Isomerization of allylic silyl ethers catalyzed by ReO3(OSiR3) complexes

Tetrahedron Letters

Volumn 41, Issue 10, 2000, Pages 1549-1552

  Bellemin Laponnaz, Stéphane ^a   Le Ny, Jean Pierre ^a   Osborn, John A ^a  

^a UNIVERSITÉ DE STRASBOURG   (France)

Author keywords

Catalysis; Isomerization; Rearrangements; Rhenium

Indexed keywords

ALCOHOL DERIVATIVE; ETHER DERIVATIVE; RHENIUM COMPLEX; SILANE DERIVATIVE;

ARTICLE; CATALYST; CHEMICAL REACTION; CHEMICAL STRUCTURE; ISOMERISM; REACTION ANALYSIS; TEMPERATURE;

EID: 0034603592     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)02352-7     Document Type: Article

References (14)

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11. For a theoretical investigation of the mechanism, see: Bellemin-Laponnaz, S.; Le Ny, J. P.; Dedieu, A. Chem. Eur. J. 1999, 5, 57-64.
12. 3 is a well-established preparative method to introduce these functionalities on a metal atom. See: Chisholm, M. H.; Rothwell, I. P. Comprehensive Coordination Chemistry; Pergamon: Oxford, 1987; Vol. 2, p. 343.
13. The initiation period observed when 50 equiv. were used could be explained by a slower formation of the active species due to a higher order in substrate in step I.
14. Herrmann, W. A.; Wojtczack, W. A.; Artus, G. R.; Kühn, F. E.; Mattner, M. R. Inorg. Chem. 1997, 36, 465-471.