SCOPUS 정보 검색 플랫폼

Journal of the American Chemical Society

Volumn 122, Issue 9, 2000, Pages 1927-1936

A novel tandem Michael addition/Meerwein-Ponndorf-Verley reduction: Asymmetric reduction of acyclic α,β-unsaturated ketones using a chiral mercapto alcohol

(5) Node, Manabu a Nishide, Kiyoharu a Shigeta, Yukihiro a Shiraki, Hiroaki a Obata, Kenichi a

a KYOTO PHARMACEUTICAL UNIVERSITY (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL DERIVATIVE; KETONE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHIRALITY; DESULFURIZATION; DIASTEREOISOMER; REACTION ANALYSIS; REDUCTION; STEREOCHEMISTRY; STRUCTURE ANALYSIS;

EID: 0034620685 PISSN: 00027863 EISSN: None Source Type: Journal
DOI: 10.1021/ja993546y Document Type: Article

Times cited : (99)

References (84)

1
- 0000426886
- Review: (a) Wilds, A. L. Org. React. 1944, 2, 178-223. (b) de Graauw, C. F.; Peters, J. A.; van Bekkum, H.; Huskens, J. Synthesis 1994, 1007-1017. (c) Takahashi, K.; Shibagaki, M.; Kuno, H.; Matsushita, H. Shokubai 1995, 37, 23-27 and references therein. Also see: (d) Knauer, B.; Krohn, K. Liebigs Ann. 1995, 677-683. (e) Krohn, K.; Knauer, B. Liebigs Ann. 1995, 1347-1351. (f) Castellani, C. B.; Carugo, O.; Perotti, A.; Sacchi, D.; Invernizzi, A. G.; Vidari, G. J. Mol. Catal. 1993, 85, 65- 74. (g) Strickler, J. R.; Bruck, M. A.; Wexler, P. A.; Wigley, D. E. Organometallics 1990, 9, 266-273. (h) Ramig, K.; Kuzemko, M. A.; Parrish, D.; Carpenter, B. K. Tetrahedron Lett. 1992, 33, 6279-6282. (i) Kaspar, J.; Trovarelli, A.; Lenarda, M.; Graziani, M. Tetrahedron Lett. 1989, 30, 2705-2706. (j) Hutton, J. Synth. Commun. 1979, 9, 483-486. (k) Kowalski, C.; Creary, X.; Rollin, A. J.; Burke, M. C. J. Org. Chem. 1978, 43, 2601-2608. (l) Takezawa, N.; Kobayashi, H. Chem. Lett. 1977, 123- 126. (m) Doering, W. von E.; Aschner, T. C. J. Am. Chem. Soc. 1953, 75, 393-397. (n) Ooi, T.; Miura, T.; Maruoka, K. Angew. Chem., Int. Ed. 1998, 37, 2347-2349.
- (1944) Org. React. , vol.2 , pp. 178-223
- Wilds, A.L.¹

2
- 0027943932
- Review: (a) Wilds, A. L. Org. React. 1944, 2, 178-223. (b) de Graauw, C. F.; Peters, J. A.; van Bekkum, H.; Huskens, J. Synthesis 1994, 1007-1017. (c) Takahashi, K.; Shibagaki, M.; Kuno, H.; Matsushita, H. Shokubai 1995, 37, 23-27 and references therein. Also see: (d) Knauer, B.; Krohn, K. Liebigs Ann. 1995, 677-683. (e) Krohn, K.; Knauer, B. Liebigs Ann. 1995, 1347-1351. (f) Castellani, C. B.; Carugo, O.; Perotti, A.; Sacchi, D.; Invernizzi, A. G.; Vidari, G. J. Mol. Catal. 1993, 85, 65- 74. (g) Strickler, J. R.; Bruck, M. A.; Wexler, P. A.; Wigley, D. E. Organometallics 1990, 9, 266-273. (h) Ramig, K.; Kuzemko, M. A.; Parrish, D.; Carpenter, B. K. Tetrahedron Lett. 1992, 33, 6279-6282. (i) Kaspar, J.; Trovarelli, A.; Lenarda, M.; Graziani, M. Tetrahedron Lett. 1989, 30, 2705-2706. (j) Hutton, J. Synth. Commun. 1979, 9, 483-486. (k) Kowalski, C.; Creary, X.; Rollin, A. J.; Burke, M. C. J. Org. Chem. 1978, 43, 2601-2608. (l) Takezawa, N.; Kobayashi, H. Chem. Lett. 1977, 123- 126. (m) Doering, W. von E.; Aschner, T. C. J. Am. Chem. Soc. 1953, 75, 393-397. (n) Ooi, T.; Miura, T.; Maruoka, K. Angew. Chem., Int. Ed. 1998, 37, 2347-2349.
- (1994) Synthesis , pp. 1007-1017
- De Graauw, C.F.¹ Peters, J.A.² Van Bekkum, H.³ Huskens, J.⁴

3
- 0038961107
- and references therein
- Review: (a) Wilds, A. L. Org. React. 1944, 2, 178-223. (b) de Graauw, C. F.; Peters, J. A.; van Bekkum, H.; Huskens, J. Synthesis 1994, 1007-1017. (c) Takahashi, K.; Shibagaki, M.; Kuno, H.; Matsushita, H. Shokubai 1995, 37, 23-27 and references therein. Also see: (d) Knauer, B.; Krohn, K. Liebigs Ann. 1995, 677-683. (e) Krohn, K.; Knauer, B. Liebigs Ann. 1995, 1347-1351. (f) Castellani, C. B.; Carugo, O.; Perotti, A.; Sacchi, D.; Invernizzi, A. G.; Vidari, G. J. Mol. Catal. 1993, 85, 65- 74. (g) Strickler, J. R.; Bruck, M. A.; Wexler, P. A.; Wigley, D. E. Organometallics 1990, 9, 266-273. (h) Ramig, K.; Kuzemko, M. A.; Parrish, D.; Carpenter, B. K. Tetrahedron Lett. 1992, 33, 6279-6282. (i) Kaspar, J.; Trovarelli, A.; Lenarda, M.; Graziani, M. Tetrahedron Lett. 1989, 30, 2705-2706. (j) Hutton, J. Synth. Commun. 1979, 9, 483-486. (k) Kowalski, C.; Creary, X.; Rollin, A. J.; Burke, M. C. J. Org. Chem. 1978, 43, 2601-2608. (l) Takezawa, N.; Kobayashi, H. Chem. Lett. 1977, 123- 126. (m) Doering, W. von E.; Aschner, T. C. J. Am. Chem. Soc. 1953, 75, 393-397. (n) Ooi, T.; Miura, T.; Maruoka, K. Angew. Chem., Int. Ed. 1998, 37, 2347-2349.
- (1995) Shokubai , vol.37 , pp. 23-27
- Takahashi, K.¹ Shibagaki, M.² Kuno, H.³ Matsushita, H.⁴

4
- 84988087920
- Review: (a) Wilds, A. L. Org. React. 1944, 2, 178-223. (b) de Graauw, C. F.; Peters, J. A.; van Bekkum, H.; Huskens, J. Synthesis 1994, 1007-1017. (c) Takahashi, K.; Shibagaki, M.; Kuno, H.; Matsushita, H. Shokubai 1995, 37, 23-27 and references therein. Also see: (d) Knauer, B.; Krohn, K. Liebigs Ann. 1995, 677-683. (e) Krohn, K.; Knauer, B. Liebigs Ann. 1995, 1347-1351. (f) Castellani, C. B.; Carugo, O.; Perotti, A.; Sacchi, D.; Invernizzi, A. G.; Vidari, G. J. Mol. Catal. 1993, 85, 65- 74. (g) Strickler, J. R.; Bruck, M. A.; Wexler, P. A.; Wigley, D. E. Organometallics 1990, 9, 266-273. (h) Ramig, K.; Kuzemko, M. A.; Parrish, D.; Carpenter, B. K. Tetrahedron Lett. 1992, 33, 6279-6282. (i) Kaspar, J.; Trovarelli, A.; Lenarda, M.; Graziani, M. Tetrahedron Lett. 1989, 30, 2705-2706. (j) Hutton, J. Synth. Commun. 1979, 9, 483-486. (k) Kowalski, C.; Creary, X.; Rollin, A. J.; Burke, M. C. J. Org. Chem. 1978, 43, 2601-2608. (l) Takezawa, N.; Kobayashi, H. Chem. Lett. 1977, 123- 126. (m) Doering, W. von E.; Aschner, T. C. J. Am. Chem. Soc. 1953, 75, 393-397. (n) Ooi, T.; Miura, T.; Maruoka, K. Angew. Chem., Int. Ed. 1998, 37, 2347-2349.
- (1995) Liebigs Ann. , pp. 677-683
- Knauer, B.¹ Krohn, K.²

