Synthesis, characterization, and interaction strengths of difluorocarbene-modified polystyrene-polyisoprene block copolymers

Macromolecules

Volumn 33, Issue 3, 2000, Pages 866-876

  Ren, Yu ^a   Lodge, Timothy P ^a   Hillmyer, Marc A ^a  

^a University of Minnesota   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHARACTERIZATION; CHEMICAL MODIFICATION; FLUORINE COMPOUNDS; MOLECULAR STRUCTURE; MOLECULAR WEIGHT; MORPHOLOGY; ORDER DISORDER TRANSITIONS; POLYISOPRENES; POLYSTYRENES; SYNTHESIS (CHEMICAL); TEMPERATURE; X RAY SCATTERING;

DIFLUOROCARBENE; INTERACTION STRENGTH;

BLOCK COPOLYMERS;

EID: 0034620457     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9917085     Document Type: Article

References (55)

1. Hamley, I. W. The Physics of Block Copolymers; Oxford University Press: Oxford, 1998.
2. Fredrickson, G. H.; Bates, F. S. Annu. Rev. Mater. Sci. 1996, 26, 501.
3. Bates, F. S.; Fredrickson, G. H. Annu. Rev. Phys. Chem. 1990, 41, 525.
4. Matsen, M. W.; Bates, F. S. Macromolecules 1996, 29, 1091.
5. (a) Khandpur, A. K.; Förster, S.; Bates, F. S.; Hamley, I. W.; Ryan, A. J.; Bras, W.; Almdal, K.; Mortensen, K. Macromolecules 1995, 28, 8796.
6. (b) Mai, S. M.; Fairclough, J. P. A.; Terrill, N. J.; Turner, S. C.; Hamley, I. W.; Matsen, M. W.; Ryan, A. J.; Booth, C. Macromolecules 1998, 31, 8110.
7. (c) Hajduk, D. A.; Kossuth, M. B.; Hillmyer, M. A.; Bates, F. S. J. Phys. Chem. B. 1998, 102, 4269.
8. Stone, V. W.; Jonas, A. M.; Legras, R.; Dubois, P.; Jérôme, R. J. Polym. Sci., Polym. Chem. 1999, 37, 233.
9. Iyengar, D. R.; Perutz, S. M.; Dai, C.; Ober, C. K.; Kramer, E. J. Macromolecules 1996, 29, 1229.
10. Wang, S. M.; Tsiang, R. C. C. J. Polym. Sci., Polym. Chem. 1996, 34, 1483.
11. (a) Gehlsen, M. D.; Bates, F. S. Macromolecules 1994, 27, 3611.
12. (b) Kimishima, I.; Jinnai, H.; Hashimoto, T. Macromolecules. 1999, 32, 2585.
13. (c) Adams, J. L.; Quiram, D. J.; Graessley, W. W.; Register, R. A.; Marchand, G. R. Macromolecules 1998, 31, 201.
14. Wang, J.; Mao, G.; Ober, C. K.; Kramer, E. J. Macromolecules 1997, 30, 1906.
15. McClain, J. B.; Betts, D. E.; Canelas, D. A.; Samulski, E. T.; DeSimone, J. M.; Londono, J. D.; Cochran, H. D.; Wignall, G. D.; Chillura-Martino, D.; Triolo, R. Science 1996, 274, 2049.
16. Ren, Y.; Lodge, T. P.; Hillmyer, M. A. J. Am. Chem. Soc. 1998, 120, 6830.
17. Gillman, H.; Cartledge, F. K. J. Organomet. Chem. 1964, 2, 447.
18. Pangborn, A. B.; Giardello, M. A.; Grubbs, R. H.; Rosen, R. K.; Timmers, F. J. Organometallics 1996, 15, 1518.
19. Craig, D.; Regenass, F. A.; Fowler, R. B. J. Org. Chem. 1959, 24, 240.
20. Ndoni, S.; Papadakis, C. M.; Bates, F. S.; Almdal, K. Rev. Sci. Instrum. 1995, 66, 1090.
21. Johnson, A. F.; Worsfold, D. J. J. Polym. Sci., Part A 1965, 3, 449.
22. Some white powder insoluble in THF was found in the solution, and we suspect that it was PTFE oligomers, a possible byproduct from the thermolysis of HFPO. See: Sargeant, P. B. J. Org. Chem. 1970, 35, 678.
23. Gordon, A. J.; Ford, R. A. The Chemist's Companion; John Wiley & Sons: New York, 1972.
24. Brandrup, J.; Immergut, E. H.; Grulke, E. A. Polymer Handbook, 4th ed.; John Wiley & Sons: New York, 1999.
