Unique chains of alternating octahedral and tetrahedral cobalt(II) sites: Crystal structures of the novel chloro-bridged complexes [Co4(μ-Cl)6Cl2(thf)4(MeOH)2](n) and [{Co4(μ-Cl)6Cl2(thf)4(H2O)2}·2THF](n)

Chemical Communications

Volumn , Issue 15, 2000, Pages 1359-1360

  Hierso, Jean Cyrille ^a   Ellis, Dianne D ^b   Spek, Anthony L ^b   Bouwman, Elisabeth ^a   Reedijk, Jan ^a  

^a LEIDEN UNIVERSITY   (Netherlands)

^b UTRECHT UNIVERSITY   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

COBALT COMPLEX;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; CRYSTALLIZATION; STRUCTURE ANALYSIS;

EID: 0034617934     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b003213l     Document Type: Article

References (23)

1. G. R. Clark and G. J. Palenik, Cryst. Struct. Commun., 1979, 8, 261; S. I. Al-Resayes, P. B. Hitchcock and J. F. Nixon, J. Chem. Soc., Chem. Commun., 1991, 78.
2. G. R. Clark and G. J. Palenik, Cryst. Struct. Commun., 1979, 8, 261; S. I. Al-Resayes, P. B. Hitchcock and J. F. Nixon, J. Chem. Soc., Chem. Commun., 1991, 78.
3. See, for example: E. Bouwman, P. Evans, R. A. G. de Graaff, H. Kooijman, R. Poinsot, P. Rabu, J. Reedijk and A. L. Spek, Inorg. Chem., 1995, 34, 6302; X.-M. Chen, X.-L Feng, X.-L. Yu and T. C. W. Mak, Inorg. Chim. Acta, 1997, 266, 121; G. A. van Albada, R. C. Guijt, J. G. Haasnoot, M. Lutz, A. L. Spek and J. Reedijk, Eur. J. Inorg. Chem., 2000, 121 and references therein.
4. See, for example: E. Bouwman, P. Evans, R. A. G. de Graaff, H. Kooijman, R. Poinsot, P. Rabu, J. Reedijk and A. L. Spek, Inorg. Chem., 1995, 34, 6302; X.-M. Chen, X.-L Feng, X.-L. Yu and T. C. W. Mak, Inorg. Chim. Acta, 1997, 266, 121; G. A. van Albada, R. C. Guijt, J. G. Haasnoot, M. Lutz, A. L. Spek and J. Reedijk, Eur. J. Inorg. Chem., 2000, 121 and references therein.
5. See, for example: E. Bouwman, P. Evans, R. A. G. de Graaff, H. Kooijman, R. Poinsot, P. Rabu, J. Reedijk and A. L. Spek, Inorg. Chem., 1995, 34, 6302; X.-M. Chen, X.-L Feng, X.-L. Yu and T. C. W. Mak, Inorg. Chim. Acta, 1997, 266, 121; G. A. van Albada, R. C. Guijt, J. G. Haasnoot, M. Lutz, A. L. Spek and J. Reedijk, Eur. J. Inorg. Chem., 2000, 121 and references therein.
6. D. Poleti and L. Karanović, Acta Crystallogr., Sect. C, 1989, 45, 1002.
7. G. Smith, D. E. Lynch, T. C. W. Mak, W.-H. Yip and C. H. L. Kennard, Polyhedron, 1993, 12, 203.
8. W. L. Driessen and T. X. Neenan, Acta Crystallogr., Sect. C, 1996, 52, 59.
9. See for example: M. M. Chowdhry, D. M. P. Mingos, A. J. P. White and D. J. Williams, Chem. Commun., 1996, 899; M. Munakata, L. P. Wu, M. Yamamoto, T. Kuroda-Sowa and M. Maekawa, J. Am. Chem. Soc., 1996, 118, 3117 and references therein.
10. See for example: M. M. Chowdhry, D. M. P. Mingos, A. J. P. White and D. J. Williams, Chem. Commun., 1996, 899; M. Munakata, L. P. Wu, M. Yamamoto, T. Kuroda-Sowa and M. Maekawa, J. Am. Chem. Soc., 1996, 118, 3117 and references therein.
11. For a review see: (a) W. E. Hatfield, W. E. Estes, W. E. Marsh, M. W. Pickens, L. W. der Haar and R. R. Weller, Extended Linear Chain Compounds, ed. J. S. Miller, Plenum Press, New York, 1982, vol. 3, p. 89;
12. (b) D. B. Losee, J. N. McElearney, G. E. Shankle, R. L. Carlin, P. J. Cresswell and W. T. Robinson, Phys. Rev. B, 1973, 8, 2185.
13. F. S. Keij, R. A. G. de Graaff, J. G. Haasnoot, A. J. Oosterling, E. Pedersen and J. Reedijk, J. Chem. Soc., Chem. Commun., 1988, 424.
14. P. Sobota, Z. Olejnik, J. Utko and T. Lis, Polyhedron, 1993, 12, 613; P. Sobota, J. Utko and L. B. Jerzykiewicz, Inorg. Chem., 1998, 37, 3428.
15. P. Sobota, Z. Olejnik, J. Utko and T. Lis, Polyhedron, 1993, 12, 613; P. Sobota, J. Utko and L. B. Jerzykiewicz, Inorg. Chem., 1998, 37, 3428.
16. B. W. Dockum and W. M. Reiff, Inorg. Chem., 1982, 21, 391; B. W. Dockum, G. A. Eisman, E. H. Witten and W. M. Reiff, Inorg. Chem., 1983, 22, 150.
17. B. W. Dockum and W. M. Reiff, Inorg. Chem., 1982, 21, 391; B. W. Dockum, G. A. Eisman, E. H. Witten and W. M. Reiff, Inorg. Chem., 1983, 22, 150.
18. P. T. Moseley and H. M. M. Shearer, J. Chem. Soc., Dalton Trans., 1973, 61.
19. N. Thorup and H. Soling, Acta Chem. Scand., 1969, 8, 2933; A. Herweijer, W. J. M. de Jonge, A. C. Botterman, A. L. M. Bongaarts and J. A. Cowen, Phys. Rev. B, 1973, 8, 2185.
20. N. Thorup and H. Soling, Acta Chem. Scand., 1969, 8, 2933; A. Herweijer, W. J. M. de Jonge, A. C. Botterman, A. L. M. Bongaarts and J. A. Cowen, Phys. Rev. B, 1973, 8, 2185.
21. C. von Hänisch, D. Fenske, F. Weigend and R. Ahlrichs, Chem. Eur. J., 1997, 3, 1494.
22. Results to be published.
23. J.-C. Hierso, D. D. Ellis, A. L. Spek, E. Bouwman and J. Reedijk, Eur. J. Inorg. Chem., submitted.