The insertion of sulfur dioxide into palladium-methyl bonds: The synthesis and X-ray crystal structure of an unusual [(dppp)PdOS(Me)O]2[BAr'4]2 dimer

Chemical Communications

Volumn , Issue 1, 2000, Pages 47-48

  Gates, Derek P ^a   White, Peter S ^a   Brookhart, Maurice ^a  

^a University of North Carolina at Chapel Hill   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DIMER; PALLADIUM COMPLEX; SULFUR DIOXIDE;

ARTICLE; CHEMICAL BINDING; CHEMICAL BOND; CHEMICAL STRUCTURE; CONFORMATION; CRYSTAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; REACTION ANALYSIS; SYNTHESIS; TEMPERATURE; X RAY CRYSTALLOGRAPHY;

EID: 0034614399     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a905993h     Document Type: Article

References (18)

1. See, for example: A. Sen, Adv. Polym. Sci., 1986, 73/74, 125; E. Drent, J. A. M. van Broekhoven and M. J. Doyle, J. Organomet. Chem., 1991, 417, 235; M. Brookhart, F. C. Rix, J. M. DeSimone, J. C. Barborak, J. Am. Chem. Soc., 1992, 114, 5894; F. C. Rix, M. Brookhart and P. S. White, J. Am. Chem. Soc., 1996, 118, 4746.
2. See, for example: A. Sen, Adv. Polym. Sci., 1986, 73/74, 125; E. Drent, J. A. M. van Broekhoven and M. J. Doyle, J. Organomet. Chem., 1991, 417, 235; M. Brookhart, F. C. Rix, J. M. DeSimone, J. C. Barborak, J. Am. Chem. Soc., 1992, 114, 5894; F. C. Rix, M. Brookhart and P. S. White, J. Am. Chem. Soc., 1996, 118, 4746.
3. See, for example: A. Sen, Adv. Polym. Sci., 1986, 73/74, 125; E. Drent, J. A. M. van Broekhoven and M. J. Doyle, J. Organomet. Chem., 1991, 417, 235; M. Brookhart, F. C. Rix, J. M. DeSimone, J. C. Barborak, J. Am. Chem. Soc., 1992, 114, 5894; F. C. Rix, M. Brookhart and P. S. White, J. Am. Chem. Soc., 1996, 118, 4746.
4. See, for example: A. Sen, Adv. Polym. Sci., 1986, 73/74, 125; E. Drent, J. A. M. van Broekhoven and M. J. Doyle, J. Organomet. Chem., 1991, 417, 235; M. Brookhart, F. C. Rix, J. M. DeSimone, J. C. Barborak, J. Am. Chem. Soc., 1992, 114, 5894; F. C. Rix, M. Brookhart and P. S. White, J. Am. Chem. Soc., 1996, 118, 4746.
5. For general reviews, see: G. J. Kubas, Acc. Chem. Res., 1994, 27, 183; A. Wojcicki, Adv. Organomet. Chem., 1974, 12, 31; W. Kitching and C. W. Fong, Organomet. Chem. Rev. A, 1970, 5, 281.
6. For general reviews, see: G. J. Kubas, Acc. Chem. Res., 1994, 27, 183; A. Wojcicki, Adv. Organomet. Chem., 1974, 12, 31; W. Kitching and C. W. Fong, Organomet. Chem. Rev. A, 1970, 5, 281.
7. For general reviews, see: G. J. Kubas, Acc. Chem. Res., 1994, 27, 183; A. Wojcicki, Adv. Organomet. Chem., 1974, 12, 31; W. Kitching and C. W. Fong, Organomet. Chem. Rev. A, 1970, 5, 281.
8. 3. See: H. S. Klein, Chem. Commun., 1968, 377.
9. E. Drent, US Pat. 4 808 697, 1989.
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12. J. Ledford, C. S. Shultz and M. Brookhart, unpublished work.
13. M. S. Morton, R. J. Lachicotte, D. A. Vicic and W. D. Jones, Organometallics, 1999, 18, 227.
14. 31P NMR line widths at 263 K.
15. J. Ledford and M. Brookhart, unpublished work.
16. 2 copolymers are poorly soluble and difficult to characterise.
17. K. J. Ivin, M. Navratil and N. A. Walker, J. Polym. Sci. Part A-1, 1972, 10, 701.
18. 2 with olefins. Temperatures as low as - 100 °C can be used. C. P. Tsonis, in Polymeric Materials Encyclopedia, ed. J. C. Salamone, CRC Press, New York, 1996, vol. 9, p. 6866.