{2,6-trip2H3C6Sn(μ-H)}2 (Trip = C6H2-2,4,6-i-Pr3): Synthesis and structure of a divalent group 14 element hydride [5]

Journal of the American Chemical Society

Volumn 122, Issue 36, 2000, Pages 8785-8786

  Eichler, Barrett E ^a   Power, Philip P ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALUMINUM DERIVATIVE; DIISOBUTYLALUMINUM HYDRIDE; ORGANOTIN HYDRIDE; UNCLASSIFIED DRUG;

CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; GEOMETRY; HYDROGEN BOND; LETTER; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 0034644384     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja000180c     Document Type: Letter

References (30)

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5. For recent reviews of low-coordinate group 14 compounds, see: (a) Brook, A. G.; Brook, M. A. Adv. Organomet. Chem. 1996, 39, 71. (b) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 232. (c) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1996, 39, 275. (d) Rappaport, Z.; Apeloig, Y., Eds. The Chemistry of Organic Silicon Compounds; John Wiley and Sons: Chichester, 1998; Vol. 2. (e) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (f) Power, P. P. Chem. Rev. 1999, 99, 3463.
6. For recent reviews of low-coordinate group 14 compounds, see: (a) Brook, A. G.; Brook, M. A. Adv. Organomet. Chem. 1996, 39, 71. (b) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 232. (c) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1996, 39, 275. (d) Rappaport, Z.; Apeloig, Y., Eds. The Chemistry of Organic Silicon Compounds; John Wiley and Sons: Chichester, 1998; Vol. 2. (e) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (f) Power, P. P. Chem. Rev. 1999, 99, 3463.
7. For recent reviews of low-coordinate group 14 compounds, see: (a) Brook, A. G.; Brook, M. A. Adv. Organomet. Chem. 1996, 39, 71. (b) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 232. (c) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1996, 39, 275. (d) Rappaport, Z.; Apeloig, Y., Eds. The Chemistry of Organic Silicon Compounds; John Wiley and Sons: Chichester, 1998; Vol. 2. (e) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (f) Power, P. P. Chem. Rev. 1999, 99, 3463.
8. For recent reviews of low-coordinate group 14 compounds, see: (a) Brook, A. G.; Brook, M. A. Adv. Organomet. Chem. 1996, 39, 71. (b) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 232. (c) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1996, 39, 275. (d) Rappaport, Z.; Apeloig, Y., Eds. The Chemistry of Organic Silicon Compounds; John Wiley and Sons: Chichester, 1998; Vol. 2. (e) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (f) Power, P. P. Chem. Rev. 1999, 99, 3463.
9. For recent reviews of low-coordinate group 14 compounds, see: (a) Brook, A. G.; Brook, M. A. Adv. Organomet. Chem. 1996, 39, 71. (b) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 232. (c) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1996, 39, 275. (d) Rappaport, Z.; Apeloig, Y., Eds. The Chemistry of Organic Silicon Compounds; John Wiley and Sons: Chichester, 1998; Vol. 2. (e) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (f) Power, P. P. Chem. Rev. 1999, 99, 3463.
10. For recent reviews of low-coordinate group 14 compounds, see: (a) Brook, A. G.; Brook, M. A. Adv. Organomet. Chem. 1996, 39, 71. (b) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 232. (c) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1996, 39, 275. (d) Rappaport, Z.; Apeloig, Y., Eds. The Chemistry of Organic Silicon Compounds; John Wiley and Sons: Chichester, 1998; Vol. 2. (e) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (f) Power, P. P. Chem. Rev. 1999, 99, 3463.
11. Twamley, B.; Haubrich, S. T.; Power, P. P. Adv. Organomet. Chem. 1999, 44, 1.
12. 6, 149.16 MHz, 25 °C): δ 698.7.
13. Olmstead, M. M.; Simons, R. S.; Power, P. P. J. Am. Chem. Soc. 1997, 119, 11705
14. Crystal data for 4 at 90 K with Mo Kα (λ = 0.71073 Å) radiation: a = 13.1343(6) Å, b = 13.2288(6) Å, c = 13.3728(6) Å, α = 93.676(1)°, β = 97.678(1)°, γ = 115.380(1)°, triclinic, space group P1, Z = 1, R1 = 0.0434 for 12 981 (1 > 2σ(I)) data, wR2 = 0.0985 for all (29 682) data.
15. Simons, R. S.; Pu, L.; Olmstead, M. M.; Power, P. P. Organometallics 1997, 16, 1920.
16. Wells, A. F. Structural Inorganic Chemistry; Oxford University Press: New York, 1984.
17. If the blue solutions are rapidly cooled, however, a blue microcrystalline solid is produced. A blue color is invariably seen with a variety of solvents such as hexane, benzene, toluene, or ether. Slow cooling of these solutions gives an orange solid.
18. max = 553 nm)display absorptions at similar wavelengths. See ref 8.
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26. Eichler, B. E.; Phillips, B. L.; Power, P. P.; Augustine, M. P. Unpublished work. The large chemical shift anisotropies arise from the very low local symmetry at the tin(II) center in monomeric, two-coordinate compounds.
27. Poole, C. P.; Farach, H. A. Relaxation in Magnetic Resonance; Academic Press: New York, 1971; p 75.
28. The Nujol mull displays a blue color suggesting the presence of monomer. Since only one Sn-H sketching band would be expected for such a species the two bands may arise from the bridged dimer in the solid.
29. 2O reference, 61.37 MHz): δ 7.69.
30. 12d