New building blocks for the design of oligonuclear copper complexes based on amino carbohydrates

Angewandte Chemie - International Edition

Volumn 39, Issue 3, 2000, Pages 595-599

  Wegner, Rainer ^a   Gottschaldt, Michael ^b   Görls, Helmer ^a   Jäger, Ernst G ^a   Klemm, Dieter ^b  

^a Inst Anorganische Analyt Chem U   (Germany)

^b Inst Org Makromolekulare Chem U   (Germany)

Author keywords

Amino carbohydrates; Copper; Magnetic properties; Oligonuclear complexes; Oxidations

Indexed keywords

AMINO ACID; CARBOHYDRATE DERIVATIVE; COPPER COMPLEX;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; METAL BINDING; SPECTROPHOTOMETRY; SYNTHESIS;

EID: 0034603019     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(20000204)39:3<595::AID-ANIE595>3.0.CO;2-C     Document Type: Article

References (65)

1. T. Klabunde, C. Eicken, J. C. Sacchettini, B. Krebs, Nature Struct. Biol. 1998, 5, 1084-1090.
2. A. Messerschmidt, Metal Sites Proteins Models 1998, 90, 37-68.
3. R. Than, A. A. Feldmann, B. Krebs, Coord. Chem. Rev. 1999, 182, 211-241.
4. a) E.-G. Jäger, Z. Chem. 1966, 6, 111-112;
5. b) H. Elias, D. Hess, H. Paulus, E.-G. Jäger, F. Gräfe, Z. Anorg. Allg. Chem. 1990, 589, 101-114.
6. a) J. J. Bertrand, J. A. Kelley, C. E. Kirkwood, Chem. Commun. 1968, 1329-1331;
7. b) J. A. Bertrand, J. A. Kelley, Inorg. Chim. Acta 1970, 4, 203-209;
8. c) J. A. Bertrand, J. A. Kelley, J. L. Breece, Inorg. Chim. Acta 1970, 4, 247-250;
9. d) J. A. Bertrand, C. Marabella, D. G. Vánderveer, Inorg. Chim. Acta 1978, 26, 113-119.
10. a) E. Sinn, Inorg. Chem. 1976, 15, 358-365;
11. b) J. A. Davis, E. Sinn, J. Chem. Soc. Dalton Trans. 1976, 165-170.
12. a) N. Matsumoto, T. Tsutsumi, A. Ohyoshi, H. Okawa, Bull. Chem. Soc. Jpn. 1983, 56, 1386-1392;
13. b) N. Matsumoto, I. Ueda, Y. Nishida, S. Kida, Bull. Chem. Soc. Jpn. 1976, 49, 1308-1312;
14. c) N. Matsumoto, T. Kondo, M. Kodera, H. Okawa, S. Kida, Bull. Chem. Soc. Jpn. 1989, 62, 4041-4043.
15. F. Wiesemann, B. Krebs, H. Görls, E.-G. Jäger, Z. Anorg. Allg. Chem. 1995, 621, 1883-1892.
16. a) W. Haase, Chem. Ber. 1973, 106, 3132-3148;
17. b) L. Merz, W. Haase, J. Chem. Soc. Dalton Trans. 1978, 1594-1598;
18. c) L. Merz, W. Haase, J. Chem. Soc. Dalton Trans. 1980, 875-879;
19. d) R. Mergehenn, L. Merz, W. Haase, J. Chem. Soc. Dalton Trans. 1980, 1703-1709;
20. e) L. Walz, H. Paulus, W. Haase, H. Langhof, F. Nepveu, J. Chem. Soc. Dalton Trans. 1983, 657-664;
21. f) L. Schwabe, W. Haase, J. Chem. Soc. Dalton Trans. 1985, 1909-1913;
22. g) H. Astheimer, F. Nepveu, L. Walz, W. Haase, J. Chem. Soc. Dalton Trans. 1985, 315-320.