5
- 84988112473
- Review: (a) Wilds, A. L. Org. React. 1944, 2, 178-223. (b) de Graauw, C. F.; Peters, J. A.; van Bekkum, H.; Huskens, J. Synthesis 1994, 1007-1017. (c) Takahashi, K.; Shibagaki, M.; Kuno, H.; Matsushita, H. Shokubai 1995, 37, 23-27 and references therein. Also see: (d) Knauer, B.; Krohn, K. Liebigs Ann. 1995, 677-683. (e) Krohn, K.; Knauer, B. Liebigs Ann. 1995, 1347-1351. (f) Castellani, C. B.; Carugo, O.; Perotti, A.; Sacchi, D.; Invernizzi, A. G.; Vidari, G. J. Mol. Catal. 1993, 85, 65- 74. (g) Strickler, J. R.; Bruck, M. A.; Wexler, P. A.; Wigley, D. E. Organometallics 1990, 9, 266-273. (h) Ramig, K.; Kuzemko, M. A.; Parrish, D.; Carpenter, B. K. Tetrahedron Lett. 1992, 33, 6279-6282. (i) Kaspar, J.; Trovarelli, A.; Lenarda, M.; Graziani, M. Tetrahedron Lett. 1989, 30, 2705-2706. (j) Hutton, J. Synth. Commun. 1979, 9, 483-486. (k) Kowalski, C.; Creary, X.; Rollin, A. J.; Burke, M. C. J. Org. Chem. 1978, 43, 2601-2608. (l) Takezawa, N.; Kobayashi, H. Chem. Lett. 1977, 123- 126. (m) Doering, W. von E.; Aschner, T. C. J. Am. Chem. Soc. 1953, 75, 393-397. (n) Ooi, T.; Miura, T.; Maruoka, K. Angew. Chem., Int. Ed. 1998, 37, 2347-2349.
- (1995) Liebigs Ann. , pp. 1347-1351
- Krohn, K.¹ Knauer, B.²

6
- 0027693758
- Review: (a) Wilds, A. L. Org. React. 1944, 2, 178-223. (b) de Graauw, C. F.; Peters, J. A.; van Bekkum, H.; Huskens, J. Synthesis 1994, 1007-1017. (c) Takahashi, K.; Shibagaki, M.; Kuno, H.; Matsushita, H. Shokubai 1995, 37, 23-27 and references therein. Also see: (d) Knauer, B.; Krohn, K. Liebigs Ann. 1995, 677-683. (e) Krohn, K.; Knauer, B. Liebigs Ann. 1995, 1347-1351. (f) Castellani, C. B.; Carugo, O.; Perotti, A.; Sacchi, D.; Invernizzi, A. G.; Vidari, G. J. Mol. Catal. 1993, 85, 65- 74. (g) Strickler, J. R.; Bruck, M. A.; Wexler, P. A.; Wigley, D. E. Organometallics 1990, 9, 266-273. (h) Ramig, K.; Kuzemko, M. A.; Parrish, D.; Carpenter, B. K. Tetrahedron Lett. 1992, 33, 6279-6282. (i) Kaspar, J.; Trovarelli, A.; Lenarda, M.; Graziani, M. Tetrahedron Lett. 1989, 30, 2705-2706. (j) Hutton, J. Synth. Commun. 1979, 9, 483-486. (k) Kowalski, C.; Creary, X.; Rollin, A. J.; Burke, M. C. J. Org. Chem. 1978, 43, 2601-2608. (l) Takezawa, N.; Kobayashi, H. Chem. Lett. 1977, 123- 126. (m) Doering, W. von E.; Aschner, T. C. J. Am. Chem. Soc. 1953, 75, 393-397. (n) Ooi, T.; Miura, T.; Maruoka, K. Angew. Chem., Int. Ed. 1998, 37, 2347-2349.
- (1993) J. Mol. Catal. , vol.85 , pp. 65-74
- Castellani, C.B.¹ Carugo, O.² Perotti, A.³ Sacchi, D.⁴ Invernizzi, A.G.⁵ Vidari, G.⁶

7
- 0025208715
- Review: (a) Wilds, A. L. Org. React. 1944, 2, 178-223. (b) de Graauw, C. F.; Peters, J. A.; van Bekkum, H.; Huskens, J. Synthesis 1994, 1007-1017. (c) Takahashi, K.; Shibagaki, M.; Kuno, H.; Matsushita, H. Shokubai 1995, 37, 23-27 and references therein. Also see: (d) Knauer, B.; Krohn, K. Liebigs Ann. 1995, 677-683. (e) Krohn, K.; Knauer, B. Liebigs Ann. 1995, 1347-1351. (f) Castellani, C. B.; Carugo, O.; Perotti, A.; Sacchi, D.; Invernizzi, A. G.; Vidari, G. J. Mol. Catal. 1993, 85, 65- 74. (g) Strickler, J. R.; Bruck, M. A.; Wexler, P. A.; Wigley, D. E. Organometallics 1990, 9, 266-273. (h) Ramig, K.; Kuzemko, M. A.; Parrish, D.; Carpenter, B. K. Tetrahedron Lett. 1992, 33, 6279-6282. (i) Kaspar, J.; Trovarelli, A.; Lenarda, M.; Graziani, M. Tetrahedron Lett. 1989, 30, 2705-2706. (j) Hutton, J. Synth. Commun. 1979, 9, 483-486. (k) Kowalski, C.; Creary, X.; Rollin, A. J.; Burke, M. C. J. Org. Chem. 1978, 43, 2601-2608. (l) Takezawa, N.; Kobayashi, H. Chem. Lett. 1977, 123- 126. (m) Doering, W. von E.; Aschner, T. C. J. Am. Chem. Soc. 1953, 75, 393-397. (n) Ooi, T.; Miura, T.; Maruoka, K. Angew. Chem., Int. Ed. 1998, 37, 2347-2349.
- (1990) Organometallics , vol.9 , pp. 266-273
- Strickler, J.R.¹ Bruck, M.A.² Wexler, P.A.³ Wigley, D.E.⁴

8
- 0026795937
- Review: (a) Wilds, A. L. Org. React. 1944, 2, 178-223. (b) de Graauw, C. F.; Peters, J. A.; van Bekkum, H.; Huskens, J. Synthesis 1994, 1007-1017. (c) Takahashi, K.; Shibagaki, M.; Kuno, H.; Matsushita, H. Shokubai 1995, 37, 23-27 and references therein. Also see: (d) Knauer, B.; Krohn, K. Liebigs Ann. 1995, 677-683. (e) Krohn, K.; Knauer, B. Liebigs Ann. 1995, 1347-1351. (f) Castellani, C. B.; Carugo, O.; Perotti, A.; Sacchi, D.; Invernizzi, A. G.; Vidari, G. J. Mol. Catal. 1993, 85, 65- 74. (g) Strickler, J. R.; Bruck, M. A.; Wexler, P. A.; Wigley, D. E. Organometallics 1990, 9, 266-273. (h) Ramig, K.; Kuzemko, M. A.; Parrish, D.; Carpenter, B. K. Tetrahedron Lett. 1992, 33, 6279-6282. (i) Kaspar, J.; Trovarelli, A.; Lenarda, M.; Graziani, M. Tetrahedron Lett. 1989, 30, 2705-2706. (j) Hutton, J. Synth. Commun. 1979, 9, 483-486. (k) Kowalski, C.; Creary, X.; Rollin, A. J.; Burke, M. C. J. Org. Chem. 1978, 43, 2601-2608. (l) Takezawa, N.; Kobayashi, H. Chem. Lett. 1977, 123- 126. (m) Doering, W. von E.; Aschner, T. C. J. Am. Chem. Soc. 1953, 75, 393-397. (n) Ooi, T.; Miura, T.; Maruoka, K. Angew. Chem., Int. Ed. 1998, 37, 2347-2349.
- (1992) Tetrahedron Lett. , vol.33 , pp. 6279-6282
- Ramig, K.¹ Kuzemko, M.A.² Parrish, D.³ Carpenter, B.K.⁴

