Stereochemistry of nonnatural aldol reactions catalyzed by DHAP aldolases

Biotechnology and Bioengineering

Volumn 70, Issue 3, 2000, Pages 349-352

  Bakker, Martin ^a   Van De Velde, Fred ^a   Van Rantwijk, Fred ^a   Sheldon, Roger A ^a  

^a DELFT UNIVERSITY OF TECHNOLOGY   (Netherlands)

Author keywords

Aldol reaction; Aldolase; Carbohydrate; Configuration; Retro aldol reaction; Selectivity; Stereoisomer

Indexed keywords

ALCOHOLS; BIOASSAY; CARBOHYDRATES; CATALYSIS; CATALYST DEACTIVATION; ISOMERS; STEREOCHEMISTRY;

ALDOL; ALDOLASE; DIHYDROXYACETONE PHOSPHATE (DHAP); ENZYMATIC ASSAY; STEREOISOMERS;

ENZYMES;

ACETALDEHYDE; BUTYRALDEHYDE; DIHYDROXYACETONE PHOSPHATE; FRUCTOSE BISPHOSPHATE ALDOLASE;

ACCURACY; ARTICLE; CATALYSIS; CHEMICAL REACTION; ENZYME ASSAY; ESCHERICHIA COLI; NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STAPHYLOCOCCUS CARNOSUS; STEREOCHEMISTRY; STEREOISOMERISM; STEREOSPECIFICITY;

ALDEHYDE-LYASES; BIOTECHNOLOGY; DIHYDROXYACETONE PHOSPHATE; ESCHERICHIA COLI; FRUCTOSE-BISPHOSPHATE ALDOLASE; STAPHYLOCOCCUS; STEREOISOMERISM; SUBSTRATE SPECIFICITY; SUPPORT, NON-U.S. GOV'T;

ESCHERICHIA COLI; STAPHYLOCOCCUS CARNOSUS;

EID: 0034610170     PISSN: 00063592     EISSN: None     Source Type: Journal    
DOI: 10.1002/1097-0290(20001105)70:3<349::AID-BIT12>3.0.CO;2-0     Document Type: Article

References (8)

1. Methods of enzymatic analysis
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7. Class I fructose-1,6-bisphosphate aldolases as catalysts for asymmetric aldol reactions
8. Fructose-1,6-bisphosphate aldolase from Staphylococcus carnosus: Overexpression, structure prediction, stereoselectivity and application in the synthesis of bicyclic sugars