A protein-rhodium complex as an efficient catalyst for two-phase olefin hydroformylation

Tetrahedron Letters

Volumn 41, Issue 19, 2000, Pages 3717-3720

  Marchetti, M ^a   Mangano, G ^a   Paganelli, S ^b   Botteghi, C ^b  

^a Ist per l'Applic delle Tecniche C   (Italy)

^b CA' FOSCARI UNIVERSITY OF VENICE   (Italy)

Author keywords

Biphasic catalysis; Hydroformylation; Rh proteins; Rhodium catalysts

Indexed keywords

ALKENE; FORMIC ACID; HUMAN SERUM ALBUMIN; RHODIUM COMPLEX;

AQUEOUS SOLUTION; ARTICLE; CATALYST; CHEMICAL REACTION; COMPLEX FORMATION; PROTEIN BINDING; STEREOSPECIFICITY;

EID: 0034612142     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)00473-1     Document Type: Article

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22. -1 suggesting that Rh(I) carbonyl complexes are present. The assay of rhodium bonded per mol of HSA was performed by ICP-MS; this analysis shows that HSA binds ca. 30 equiv. of Rh(I).
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