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Volumn 113, Issue 10, 2000, Pages 3951-3959

Molecular engineering of push-pull dipolar and quadrupolar molecules for two-photon absorption: A multivalence-bond states approach

Author keywords

[No Author keywords available]

Indexed keywords

BINDING ENERGY; EIGENVALUES AND EIGENFUNCTIONS; GROUND STATE; LIGHT POLARIZATION; MATRIX ALGEBRA; MOLECULAR DYNAMICS; PHOTONS; WAVE EQUATIONS;

EID: 0034622731     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1288367     Document Type: Article
Times cited : (180)

References (51)
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    • In this three-state model, a coupling parameter between the zwitterionic forms was considered
    • The structure-cubic polarizability γ(0) relationship of linear quadrupolar D-A-D or A-D-A systems has been investigated in the following reference, based on the VB theory: S. Hahn, D. Kim, and M. Cho, J. Phys. Chem. B 103, 8221 (1999). In this three-state model, a coupling parameter between the zwitterionic forms was considered.
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    • ijkl(ω) component projected along this axis
    • ijkl(ω) component projected along this axis.
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    • note
    • eg. The β(0) peaks are reached for the optimal MIX values MIX = ± 1/√5 (i.e., V = ∓t). For the dependence of β(0) and γ(0) on MIX see Ref. 27.
  • 44
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    • As already noted, this is the case for push-pull quadrupolar compound 9 of Fig. 2. Examples of push-pull dipolar compounds having MIX ≈ - 1/√3 can be found in Refs. 28, 29, and 31
    • As already noted, this is the case for push-pull quadrupolar compound 9 of Fig. 2. Examples of push-pull dipolar compounds having MIX ≈ - 1/√3 can be found in Refs. 28, 29, and 31.
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    • It is interesting to note that compounds 8 and 9 of Ref. 14 can be described as the superposition of structures of types I′ and III′
    • It is interesting to note that compounds 8 and 9 of Ref. 14 can be described as the superposition of structures of types I′ and III′.


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