9
- 0000496771
- Review: (a) Wilds, A. L. Org. React. 1944, 2, 178-223. (b) de Graauw, C. F.; Peters, J. A.; van Bekkum, H.; Huskens, J. Synthesis 1994, 1007-1017. (c) Takahashi, K.; Shibagaki, M.; Kuno, H.; Matsushita, H. Shokubai 1995, 37, 23-27 and references therein. Also see: (d) Knauer, B.; Krohn, K. Liebigs Ann. 1995, 677-683. (e) Krohn, K.; Knauer, B. Liebigs Ann. 1995, 1347-1351. (f) Castellani, C. B.; Carugo, O.; Perotti, A.; Sacchi, D.; Invernizzi, A. G.; Vidari, G. J. Mol. Catal. 1993, 85, 65- 74. (g) Strickler, J. R.; Bruck, M. A.; Wexler, P. A.; Wigley, D. E. Organometallics 1990, 9, 266-273. (h) Ramig, K.; Kuzemko, M. A.; Parrish, D.; Carpenter, B. K. Tetrahedron Lett. 1992, 33, 6279-6282. (i) Kaspar, J.; Trovarelli, A.; Lenarda, M.; Graziani, M. Tetrahedron Lett. 1989, 30, 2705-2706. (j) Hutton, J. Synth. Commun. 1979, 9, 483-486. (k) Kowalski, C.; Creary, X.; Rollin, A. J.; Burke, M. C. J. Org. Chem. 1978, 43, 2601-2608. (l) Takezawa, N.; Kobayashi, H. Chem. Lett. 1977, 123- 126. (m) Doering, W. von E.; Aschner, T. C. J. Am. Chem. Soc. 1953, 75, 393-397. (n) Ooi, T.; Miura, T.; Maruoka, K. Angew. Chem., Int. Ed. 1998, 37, 2347-2349.
- (1989) Tetrahedron Lett. , vol.30 , pp. 2705-2706
- Kaspar, J.¹ Trovarelli, A.² Lenarda, M.³ Graziani, M.⁴

10
- 84972811631
- Review: (a) Wilds, A. L. Org. React. 1944, 2, 178-223. (b) de Graauw, C. F.; Peters, J. A.; van Bekkum, H.; Huskens, J. Synthesis 1994, 1007-1017. (c) Takahashi, K.; Shibagaki, M.; Kuno, H.; Matsushita, H. Shokubai 1995, 37, 23-27 and references therein. Also see: (d) Knauer, B.; Krohn, K. Liebigs Ann. 1995, 677-683. (e) Krohn, K.; Knauer, B. Liebigs Ann. 1995, 1347-1351. (f) Castellani, C. B.; Carugo, O.; Perotti, A.; Sacchi, D.; Invernizzi, A. G.; Vidari, G. J. Mol. Catal. 1993, 85, 65- 74. (g) Strickler, J. R.; Bruck, M. A.; Wexler, P. A.; Wigley, D. E. Organometallics 1990, 9, 266-273. (h) Ramig, K.; Kuzemko, M. A.; Parrish, D.; Carpenter, B. K. Tetrahedron Lett. 1992, 33, 6279-6282. (i) Kaspar, J.; Trovarelli, A.; Lenarda, M.; Graziani, M. Tetrahedron Lett. 1989, 30, 2705-2706. (j) Hutton, J. Synth. Commun. 1979, 9, 483-486. (k) Kowalski, C.; Creary, X.; Rollin, A. J.; Burke, M. C. J. Org. Chem. 1978, 43, 2601-2608. (l) Takezawa, N.; Kobayashi, H. Chem. Lett. 1977, 123- 126. (m) Doering, W. von E.; Aschner, T. C. J. Am. Chem. Soc. 1953, 75, 393-397. (n) Ooi, T.; Miura, T.; Maruoka, K. Angew. Chem., Int. Ed. 1998, 37, 2347-2349.
- (1979) Synth. Commun. , vol.9 , pp. 483-486
- Hutton, J.¹

11
- 0000813335
- Review: (a) Wilds, A. L. Org. React. 1944, 2, 178-223. (b) de Graauw, C. F.; Peters, J. A.; van Bekkum, H.; Huskens, J. Synthesis 1994, 1007-1017. (c) Takahashi, K.; Shibagaki, M.; Kuno, H.; Matsushita, H. Shokubai 1995, 37, 23-27 and references therein. Also see: (d) Knauer, B.; Krohn, K. Liebigs Ann. 1995, 677-683. (e) Krohn, K.; Knauer, B. Liebigs Ann. 1995, 1347-1351. (f) Castellani, C. B.; Carugo, O.; Perotti, A.; Sacchi, D.; Invernizzi, A. G.; Vidari, G. J. Mol. Catal. 1993, 85, 65- 74. (g) Strickler, J. R.; Bruck, M. A.; Wexler, P. A.; Wigley, D. E. Organometallics 1990, 9, 266-273. (h) Ramig, K.; Kuzemko, M. A.; Parrish, D.; Carpenter, B. K. Tetrahedron Lett. 1992, 33, 6279-6282. (i) Kaspar, J.; Trovarelli, A.; Lenarda, M.; Graziani, M. Tetrahedron Lett. 1989, 30, 2705-2706. (j) Hutton, J. Synth. Commun. 1979, 9, 483-486. (k) Kowalski, C.; Creary, X.; Rollin, A. J.; Burke, M. C. J. Org. Chem. 1978, 43, 2601-2608. (l) Takezawa, N.; Kobayashi, H. Chem. Lett. 1977, 123- 126. (m) Doering, W. von E.; Aschner, T. C. J. Am. Chem. Soc. 1953, 75, 393-397. (n) Ooi, T.; Miura, T.; Maruoka, K. Angew. Chem., Int. Ed. 1998, 37, 2347-2349.
- (1978) J. Org. Chem. , vol.43 , pp. 2601-2608
- Kowalski, C.¹ Creary, X.² Rollin, A.J.³ Burke, M.C.⁴

12
- 0040145387
- Review: (a) Wilds, A. L. Org. React. 1944, 2, 178-223. (b) de Graauw, C. F.; Peters, J. A.; van Bekkum, H.; Huskens, J. Synthesis 1994, 1007-1017. (c) Takahashi, K.; Shibagaki, M.; Kuno, H.; Matsushita, H. Shokubai 1995, 37, 23-27 and references therein. Also see: (d) Knauer, B.; Krohn, K. Liebigs Ann. 1995, 677-683. (e) Krohn, K.; Knauer, B. Liebigs Ann. 1995, 1347-1351. (f) Castellani, C. B.; Carugo, O.; Perotti, A.; Sacchi, D.; Invernizzi, A. G.; Vidari, G. J. Mol. Catal. 1993, 85, 65- 74. (g) Strickler, J. R.; Bruck, M. A.; Wexler, P. A.; Wigley, D. E. Organometallics 1990, 9, 266-273. (h) Ramig, K.; Kuzemko, M. A.; Parrish, D.; Carpenter, B. K. Tetrahedron Lett. 1992, 33, 6279-6282. (i) Kaspar, J.; Trovarelli, A.; Lenarda, M.; Graziani, M. Tetrahedron Lett. 1989, 30, 2705-2706. (j) Hutton, J. Synth. Commun. 1979, 9, 483-486. (k) Kowalski, C.; Creary, X.; Rollin, A. J.; Burke, M. C. J. Org. Chem. 1978, 43, 2601-2608. (l) Takezawa, N.; Kobayashi, H. Chem. Lett. 1977, 123-126. (m) Doering, W. von E.; Aschner, T. C. J. Am. Chem. Soc. 1953, 75, 393-397. (n) Ooi, T.; Miura, T.; Maruoka, K. Angew. Chem., Int. Ed. 1998, 37, 2347-2349.
- (1977) Chem. Lett. , pp. 123-126
- Takezawa, N.¹ Kobayashi, H.²

