Reactivities of silicas with organometallic methylating agents

Journal of the American Chemical Society

Volumn 122, Issue 13, 2000, Pages 3118-3126

  Tao, Ting ^a   Maciel, Gary E ^a  

^a Department of Environmental and Radiological Health Sciences   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALUMINUM DERIVATIVE; LITHIUM DERIVATIVE; MAGNESIUM DERIVATIVE; METHYL GROUP; ORGANOMETALLIC COMPOUND; REAGENT; SILICA GEL; SILICON DIOXIDE; ZINC DERIVATIVE;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL MODIFICATION; CHEMICAL REACTION; CHLORINATION; METHYLATION; SOLID STATE;

EID: 0034607370     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja991950r     Document Type: Article

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35. Dimethylzinc bursts into flames upon exposure to air and reacts with explosive violence with water. Therefore, it must be handled in an inert atmosphere. See discussion in: Wilkmson, G.; Stone, F. G. A.; Abel, E. W., Eds. Comprehensive Organometallic Chemistry: The Synthesis, Reactions and Structures of Organometallic Compounds; Pergamon Press: New York. 1982; Vol. 2, p 827. Errington. R. J. Advanced Practical Inorganic and Metalorganic Chemistry; Blackie Academic & Professional: London, 1997; p 110.
36. The spontaneous flammability of trimethylaluminum in air demands special precautions. All transfers, storage, and reactions must be done under an anhydrous atmosphere of pure nitrogen or argon. See the detailed discussion in: Wilkinson, G.; Stone, F. G. A.; Abel, E. W., Eds. Comprehensive Organometallic Chemistry: The Synthesis, Reactions and Structures of Organometallic Compounds: Pergamon Press:New York, 1982; Vol. 1, p 579;