A new procedure for construction of oxocane and oxonane derivatives based on alkyne-Co2(CO)6 complexes

Tetrahedron

Volumn 56, Issue 15, 2000, Pages 2203-2209

  Mukai, Chisato ^a   Yamashita, Haruhisa ^a   Ichiryu, Tetsuya ^a   Hanaoka, Miyoji ^a  

^a KANAZAWA UNIVERSITY   (Japan)

Author keywords

Oxocane; Oxonane; Oxopane

Indexed keywords

ALKYNE DERIVATIVE; COBALT COMPLEX; MESYLIC ACID DERIVATIVE; TETRAHYDROFURAN DERIVATIVE; TRIETHYLAMINE;

CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; CONFERENCE PAPER; PRIORITY JOURNAL; SYNTHESIS;

EID: 0034616177     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(99)01103-5     Document Type: Conference Paper

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32. When the methyl and benzyl congeners 30 and 31 were independently submitted to the reaction conditions described for the transformation of 19 into 20, the corresponding oxocane derivatives, 20 and 32, could not be detected in the reaction mixture. These results can tentatively be interpreted in terms of the lack of a cationic intermediate like 22. Therefore, it might be concluded that the β-trimethylsilylmethyl group at the C-2 position of the tetrahydrofuran ring is mandatory for conversion of 19 to 20. The details of these results will be reported in the near future.