stille2
-
21
-
-
33744667278
-
-
Eur. Pat. Appl. 495.548 (1992).
-
E. Drent, E. Kragtwijk, Eur. Pat. Appl. 495.548 (1992).
-
-
-
E. Drent1
E. Kragtwijk2
-
24
-
-
0025210761
-
-
Strictly speaking, only one of the two CO insertions needs to be reversible. There is precedent for a difference in reversibility between n-acyl and iso-acyl formation in rhodium catalyzed hydroformylation (see
-
Strictly speaking, only one of the two CO insertions needs to be reversible. There is precedent for a difference in reversibility between n-acyl and iso-acyl formation in rhodium catalyzed hydroformylation (see R. Lazzaroni, P. Pertici, G.J. Fabrici, J. Mol. Catal. 58 (1990) 75).
-
(1990)
J. Mol. Catal.
, vol.58
, pp. 75
-
-
R. Lazzaroni1
P. Pertici2
G.J. Fabrici3
-
25
-
-
33744662074
-
-
Eur. Pat. Appl. 229.408 (1986).
-
(a) E. Drent, Eur. Pat. Appl. 229.408 (1986).
-
-
-
E. Drent1
-
31
-
-
0027589608
-
-
Wong P.K., van Doorn J.A., Drent E., Sudmeijer O., Stil H.A. Ind. Eng. Chem. Res. 32:1993;986.
-
(1993)
Ind. Eng. Chem. Res.
, vol.32
, pp. 986
-
-
Wong, P.K.1
Van Doorn, J.A.2
Drent, E.3
Sudmeijer, O.4
Stil, H.A.5
-
32
-
-
33744668126
-
-
Eur. Pat. Appl. 384.517 (1989).
-
(a) P.K. Wong, Eur. Pat. Appl. 384.517 (1989).
-
-
-
P.K. Wong1
-
34
-
-
0003696349
-
-
Thesis, University of Amsterdam, The Netherlands
-
J.A. van Doorn, Functionalised Phosphines, Thesis, University of Amsterdam, The Netherlands, 1991.
-
(1991)
Functionalised Phosphines
-
-
J.A. van Doorn1
|