13
- 0000331808
- Review: (a) Wilds, A. L. Org. React. 1944, 2, 178-223. (b) de Graauw, C. F.; Peters, J. A.; van Bekkum, H.; Huskens, J. Synthesis 1994, 1007-1017. (c) Takahashi, K.; Shibagaki, M.; Kuno, H.; Matsushita, H. Shokubai 1995, 37, 23-27 and references therein. Also see: (d) Knauer, B.; Krohn, K. Liebigs Ann. 1995, 677-683. (e) Krohn, K.; Knauer, B. Liebigs Ann. 1995, 1347-1351. (f) Castellani, C. B.; Carugo, O.; Perotti, A.; Sacchi, D.; Invernizzi, A. G.; Vidari, G. J. Mol. Catal. 1993, 85, 65- 74. (g) Strickler, J. R.; Bruck, M. A.; Wexler, P. A.; Wigley, D. E. Organometallics 1990, 9, 266-273. (h) Ramig, K.; Kuzemko, M. A.; Parrish, D.; Carpenter, B. K. Tetrahedron Lett. 1992, 33, 6279-6282. (i) Kaspar, J.; Trovarelli, A.; Lenarda, M.; Graziani, M. Tetrahedron Lett. 1989, 30, 2705-2706. (j) Hutton, J. Synth. Commun. 1979, 9, 483-486. (k) Kowalski, C.; Creary, X.; Rollin, A. J.; Burke, M. C. J. Org. Chem. 1978, 43, 2601-2608. (l) Takezawa, N.; Kobayashi, H. Chem. Lett. 1977, 123- 126. (m) Doering, W. von E.; Aschner, T. C. J. Am. Chem. Soc. 1953, 75, 393-397. (n) Ooi, T.; Miura, T.; Maruoka, K. Angew. Chem., Int. Ed. 1998, 37, 2347-2349.
- (1953) J. Am. Chem. Soc. , vol.75 , pp. 393-397
- Doering, W.V.E.¹ Aschner, T.C.²

14
- 0032544562
- Review: (a) Wilds, A. L. Org. React. 1944, 2, 178-223. (b) de Graauw, C. F.; Peters, J. A.; van Bekkum, H.; Huskens, J. Synthesis 1994, 1007-1017. (c) Takahashi, K.; Shibagaki, M.; Kuno, H.; Matsushita, H. Shokubai 1995, 37, 23-27 and references therein. Also see: (d) Knauer, B.; Krohn, K. Liebigs Ann. 1995, 677-683. (e) Krohn, K.; Knauer, B. Liebigs Ann. 1995, 1347-1351. (f) Castellani, C. B.; Carugo, O.; Perotti, A.; Sacchi, D.; Invernizzi, A. G.; Vidari, G. J. Mol. Catal. 1993, 85, 65- 74. (g) Strickler, J. R.; Bruck, M. A.; Wexler, P. A.; Wigley, D. E. Organometallics 1990, 9, 266-273. (h) Ramig, K.; Kuzemko, M. A.; Parrish, D.; Carpenter, B. K. Tetrahedron Lett. 1992, 33, 6279-6282. (i) Kaspar, J.; Trovarelli, A.; Lenarda, M.; Graziani, M. Tetrahedron Lett. 1989, 30, 2705-2706. (j) Hutton, J. Synth. Commun. 1979, 9, 483-486. (k) Kowalski, C.; Creary, X.; Rollin, A. J.; Burke, M. C. J. Org. Chem. 1978, 43, 2601-2608. (l) Takezawa, N.; Kobayashi, H. Chem. Lett. 1977, 123- 126. (m) Doering, W. von E.; Aschner, T. C. J. Am. Chem. Soc. 1953, 75, 393-397. (n) Ooi, T.; Miura, T.; Maruoka, K. Angew. Chem., Int. Ed. 1998, 37, 2347-2349.
- (1998) Angew. Chem., Int. Ed. , vol.37 , pp. 2347-2349
- Ooi, T.¹ Miura, T.² Maruoka, K.³

15
- 0025899334
- (a) Ketoepoxide (RCHO Li): Baramee, A.; Chaichit, N.; Intawee, P.; Thebtaranonth, C.; Thebtaranonth, Y. J. Chem. Soc., Chem. Commun. 1991, 1016-1017.
- (1991) J. Chem. Soc., Chem. Commun. , pp. 1016-1017
- Baramee, A.¹ Chaichit, N.² Intawee, P.³ Thebtaranonth, C.⁴ Thebtaranonth, Y.⁵

16
- 0040145389
- 2OLi SET mechanism: Ashby, E. C.; Argyropoulos, J. N. J. Org. Chem. 1986, 51, 3593-3597.
- (1986) J. Org. Chem. , vol.51 , pp. 3593-3597
- Ashby, E.C.¹ Argyropoulos, J.N.²

17
- 33845280639
- (c) Ashby, E. C. Acc. Chem. Res. 1988, 21, 414-421.
- (1988) Acc. Chem. Res. , vol.21 , pp. 414-421
- Ashby, E.C.¹

18
- 0000496771
- (a) MgO: Kaspar, J.; Trovarelli, A.; Lenarda, M.; Graziani, M. Tetrahedron Lett. 1989, 20, 2705-2706.
- (1989) Tetrahedron Lett. , vol.20 , pp. 2705-2706
- Kaspar, J.¹ Trovarelli, A.² Lenarda, M.³ Graziani, M.⁴

19
- 0040145387
- (b) MgO mechanism: Takezawa, N.; Kobayashi, H. Chem. Lett. 1977, 123-126.
- (1977) Chem. Lett. , pp. 123-126
- Takezawa, N.¹ Kobayashi, H.²

20
- 0000331808
- (c) Equilibrium: Doering, W. von E.; Aschner, T. C. J. Am. Chem. Soc. 1953, 75, 393-397.
- (1953) J. Am. Chem. Soc. , vol.75 , pp. 393-397
- Doering, W.V.E.¹ Aschner, T.C.²

21
- 0027693758
- Castellani, C. B.; Carugo, O.; Perotti, A.; Sacchi, D.; Invernizzi, A. G.; Vidari, G. J. Mol. Catal. 1993, 85, 65-74.
- (1993) J. Mol. Catal. , vol.85 , pp. 65-74
- Castellani, C.B.¹ Carugo, O.² Perotti, A.³ Sacchi, D.⁴ Invernizzi, A.G.⁵ Vidari, G.⁶

22
- 0025864813
- (a) Lanthanide alkoxide: Lebrun, A.; Namy, J. L.; Kagan, H. B. Tetrahedron Lett. 1991, 32, 2355-2358.
- (1991) Tetrahedron Lett. , vol.32 , pp. 2355-2358
- Lebrun, A.¹ Namy, J.L.² Kagan, H.B.³

23
- 0002013709
- (b) Okano, T.; Matsuoka, M.; Konishi, H.; Kiji, J. Chem. Lett. 1987, 181-184.
- (1987) Chem. Lett. , pp. 181-184
- Okano, T.¹ Matsuoka, M.² Konishi, H.³ Kiji, J.⁴

24
- 0001143623
- (c) Namy, J. L.; Souppe, J.; Collin, J.; Kagan, H. B. J. Org. Chem. 1984, 49, 2045-2049.
- (1984) J. Org. Chem. , vol.49 , pp. 2045-2049
- Namy, J.L.¹ Souppe, J.² Collin, J.³ Kagan, H.B.⁴

25
- 0013590923
- 2): Evans, D. A.; Hoveyda, A. H. J. Am. Chem. Soc. 1990, 112, 6447-6449.
- (1990) J. Am. Chem. Soc. , vol.112 , pp. 6447-6449
- Evans, D.A.¹ Hoveyda, A.H.²

26
- 0000658203
- (a) Zirconium or Hafnium hydride i-PrOH: Nakano, T.; Umano, S.; Kino, Y.; Ishii, Y.; Ogawa, M. J. Org. Chem. 1988, 53, 3752-3757.
- (1988) J. Org. Chem. , vol.53 , pp. 3752-3757
- Nakano, T.¹ Umano, S.² Kino, Y.³ Ishii, Y.⁴ Ogawa, M.⁵

27
- 33845376548
- 2; Ishii, Y.; Nakano, T.; Inada, A.; Kishigami, Y.; Sakurai, K.; Ogawa, M. J. Org. Chem. 1986, 51, 240-242.
- (1986) J. Org. Chem. , vol.51 , pp. 240-242
- Ishii, Y.¹ Nakano, T.² Inada, A.³ Kishigami, Y.⁴ Sakurai, K.⁵ Ogawa, M.⁶

28
- 37049069937
- 4Zr (pyrimidone 3,4-reduction): Hfseggen, T.; Rise, F.; Undheim, K. J. Chem. Soc., Perkin Trans. 1 1986, 849-850.
- (1986) J. Chem. Soc., Perkin Trans. 1 , vol.1 , pp. 849-850
- Hfseggen, T.¹ Rise, F.² Undheim, K.³

