Peroxidase-catalyzed asymmetric sulfoxidation in organic solvents versus in water

Biotechnology and Bioengineering

Volumn 70, Issue 3, 2000, Pages 353-357

  Schoevaart, Rob ^a   Van Rantwijk, Fred ^a   Sheldon, Roger A ^a  

^a DELFT UNIVERSITY OF TECHNOLOGY   (Netherlands)

Author keywords

Chiral sulfoxides; Hemoproteins; Nonaqueous biocatalysis; Organic solvents; Peroxidase; Sulfoxidation

Indexed keywords

CATALYSIS; ENZYMES; METHANOL; ORGANIC SOLVENTS; OXIDATION; PROTEINS; SOLUBILITY; WATER;

HEMOPROTEINS; PEROXIDASE; SULFOXIDATION;

BIOTECHNOLOGY;

2 PROPANOL; ANISOLE DERIVATIVE; CYTOCHROME C; HEMOGLOBIN; HORSERADISH PEROXIDASE; METHANOL; MYOGLOBIN; ORGANIC SOLVENT; PEROXIDASE; SULFOXIDE; WATER;

ARTICLE; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL REACTION KINETICS; CHIRALITY; COMPARATIVE STUDY; OXIDATION; SOLUBILITY;

BIOTECHNOLOGY; CATALYSIS; COMPARATIVE STUDY; HEMEPROTEINS; HORSERADISH PEROXIDASE; IN VITRO; KINETICS; SOLVENTS; SUBSTRATE SPECIFICITY; SULFIDES; SULFOXIDES; SUPPORT, U.S. GOV'T, NON-P.H.S.; WATER;

ARMORACIA RUSTICANA; GLYCINE MAX;

EID: 0034610169     PISSN: 00063592     EISSN: None     Source Type: Journal    
DOI: 10.1002/1097-0290(20001105)70:3<353::AID-BIT13>3.0.CO;2-0     Document Type: Article

References (22)

1. Biotransformations with peroxidases
2. Cytochrome P450-like substrate oxidation catalyzed by cytochrome c and immobilized cytochrome c
3. Mechanism of S-oxidation reactions catalyzed by soybean hydroperoxide-dependent oxygenase
4. Applications of sulfoxides to asymmetric synthesis of biologically active compounds
5. Horseradish peroxidase catalyzed sulfoxidation is enantioselective
6. The microperoxidase-catalyzed oxidation of sulfides is enantioselective
7. Chloroperoxidase and hydrogen peroxide: An efficient system for enzymatic enantioselective sulfoxidations
8. Enantioselective oxidations of sulfides catalyzed by chloroperoxidase
9. Enantioselective sulphoxidations catalyzed by lactoperoxidase
10. Recent biotechnological developments in the use of peroxidases
11. Striking activation of oxidative enzymes suspended in nonaqueous media
12. Horseradish peroxidase-catalyzed 2-electron oxidations - Oxidation of iodide, thioanisoles, and phenols at distinct sites
13. Monoxygenase activity of cytochrome-c peroxidase
14. Conversion of myoglobin into a peroxygenase: A catalytic intermediate of sulfoxidation and epoxidation by the F43H/H64L mutant
15. Molecular engineering of horseradish peroxidase: Thioether sulfoxidation and styrene epoxidation by Phe-41 leucine and threonine mutants
16. Asymmetric oxidation catalyzed by myoglobin mutants
17. How do organic solvents affect peroxidase structure and function?
18. The rational design of semisynthetic peroxidases
19. Chloroperoxidase catalyzed oxidations in t-butyl alcohol/water mixtures
20. Selective oxidations catalyzed by peroxidases