23. H. Oshio, Y. Saito, T. Ito, Angew. Chem. 1997, 122, 2789-2791; Agnew. Chem. Int. Ed. Engl. 1997, 36, 2673-2675.
24. H. Oshio, Y. Saito, T. Ito, Angew. Chem. 1997, 122, 2789-2791; Agnew. Chem. Int. Ed. Engl. 1997, 36, 2673-2675.
25. Yu. M. Chumakov, V. N. Biyushkin, T. I. Malinovskii, S. Kulemu, V. I. Tsapkov, M. S. Popov, N. M. Samus, Koord. Khim. 1990, 16, 945-949.
26. a) V. Tangoulis, S. Paschalidou, E. G. Bakalbassis, S. P. Perlepes, C. P. Raptopoulou, A. Terzis, Chem. Commun. 1996, 1297-1298;
27. b) V. Tangoulis, C. P. Raptopoulou, A. Terzis, S. Paschalidou, S. P. Perlepes, E. G. Bakalbassis, Inorg. Chem. 1997, 36, 3996-4006.
28. G. A. van Albada, J. Reedijk, R. Hamalainen, U. Turpeinen, A. L. Spek, Inorg. Chim. Acta 1989, 163, 213-217.
29. P. L. Dedert, T. Sorrell, T. J. Marks, J. A. Ibers, Inorg. Chem. 1982, 21, 3506-3517.
30. a) H. Muhonen, Acta Chem. Scand. Ser. A 1980, 34, 79;
31. b) H. Muhonen, W. E. Hatfield, J. H. Helms, Inorg. Chem. 1986, 25, 800-812.
32. J. Sassmannshausen, H. F. von Schnering, L. Walz, Z. Kristallogr, 1997, 212, 656-661.
33. a) E.-G. Jäger, K. Müller, Z. Anorg. Allg. Chem. 1981, 482, 201-216;
34. b) E.-G. Jäger, K. Schuhmann, H. Görls, Chem. Ber. 1997, 130, 1643-1646.
35. D. Klemm, T. Heinze, B. Philipp, W. Wagenknecht, Acta Polym. 1977, 48, 277-297.
36. D. Klemm, B. Philipp, T. Heinze, U. Heinze, W. Wagenknecht, Comprehensive Cellulose Chemistry, Vols. 1 and 2. Wiley-VCH, Weinheim, 1998.
37. J. Tiller, P. Berlin, D. Klemm, Macromol. Chem. Phys. 1999, 200, 1-9.
38. D. N. Williams, U. Piarulli, C. Floriani, A. Chiesi-Villa, C. Rizzoli, J. Chem. Soc. Dalton Trans. 1994, 1243-1250.
39. a) P. Klüfers, H. Piotrowski, J. Uhlendorf, Chem. Eur. J. 1997, 3, 601-608;
40. b) H. P. Wu, C. Janiak, P. Klüfers, P. Mayer, Chem. Commun. 1998, 2637-2638;
41. c) P. Mayer, P. Klüfers, Acta Crystallogr. Sect. C 1998, 54, 583-586;
42. d) R. Ahlrichs, B. Ballauf, K. Eichkorn, O. Hanemann, G. Kettenbach, P. Klüfers, Chem. Eur. J. 1998, 4, 835-844;
43. e) A. Geisselmann, P. Klüfers, B. Pilawa, Angew. Chem. 1998, 123, 1181-1184; Angew. Chem. Int. Ed. 1998, 37, 1119-1121;
44. e) A. Geisselmann, P. Klüfers, B. Pilawa, Angew. Chem. 1998, 123, 1181-1184; Angew. Chem. Int. Ed. 1998, 37, 1119-1121;
45. f) J. Bürger, P. Klüfers, Z. Anorg. Allg. Chem. 1998, 624, 359-360.
46. a) S. Yano, Coord. Chem. Rev. 1988, 92, 113-156;
47. b) S. Yano, M. Doi, S. Tamakoshi, W. Mori, M. Mikuriya, A. Ichimura, I. Kinoshita, Y. Yamamoto, T. Tanase, Chem. Commun. 1997, 997-998;