29
- 84988087920
- 4-1-(4-dimethylaminophenyl)-ethanol: Knauer, B.; Krohn, K. Liebigs Ann. 1995, 677-683.
- (1995) Liebigs Ann. , pp. 677-683
- Knauer, B.¹ Krohn, K.²

30
- 0025208715
- Tantalum(V): Strickler, J. R.; Bruck, M. A.; Wexler, P. A.; Wigley, D. E. Organometallics 1990, 9, 266-273.
- (1990) Organometallics , vol.9 , pp. 266-273
- Strickler, J.R.¹ Bruck, M.A.² Wexler, P.A.³ Wigley, D.E.⁴

31
- 0005140019
- Chiral Grignard reagent: (a) Streitweiser, A., Jr.; Wolfe, J. R.; Schaeffer, W. D. Tetrahedron 1959, 6, 338-344. (b) Foley, W. M.; Welch, F. J.; La Combe, E. M.; Mosher, H. S. J. Am. Chem. Soc. 1959, 81, 2779- 2784. (c) MacLeod, R.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 876-880. (d) Burrows, E. P.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 880-885. (e) Birtwistle, J. S.; Lee, K.; Morrison, J. D.; Sanderson, W. A.; Mosher, H. S. J. Org. Chem. 1964, 29, 37-40. Chiral aluminum alkoxide: (f) Doering, W. von E.; Young. R. W. J. Am. Chem. Soc. 1950, 72, 631. (g) Jackman, L. M.; Mills, J. A.; Shannon, J. S. J. Am. Chem. Soc. 1950, 72, 4814-4815. (h) Newman, P.; Rutkin, P.; Mislow, K. J. Am. Chem. Soc. 1958, 80, 465-473. (i) Nasipuri, D.; Sarker, G. J. Indian Chem. Soc. 1967, 44, 165-166. (j) Nasipuri, D.; Sarker, G.; Ghosh C. K. Tetrahedron Lett. 1967, 5189-5192. (k) Fles, D.; Majhofer, B.; Kovac, M. Tetrahedron 1968, 24, 3053-3057.
- (1959) Tetrahedron , vol.6 , pp. 338-344
- Streitweiser A., Jr.¹ Wolfe, J.R.² Schaeffer, W.D.³

32
- 0013056652
- Chiral Grignard reagent: (a) Streitweiser, A., Jr.; Wolfe, J. R.; Schaeffer, W. D. Tetrahedron 1959, 6, 338-344. (b) Foley, W. M.; Welch, F. J.; La Combe, E. M.; Mosher, H. S. J. Am. Chem. Soc. 1959, 81, 2779- 2784. (c) MacLeod, R.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 876-880. (d) Burrows, E. P.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 880-885. (e) Birtwistle, J. S.; Lee, K.; Morrison, J. D.; Sanderson, W. A.; Mosher, H. S. J. Org. Chem. 1964, 29, 37-40. Chiral aluminum alkoxide: (f) Doering, W. von E.; Young. R. W. J. Am. Chem. Soc. 1950, 72, 631. (g) Jackman, L. M.; Mills, J. A.; Shannon, J. S. J. Am. Chem. Soc. 1950, 72, 4814-4815. (h) Newman, P.; Rutkin, P.; Mislow, K. J. Am. Chem. Soc. 1958, 80, 465-473. (i) Nasipuri, D.; Sarker, G. J. Indian Chem. Soc. 1967, 44, 165-166. (j) Nasipuri, D.; Sarker, G.; Ghosh C. K. Tetrahedron Lett. 1967, 5189-5192. (k) Fles, D.; Majhofer, B.; Kovac, M. Tetrahedron 1968, 24, 3053-3057.
- (1959) J. Am. Chem. Soc. , vol.81 , pp. 2779-2784
- Foley, W.M.¹ Welch, F.J.² La Combe, E.M.³ Mosher, H.S.⁴

33
- 0011246353
- Chiral Grignard reagent: (a) Streitweiser, A., Jr.; Wolfe, J. R.; Schaeffer, W. D. Tetrahedron 1959, 6, 338-344. (b) Foley, W. M.; Welch, F. J.; La Combe, E. M.; Mosher, H. S. J. Am. Chem. Soc. 1959, 81, 2779- 2784. (c) MacLeod, R.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 876-880. (d) Burrows, E. P.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 880-885. (e) Birtwistle, J. S.; Lee, K.; Morrison, J. D.; Sanderson, W. A.; Mosher, H. S. J. Org. Chem. 1964, 29, 37-40. Chiral aluminum alkoxide: (f) Doering, W. von E.; Young. R. W. J. Am. Chem. Soc. 1950, 72, 631. (g) Jackman, L. M.; Mills, J. A.; Shannon, J. S. J. Am. Chem. Soc. 1950, 72, 4814-4815. (h) Newman, P.; Rutkin, P.; Mislow, K. J. Am. Chem. Soc. 1958, 80, 465-473. (i) Nasipuri, D.; Sarker, G. J. Indian Chem. Soc. 1967, 44, 165-166. (j) Nasipuri, D.; Sarker, G.; Ghosh C. K. Tetrahedron Lett. 1967, 5189-5192. (k) Fles, D.; Majhofer, B.; Kovac, M. Tetrahedron 1968, 24, 3053-3057.
- (1960) J. Am. Chem. Soc. , vol.82 , pp. 876-880
- MacLeod, R.¹ Welch, F.J.² Mosher, H.S.³

34
- 0007100604
- Chiral Grignard reagent: (a) Streitweiser, A., Jr.; Wolfe, J. R.; Schaeffer, W. D. Tetrahedron 1959, 6, 338-344. (b) Foley, W. M.; Welch, F. J.; La Combe, E. M.; Mosher, H. S. J. Am. Chem. Soc. 1959, 81, 2779- 2784. (c) MacLeod, R.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 876-880. (d) Burrows, E. P.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 880-885. (e) Birtwistle, J. S.; Lee, K.; Morrison, J. D.; Sanderson, W. A.; Mosher, H. S. J. Org. Chem. 1964, 29, 37-40. Chiral aluminum alkoxide: (f) Doering, W. von E.; Young. R. W. J. Am. Chem. Soc. 1950, 72, 631. (g) Jackman, L. M.; Mills, J. A.; Shannon, J. S. J. Am. Chem. Soc. 1950, 72, 4814-4815. (h) Newman, P.; Rutkin, P.; Mislow, K. J. Am. Chem. Soc. 1958, 80, 465-473. (i) Nasipuri, D.; Sarker, G. J. Indian Chem. Soc. 1967, 44, 165-166. (j) Nasipuri, D.; Sarker, G.; Ghosh C. K. Tetrahedron Lett. 1967, 5189-5192. (k) Fles, D.; Majhofer, B.; Kovac, M. Tetrahedron 1968, 24, 3053-3057.
- (1960) J. Am. Chem. Soc. , vol.82 , pp. 880-885
- Burrows, E.P.¹ Welch, F.J.² Mosher, H.S.³

35
- 0040145388
- Chiral Grignard reagent: (a) Streitweiser, A., Jr.; Wolfe, J. R.; Schaeffer, W. D. Tetrahedron 1959, 6, 338-344. (b) Foley, W. M.; Welch, F. J.; La Combe, E. M.; Mosher, H. S. J. Am. Chem. Soc. 1959, 81, 2779- 2784. (c) MacLeod, R.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 876-880. (d) Burrows, E. P.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 880-885. (e) Birtwistle, J. S.; Lee, K.; Morrison, J. D.; Sanderson, W. A.; Mosher, H. S. J. Org. Chem. 1964, 29, 37-40. Chiral aluminum alkoxide: (f) Doering, W. von E.; Young. R. W. J. Am. Chem. Soc. 1950, 72, 631. (g) Jackman, L. M.; Mills, J. A.; Shannon, J. S. J. Am. Chem. Soc. 1950, 72, 4814-4815. (h) Newman, P.; Rutkin, P.; Mislow, K. J. Am. Chem. Soc. 1958, 80, 465-473. (i) Nasipuri, D.; Sarker, G. J. Indian Chem. Soc. 1967, 44, 165-166. (j) Nasipuri, D.; Sarker, G.; Ghosh C. K. Tetrahedron Lett. 1967, 5189-5192. (k) Fles, D.; Majhofer, B.; Kovac, M. Tetrahedron 1968, 24, 3053-3057.
- (1964) J. Org. Chem. , vol.29 , pp. 37-40
- Birtwistle, J.S.¹ Lee, K.² Morrison, J.D.³ Sanderson, W.A.⁴ Mosher, H.S.⁵

