Non-statistical effects in the gas phase S(N)2 reaction [4]

Journal of the American Chemical Society

Volumn 122, Issue 36, 2000, Pages 8783-8784

  Tonner, D S ^a   McMahon, T B ^a  

^a UNIVERSITY OF WATERLOO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REACTION; CHLORIDE TRANSPORT; DISSOCIATION; ELECTRIC POTENTIAL; FOURIER TRANSFORMATION; INFRARED SPECTROSCOPY; ION TRANSPORT; LETTER; STATISTICAL ANALYSIS; VIBRATION;

EID: 0034644429     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja000881+     Document Type: Letter

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28. 3Br)] may also arise from a non-Boltzmann distribution. Population of intramolecular and intermolecular modes occurs via absorption from the appropriate region of the blackbody spectrum. While these complexes will then have vibrational energy in each of these types of modes, communication between the modes may be too slow, on the time scale of the experiment, to achieve a Boltzmann like distribution.
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