48. c) S. Yano, S. Inoue, R. Nouchi, M. Reiko, S. Kaoru, Y. Yoshic, Y. Yasuda, M. Kato, T. Tanase, T. Kakuchi, Y. Mikata, T. Suzuki, Y. Yamamoto, J. Inorg. Biochem. 1998, 69, 15-23;
49. d) T. Tanase, T. Onaka, M. Hakagoshi, I. Kinoshita, S. Shibata, M. Doe, J. Fujii, S. Yano, Chem. Commun. 1997, 2115-2116;
50. e) T. Tsubomura, M. Ogawa, S. Yano, K. Kobayashi, T. Sakurai, S. Yoshikawa, Inorg. Chem. 1990, 29, 2622-2626.
51. Y. Zhou, B. Wagner, K. Polborn, K. Sunkel, W. Beck, Z. Naturforsch. B 1994, 49, 1193-1202.
52. J. M. Harrowfield, M. Mocerino, B. W. Skelton, W. Wei, A. H. White, J. Chem. Soc. Dalton Trans. 1995, 783-797.
53. a) A. Bernalte-Garcia, M. A. Diaz-Diez, F. J. Garcia-Barros, F. J. Higes-Rolando, C. Valenzuela-Calahorro, Trans. Met. Chem. 1996, 21, 197-199;
54. b) M. A. Diaz-Diez, F. J. Garcia-Barros, F. J. Higes-Rolando, A. Bernalte-Garcia, C. Valenzuela-Calahorro, Trans. Met. Chem. 1995, 20, 402-405;
55. c) M. A. Diaz-Diez, F. J. Garcia-Barros, F. J. Higes-Rolando, A. Bernalte-Garcia, C. Valenzuela-Calahorro, Polyhedron 1993, 12, 2519-2523.
56. a) K. Hegetschweiler, M. Weber, V. Huch, R. J. Geue, A. D. Rae, A. C. Willis, A. M. Sargeson, Inorg. Chem. 1998, 37, 6136-6146;
57. b) G. J. Reiss, W. Frank, K. Hegetschweiler, D. Kuppert, Acta Crystallogr. Sect. C 1998, 54, 614-616;
58. c) L. Hausherr-Primo, K. Hegetschweiler, H. Ruegger, L. Odier, R. D. Hancock, H. W. Schmalle, V. Gramlich, J. Chem. Soc. Dalton Trans. 1994, 1689-1701.
59. E.-G. Jäger, R. Wegner, H. Görls, D. Klemm, M. Gottschaldt, unpublished results.
60. Synthesis: K. Dax, B. Gaigg, V. Grassberger, B. Kölbinger, A. E. Stütz, J. Carbohydr. Chem. 1990, 9, 474-499; B. P. Bashyal, H. F. Chow, L. E. Fellows, G. W. J. Fleet, Tetrahedron 1987, 43, 415.
61. Synthesis: K. Dax, B. Gaigg, V. Grassberger, B. Kölbinger, A. E. Stütz, J. Carbohydr. Chem. 1990, 9, 474-499; B. P. Bashyal, H. F. Chow, L. E. Fellows, G. W. J. Fleet, Tetrahedron 1987, 43, 415.
62. [31b]
63. 3. Distances [Å] and angles [ ]: Cu(A) ⋯ Cu(B) 5.735(3), Cu(A) ⋯ Cu(C) 3.248(3), Cu(B) ⋯ Cu(C) 3.207(3), Cu-O/N 1.940(4), Cu(A) ⋯ O6(B) (symmetry operation for equivalent atoms: x, 0.5 + y, z) 2.753(4), Cu(B) ⋯ O2(A) 2.898(4), Cu(C)-O2(A) 2.586(4), Cu(C)-O2(B) 2.572(4); O1(A)-Cu(A)-Nl(A) 95.6(1), O/N-Cu-O/N 73.6(1) - 106.9(1) and 152.0(1)-172.3(1).
64. b) Crystallographic Data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-129253 (1a) and -129254 (2). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: (+ 44) 1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
65. 1). The given rate constants are mean values of three measurements with a discrepancy value of the Lineweaver-Burk plot of r ≥ 0.992.