36
- 0005169384
- Chiral Grignard reagent: (a) Streitweiser, A., Jr.; Wolfe, J. R.; Schaeffer, W. D. Tetrahedron 1959, 6, 338-344. (b) Foley, W. M.; Welch, F. J.; La Combe, E. M.; Mosher, H. S. J. Am. Chem. Soc. 1959, 81, 2779- 2784. (c) MacLeod, R.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 876-880. (d) Burrows, E. P.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 880-885. (e) Birtwistle, J. S.; Lee, K.; Morrison, J. D.; Sanderson, W. A.; Mosher, H. S. J. Org. Chem. 1964, 29, 37-40. Chiral aluminum alkoxide: (f) Doering, W. von E.; Young. R. W. J. Am. Chem. Soc. 1950, 72, 631. (g) Jackman, L. M.; Mills, J. A.; Shannon, J. S. J. Am. Chem. Soc. 1950, 72, 4814-4815. (h) Newman, P.; Rutkin, P.; Mislow, K. J. Am. Chem. Soc. 1958, 80, 465-473. (i) Nasipuri, D.; Sarker, G. J. Indian Chem. Soc. 1967, 44, 165-166. (j) Nasipuri, D.; Sarker, G.; Ghosh C. K. Tetrahedron Lett. 1967, 5189-5192. (k) Fles, D.; Majhofer, B.; Kovac, M. Tetrahedron 1968, 24, 3053-3057.
- (1950) J. Am. Chem. Soc. , vol.72 , pp. 631
- Doering, W.V.E.¹ Young, R.W.²

37
- 0038961104
- Chiral Grignard reagent: (a) Streitweiser, A., Jr.; Wolfe, J. R.; Schaeffer, W. D. Tetrahedron 1959, 6, 338-344. (b) Foley, W. M.; Welch, F. J.; La Combe, E. M.; Mosher, H. S. J. Am. Chem. Soc. 1959, 81, 2779- 2784. (c) MacLeod, R.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 876-880. (d) Burrows, E. P.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 880-885. (e) Birtwistle, J. S.; Lee, K.; Morrison, J. D.; Sanderson, W. A.; Mosher, H. S. J. Org. Chem. 1964, 29, 37-40. Chiral aluminum alkoxide: (f) Doering, W. von E.; Young. R. W. J. Am. Chem. Soc. 1950, 72, 631. (g) Jackman, L. M.; Mills, J. A.; Shannon, J. S. J. Am. Chem. Soc. 1950, 72, 4814-4815. (h) Newman, P.; Rutkin, P.; Mislow, K. J. Am. Chem. Soc. 1958, 80, 465-473. (i) Nasipuri, D.; Sarker, G. J. Indian Chem. Soc. 1967, 44, 165-166. (j) Nasipuri, D.; Sarker, G.; Ghosh C. K. Tetrahedron Lett. 1967, 5189-5192. (k) Fles, D.; Majhofer, B.; Kovac, M. Tetrahedron 1968, 24, 3053-3057.
- (1950) J. Am. Chem. Soc. , vol.72 , pp. 4814-4815
- Jackman, L.M.¹ Mills, J.A.² Shannon, J.S.³

38
- 0000715208
- Chiral Grignard reagent: (a) Streitweiser, A., Jr.; Wolfe, J. R.; Schaeffer, W. D. Tetrahedron 1959, 6, 338-344. (b) Foley, W. M.; Welch, F. J.; La Combe, E. M.; Mosher, H. S. J. Am. Chem. Soc. 1959, 81, 2779- 2784. (c) MacLeod, R.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 876-880. (d) Burrows, E. P.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 880-885. (e) Birtwistle, J. S.; Lee, K.; Morrison, J. D.; Sanderson, W. A.; Mosher, H. S. J. Org. Chem. 1964, 29, 37-40. Chiral aluminum alkoxide: (f) Doering, W. von E.; Young. R. W. J. Am. Chem. Soc. 1950, 72, 631. (g) Jackman, L. M.; Mills, J. A.; Shannon, J. S. J. Am. Chem. Soc. 1950, 72, 4814-4815. (h) Newman, P.; Rutkin, P.; Mislow, K. J. Am. Chem. Soc. 1958, 80, 465-473. (i) Nasipuri, D.; Sarker, G. J. Indian Chem. Soc. 1967, 44, 165-166. (j) Nasipuri, D.; Sarker, G.; Ghosh C. K. Tetrahedron Lett. 1967, 5189-5192. (k) Fles, D.; Majhofer, B.; Kovac, M. Tetrahedron 1968, 24, 3053-3057.
- (1958) J. Am. Chem. Soc. , vol.80 , pp. 465-473
- Newman, P.¹ Rutkin, P.² Mislow, K.³

39
- 0000292138
- Chiral Grignard reagent: (a) Streitweiser, A., Jr.; Wolfe, J. R.; Schaeffer, W. D. Tetrahedron 1959, 6, 338-344. (b) Foley, W. M.; Welch, F. J.; La Combe, E. M.; Mosher, H. S. J. Am. Chem. Soc. 1959, 81, 2779- 2784. (c) MacLeod, R.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 876-880. (d) Burrows, E. P.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 880-885. (e) Birtwistle, J. S.; Lee, K.; Morrison, J. D.; Sanderson, W. A.; Mosher, H. S. J. Org. Chem. 1964, 29, 37-40. Chiral aluminum alkoxide: (f) Doering, W. von E.; Young. R. W. J. Am. Chem. Soc. 1950, 72, 631. (g) Jackman, L. M.; Mills, J. A.; Shannon, J. S. J. Am. Chem. Soc. 1950, 72, 4814-4815. (h) Newman, P.; Rutkin, P.; Mislow, K. J. Am. Chem. Soc. 1958, 80, 465-473. (i) Nasipuri, D.; Sarker, G. J. Indian Chem. Soc. 1967, 44, 165-166. (j) Nasipuri, D.; Sarker, G.; Ghosh C. K. Tetrahedron Lett. 1967, 5189-5192. (k) Fles, D.; Majhofer, B.; Kovac, M. Tetrahedron 1968, 24, 3053-3057.
- (1967) J. Indian Chem. Soc. , vol.44 , pp. 165-166
- Nasipuri, D.¹ Sarker, G.²

40
- 0038961106
- Chiral Grignard reagent: (a) Streitweiser, A., Jr.; Wolfe, J. R.; Schaeffer, W. D. Tetrahedron 1959, 6, 338-344. (b) Foley, W. M.; Welch, F. J.; La Combe, E. M.; Mosher, H. S. J. Am. Chem. Soc. 1959, 81, 2779- 2784. (c) MacLeod, R.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 876-880. (d) Burrows, E. P.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 880-885. (e) Birtwistle, J. S.; Lee, K.; Morrison, J. D.; Sanderson, W. A.; Mosher, H. S. J. Org. Chem. 1964, 29, 37-40. Chiral aluminum alkoxide: (f) Doering, W. von E.; Young. R. W. J. Am. Chem. Soc. 1950, 72, 631. (g) Jackman, L. M.; Mills, J. A.; Shannon, J. S. J. Am. Chem. Soc. 1950, 72, 4814-4815. (h) Newman, P.; Rutkin, P.; Mislow, K. J. Am. Chem. Soc. 1958, 80, 465-473. (i) Nasipuri, D.; Sarker, G. J. Indian Chem. Soc. 1967, 44, 165-166. (j) Nasipuri, D.; Sarker, G.; Ghosh C. K. Tetrahedron Lett. 1967, 5189-5192. (k) Fles, D.; Majhofer, B.; Kovac, M. Tetrahedron 1968, 24, 3053-3057.
- (1967) Tetrahedron Lett. , pp. 5189-5192
- Nasipuri, D.¹ Sarker, G.² Ghosh, C.K.³