25. (a) Lodge, T. P.; Pan, C.; Jin, X.; Liu, Z.; Zhao, J.; Maurer, W. W.; Bates, F. S. J. Polym. Sci., Polym. Phys. Ed. 1995, 33, 2289.
26. (b) Balsara, N. P.; Perahia, D.; Safinya, C. R.; Tirrell, M.; Lodge, T. P. Macromolecules 1992, 25, 3896.
27. Brahms, D. L. S.; Dailey, W. P. Chem. Rev. 1996, 96, 1585.
28. Kagabu, S.; Saito, K. Tetrahedron Lett. 1988, 29, 675.
29. Likhotvorik, I. R.; Yuan, K.; Brown, D. W.; Krasutsky, P. A.; Smyth, N.; Jones, M. Tetrahedron Lett. 1992, 33, 911.
30. 13C NMR spectroscopic analysis, Cais and co-workers concluded that the insertion of difluorocarbene (generated from a different source) into cis- and trans-polybutadiene takes place randomly. See: Cais, R. E.; Siddiqui, S. Macromolecules 1986, 19, 595.
31. 12
32. 2 modification, the contrast factor between the PS and FPI blocks becomes larger than that between PS and PI. See: Lodge, T. P. Mikrochim. Acta 1994, 116, 1. Foster, M. D. Crit. Rev. Anal. Chem. 1993, 24, 179. Wilson, A. J. C. International Tables for Crystallography; Kluwer Academic Publishers: Dordrecht, 1992; Vol. C.
33. 2 modification, the contrast factor between the PS and FPI blocks becomes larger than that between PS and PI. See: Lodge, T. P. Mikrochim. Acta 1994, 116, 1. Foster, M. D. Crit. Rev. Anal. Chem. 1993, 24, 179. Wilson, A. J. C. International Tables for Crystallography; Kluwer Academic Publishers: Dordrecht, 1992; Vol. C.
34. 2 modification, the contrast factor between the PS and FPI blocks becomes larger than that between PS and PI. See: Lodge, T. P. Mikrochim. Acta 1994, 116, 1. Foster, M. D. Crit. Rev. Anal. Chem. 1993, 24, 179. Wilson, A. J. C. International Tables for Crystallography; Kluwer Academic Publishers: Dordrecht, 1992; Vol. C.
35. Hanley, K. J.; Lodge, T. P. J. Polym. Sci., Polym. Phys. Ed. 1998, 36, 3101.
36. ODT by this method.
37. Leibler, L. Macromolecules 1980, 13, 1602.
38. Fredrickson, G. H.; Helfand, E. J. Chem. Phys. 1987, 87, 697.
39. Semenov, A. N. Sov. Phys. JETP 1985, 61, 773.
40. Hadziioannou, G.; Skoulios, A. Macromolecules 1982, 15, 258.
41. 3 at room temperature from direct mass and volume measurements.
42. See: Fetters, L. J.; et al. In Physical Properties of Polymers Handbook; Mark, J. E., Ed.; American Institute of Physics: Woodbury, New York, 1996.
43. SI.
44. Boothroyd, A. T.; Rennie, A. R.; Wignall, G. D. J. Chem. Phys. 1993, 99, 9135.
45. (a) Paul, D. R.; Barlow, J. W. Polymer 1984, 25, 487.
46. (b) ten Brinke, G.; Karasz, F. E.; MacKnight, W. J. Macromolecules1983, 16, 1827.
47. (c) Kambour, R. P.; Bendler, J. T.; Bopp, R. C. Macromolecules 1983, 16, 753.
48. (d) Sakurai, S.; Jinnai, H.; Hasegawa, H.; Hashimoto, T. Macromolecules 1991, 24, 4839.
49. (e) Sakurai, S.; Izumitani, T.; Hasegawa, H.; Hashimoto, T. Macromolecules 1991, 24, 4844.
50. SI, respectively.
51. Stein, D. J.; Jung, R. H.; Illers, K. H.; Hendus, H. Angew. Makromol. Chem. 1974, 36, 89.
52. Hammer, C. F. Macromolecules 1971, 4, 69.
53. Pfennig, J. L. G.; Keskkula, H.; Barlow, J. W.; Paul, D. R. Macromolecules 1985, 18, 1937.
54. Chapiro, A.; Mankowski, Z.; Schmitt, N. J. Polym. Sci., Polym. Chem. Ed. 1982, 20, 1791.
55. Bottino, A.; Capannelli, G.; Munari, S.; Turturro, A. J. Polym. Sci., Polym. Phys. Ed. 1988, 26, 785.