41
- 0038961105
- Chiral Grignard reagent: (a) Streitweiser, A., Jr.; Wolfe, J. R.; Schaeffer, W. D. Tetrahedron 1959, 6, 338-344. (b) Foley, W. M.; Welch, F. J.; La Combe, E. M.; Mosher, H. S. J. Am. Chem. Soc. 1959, 81, 2779- 2784. (c) MacLeod, R.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 876-880. (d) Burrows, E. P.; Welch, F. J.; Mosher, H. S. J. Am. Chem. Soc. 1960, 82, 880-885. (e) Birtwistle, J. S.; Lee, K.; Morrison, J. D.; Sanderson, W. A.; Mosher, H. S. J. Org. Chem. 1964, 29, 37-40. Chiral aluminum alkoxide: (f) Doering, W. von E.; Young. R. W. J. Am. Chem. Soc. 1950, 72, 631. (g) Jackman, L. M.; Mills, J. A.; Shannon, J. S. J. Am. Chem. Soc. 1950, 72, 4814-4815. (h) Newman, P.; Rutkin, P.; Mislow, K. J. Am. Chem. Soc. 1958, 80, 465-473. (i) Nasipuri, D.; Sarker, G. J. Indian Chem. Soc. 1967, 44, 165-166. (j) Nasipuri, D.; Sarker, G.; Ghosh C. K. Tetrahedron Lett. 1967, 5189-5192. (k) Fles, D.; Majhofer, B.; Kovac, M. Tetrahedron 1968, 24, 3053-3057.
- (1968) Tetrahedron , vol.24 , pp. 3053-3057
- Fles, D.¹ Majhofer, B.² Kovac, M.³

42
- 0005227093
- (a) Zhou, W. S.; Zhou, X. M.; Ni, Y. Acta Chim. Sin. 1984, 42, 706-709.
- (1984) Acta Chim. Sin. , vol.42 , pp. 706-709
- Zhou, W.S.¹ Zhou, X.M.² Ni, Y.³

43
- 0005143957
- (b) Zhou, W. S.; Wang, Z. Q.; Zhang, H.; Fei, R. Y.; Zhuang, Z. P. Acta Chim. Sin. 1985, 43, 168-173.
- (1985) Acta Chim. Sin. , vol.43 , pp. 168-173
- Zhou, W.S.¹ Wang, Z.Q.² Zhang, H.³ Fei, R.Y.⁴ Zhuang, Z.P.⁵

44
- 1542635938
- (c) Ishihara, K.; Hanaki, N.; Yamamoto, H. J. Am. Chem. Soc. 1991, 113, 7074-7075.
- (1991) J. Am. Chem. Soc. , vol.113 , pp. 7074-7075
- Ishihara, K.¹ Hanaki, N.² Yamamoto, H.³

45
- 85033185570
- (d) Ishihara, K.; Hanaki, N.; Yamamoto, H. Synlett 1993, 127-129.
- (1993) Synlett , pp. 127-129
- Ishihara, K.¹ Hanaki, N.² Yamamoto, H.³

46
- 0000012967
- (e) Molander, G. A.; McKie, J. A. J. Am. Chem. Soc. 1993, 115, 5821-5822.
- (1993) J. Am. Chem. Soc. , vol.115 , pp. 5821-5822
- Molander, G.A.¹ McKie, J.A.²

47
- 0025899334
- (f) Baramee, A.; Chaichit, N.; Intawee, P.; Thebtaranonth, C.; Thebtaranonth, Y. J. Chem. Soc., Chem. Commun. 1991, 1016-1017.
- (1991) J. Chem. Soc., Chem. Commun. , pp. 1016-1017
- Baramee, A.¹ Chaichit, N.² Intawee, P.³ Thebtaranonth, C.⁴ Thebtaranonth, Y.⁵

48
- 0002320348
- (g) Fujita, M.; Takarada, Y.; Sugimura, T.; Tai, A. J. Chem. Soc., Chem. Commun. 1997, 1631-1632.
- (1997) J. Chem. Soc., Chem. Commun. , pp. 1631-1632
- Fujita, M.¹ Takarada, Y.² Sugimura, T.³ Tai, A.⁴

49
- 0013590923
- Also see intramolecular Tishchenko reduction: (h) Evans, D. A.; Hoveyda, A. H. J. Am. Chem. Soc. 1990, 112, 6447-6449.
- (1990) J. Am. Chem. Soc. , vol.112 , pp. 6447-6449
- Evans, D.A.¹ Hoveyda, A.H.²

50
- 0025162084
- Also see hydride shift in a rigid cyclic system: (i) Sherrod, M. J.; Menger, F. M. Tetrahedron Lett. 1990, 31, 459-462.
- (1990) Tetrahedron Lett. , vol.31 , pp. 459-462
- Sherrod, M.J.¹ Menger, F.M.²

51
- 0342875346
- (j) Mills, O. S.; Watt, C. I. F.; Whitworth, S. M. J. Chem. Soc., Perkin Trans. 2 1990, 487-497.
- (1990) J. Chem. Soc., Perkin Trans. 2 , vol.2 , pp. 487-497
- Mills, O.S.¹ Watt, C.I.F.² Whitworth, S.M.³

52
- 0001432032
- (k) Denmark, S. E.; Henke, B. R. J. Am. Chem. Soc. 1991, 113, 2177-2194.
- (1991) J. Am. Chem. Soc. , vol.113 , pp. 2177-2194
- Denmark, S.E.¹ Henke, B.R.²

53
- 0001767033
- Evans, D. A.; Nelson, S. G.; Gagné, M. R.; Muci, A. R. J. Am. Chem. Soc. 1993, 115, 9800-9801.
- (1993) J. Am. Chem. Soc. , vol.115 , pp. 9800-9801
- Evans, D.A.¹ Nelson, S.G.² Gagné, M.R.³ Muci, A.R.⁴

54
- 0001040853
- (a) Hashiguchi, S.; Fujii, A.; Takehara, J.; Ikariya, T.; Noyori, R. J. Am. Chem. Soc. 1995, 117, 7562-7563.
- (1995) J. Am. Chem. Soc. , vol.117 , pp. 7562-7563
- Hashiguchi, S.¹ Fujii, A.² Takehara, J.³ Ikariya, T.⁴ Noyori, R.⁵

55
- 0029879373
- (b) Fujii, A.; Hashiguchi, S.; Uematsu, N.; Ikariya, T.; Noyori, R. J. Am. Chem. Soc. 1996, 118, 2521-2522.
- (1996) J. Am. Chem. Soc. , vol.118 , pp. 2521-2522
- Fujii, A.¹ Hashiguchi, S.² Uematsu, N.³ Ikariya, T.⁴ Noyori, R.⁵

56
- 3242664987
- (c) Gao, J.-X.; Ikariya, T.; Noyori, R. Organometallics 1996, 15, 1087-1089.
- (1996) Organometallics , vol.15 , pp. 1087-1089
- Gao, J.-X.¹ Ikariya, T.² Noyori, R.³

57
- 0031321853
- (d) Inoue, S.; Nomura, K.; Hashiguchi, S.; Noyori, R.; Izawa, Y. Chem. Lett. 1997, 957-958.
- (1997) Chem. Lett. , pp. 957-958
- Inoue, S.¹ Nomura, K.² Hashiguchi, S.³ Noyori, R.⁴ Izawa, Y.⁵

58
- 0030883527
- (e) Matsumura, K.; Hashiguchi, S.; Ikariya, T.; Noyori, R. J. Am. Chem. Soc. 1997, 119, 8738-8739.
- (1997) J. Am. Chem. Soc. , vol.119 , pp. 8738-8739
- Matsumura, K.¹ Hashiguchi, S.² Ikariya, T.³ Noyori, R.⁴

59
- 85015578054
- (f) Also see BINAP-diamine-ruthenium catalyst: Ohkuma, T.; Ooka, H.; Hashiguchi, S.; Ikariya, T.; Noyori, R. J. Am. Chem. Soc. 1995, 117, 2675-2676.
- (1995) J. Am. Chem. Soc. , vol.117 , pp. 2675-2676
- Ohkuma, T.¹ Ooka, H.² Hashiguchi, S.³ Ikariya, T.⁴ Noyori, R.⁵

60
- 0030453050
- For a preliminary communication see: Nishide, K.; Shigeta, Y.; Obata, K.; Node, M. J. Am. Chem. Soc. 1996, 118, 13103-13104.
- (1996) J. Am. Chem. Soc. , vol.118 , pp. 13103-13104
- Nishide, K.¹ Shigeta, Y.² Obata, K.³ Node, M.⁴

61
- 0001073486
- Eliel, E. L.; Frazee, W. J. J. Org. Chem. 1979, 44, 3598-3599.
- (1979) J. Org. Chem. , vol.44 , pp. 3598-3599
- Eliel, E.L.¹ Frazee, W.J.²

62
- 0000184150
- (a) Eliel, E. L.; Lynch, J. E. Tetrahedron Lett. 1981, 22, 2855-2858.
- (1981) Tetrahedron Lett. , vol.22 , pp. 2855-2858
- Eliel, E.L.¹ Lynch, J.E.²

63
- 0021436266
- (b) Lynch, J. E.; Eliel, E. L. J. Am. Chem. Soc. 1984, 106, 2943-2948.
- (1984) J. Am. Chem. Soc. , vol.106 , pp. 2943-2948
- Lynch, J.E.¹ Eliel, E.L.²

64
- 0013351217
- (c) Eliel, E. L.; Lynch, J. E.; Kume, F.; Frye, S. V. Org. Synth. 1987, 65, 214-223.
- (1987) Org. Synth. , vol.65 , pp. 214-223
- Eliel, E.L.¹ Lynch, J.E.² Kume, F.³ Frye, S.V.⁴

65
- 0030009687
- (a) Nishide, K.; Shigeta, Y.; Obata, K.; Inoue, T.; Node, M. Tetrahedron Lett. 1996, 37, 2271-2274.
- (1996) Tetrahedron Lett. , vol.37 , pp. 2271-2274
- Nishide, K.¹ Shigeta, Y.² Obata, K.³ Inoue, T.⁴ Node, M.⁵

66
- 0030863986
- (b) Node, M.; Nishide, K.; Shigeta, Y.; Obata, K.; Shiraki, H.; Kunishige, H. Tetrahedron 1997, 53, 12883-12894.
- (1997) Tetrahedron , vol.53 , pp. 12883-12894
- Node, M.¹ Nishide, K.² Shigeta, Y.³ Obata, K.⁴ Shiraki, H.⁵ Kunishige, H.⁶

67
- 1542735933
- (a) Butlin, R. J.; Linney, I. D.; Mahon, M. F.; Tye, H.; Wills, M. J. Chem. Soc., Perkin Trans. 1 1996, 95-105.
- (1996) J. Chem. Soc., Perkin Trans. 1 , vol.1 , pp. 95-105
- Butlin, R.J.¹ Linney, I.D.² Mahon, M.F.³ Tye, H.⁴ Wills, M.⁵

68
- 0032513159
- (b) García, M. M. C.; Rauno, J. L. G.; Castro, A. M. M.; Ramos, J. H. R.; Fernández, I. Tetrahedron: Asymmetry 1998, 9, 859-864.
- (1998) Tetrahedron: Asymmetry , vol.9 , pp. 859-864
- García, M.M.C.¹ Rauno, J.L.G.² Castro, A.M.M.³ Ramos, J.H.R.⁴ Fernández, I.⁵

69
- 2142858450
- Ohtani, I.; Kusumi, T.; Kashman, Y.; Kakisawa, H. J. Am. Chem. Soc. 1991, 113, 4092-4096.
- (1991) J. Am. Chem. Soc. , vol.113 , pp. 4092-4096
- Ohtani, I.¹ Kusumi, T.² Kashman, Y.³ Kakisawa, H.⁴

70
- 37049069261
- Barrett, A. G. M.; Kamimura, A. J. Chem. Soc., Chem. Commun. 1995, 1754-1755.
- (1995) J. Chem. Soc., Chem. Commun. , pp. 1754-1755
- Barrett, A.G.M.¹ Kamimura, A.²

71
- 0006699075
- (a) Starowieyski, K. B.; Pasynkiewicz, S.; Skowroñska-Ptasiñska, M. J. Organomet. Chem. 1975, 90, C43-C44.
- (1975) J. Organomet. Chem. , vol.90
- Starowieyski, K.B.¹ Pasynkiewicz, S.² Skowroñska-Ptasiñska, M.³

72
- 0001588908
- (b) Maruoka, K.; Itoh, T.; Yamamoto, H. J. Am. Chem. Soc. 1985, 107, 4573-4576.
- (1985) J. Am. Chem. Soc. , vol.107 , pp. 4573-4576
- Maruoka, K.¹ Itoh, T.² Yamamoto, H.³

73
- 0030109482
- (c) Ooi, T.; Maruoka, K. J. Synth. Org. Chem. Jpn. 1996, 54, 200-211.
- (1996) J. Synth. Org. Chem. Jpn. , vol.54 , pp. 200-211
- Ooi, T.¹ Maruoka, K.²

74
- 0003665716
- [1,7] sigmatropic rearrangement of conjugated trienes: for example: (a) Baldwin, J. E.; Reddy, V. P. J. Am. Chem. Soc. 1988, 110, 8223-8228. (b) Baldwin, J. E.; Reddy, V. P. J. Am. Chem. Soc. 1987, 109, 8051-8056.
- (1988) J. Am. Chem. Soc. , vol.110 , pp. 8223-8228
- Baldwin, J.E.¹ Reddy, V.P.²

75
- 0000845113
- [1,7] sigmatropic rearrangement of conjugated trienes: for example: (a) Baldwin, J. E.; Reddy, V. P. J. Am. Chem. Soc. 1988, 110, 8223-8228. (b) Baldwin, J. E.; Reddy, V. P. J. Am. Chem. Soc. 1987, 109, 8051-8056.
- (1987) J. Am. Chem. Soc. , vol.109 , pp. 8051-8056
- Baldwin, J.E.¹ Reddy, V.P.²

76
- 0002923489
- (a) Noyori, R.; Tokunaga, M.; Kitamura, M. Bull. Chem. Soc. Jpn. 1995, 68, 36-56.
- (1995) Bull. Chem. Soc. Jpn. , vol.68 , pp. 36-56
- Noyori, R.¹ Tokunaga, M.² Kitamura, M.³

77
- 0029103383
- and references therein
- (b) Ward, R. S. Tetrahedron: Asymmetry 1995, 6, 1475-1490,and references therein.
- (1995) Tetrahedron: Asymmetry , vol.6 , pp. 1475-1490
- Ward, R.S.¹

78
- 0021510134
- (a) Noyori, R.; Tomino, M.; Yamada, M.; Nishizawa, M. J. Am. Chem. Soc. 1984, 106, 6717-6725.
- (1984) J. Am. Chem. Soc. , vol.106 , pp. 6717-6725
- Noyori, R.¹ Tomino, M.² Yamada, M.³ Nishizawa, M.⁴

79
- 0025143597
- (b) Ohkuma, T.; Kitamura, M.; Noyori, R. Tetrahedron Lett. 1990, 31, 5509-5512.
- (1990) Tetrahedron Lett. , vol.31 , pp. 5509-5512
- Ohkuma, T.¹ Kitamura, M.² Noyori, R.³

80
- 0028080269
- (c) Masuya, K.; Tanino, K.; Kuwajima, I. Tetrahedron Lett. 1994, 35, 7965-7968.
- (1994) Tetrahedron Lett. , vol.35 , pp. 7965-7968
- Masuya, K.¹ Tanino, K.² Kuwajima, I.³

81
- 0001590139
- (d) Pirkle, W. H.; Adams, P. E. J. Org. Chem. 1979, 44, 2169.
- (1979) J. Org. Chem. , vol.44 , pp. 2169
- Pirkle, W.H.¹ Adams, P.E.²

82
- 0000147012
- (e) Vigneron, J. P.; Bloy, V. Tetrahedron Lett. 1980, 21, 1735.
- (1980) Tetrahedron Lett. , vol.21 , pp. 1735
- Vigneron, J.P.¹ Bloy, V.²

83
- 0010419953
- (f) Sugai, T.; Mori, K. Agric. Biol. Chem. 1984, 48, 2497-2500.
- (1984) Agric. Biol. Chem. , vol.48 , pp. 2497-2500
- Sugai, T.¹ Mori, K.²

84
- 2542433188
- Carlsen, P. H. J.; Katuki, T.; Martin, V. S.; Sharpless, K. B. J. Org. Chem. 1981, 46, 3936-3938.
- (1981) J. Org. Chem. , vol.46 , pp. 3936-3938
- Carlsen, P.H.J.¹ Katuki, T.² Martin, V.S.³ Sharpless, K.B.⁴

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