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Volumn 39, Issue 7, 2000, Pages 1256-1259

Novel water-soluble calix[4]arene ligands with phosphane-containing groups for dual functional metal-complex catalysts: The biphasic hydroformylation of water-insoluble olefins

Author keywords

Calixarenes; Hydroformylations; Phase transfer catalysis; Phosphanes; Rhodium

Indexed keywords

ALKENE; CALIXARENE; LIGAND; METAL COMPLEX;

EID: 0034599408     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(20000403)39:7<1256::AID-ANIE1256>3.0.CO;2-F     Document Type: Article
Times cited : (96)

References (51)
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    • [s] the addition of an organic solvent such as toluene is necessary to favor the partitioning of the catalysts
    • [s] the addition of an organic solvent such as toluene is necessary to favor the partitioning of the catalysts.
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    • Water-soluble calix[n]arenes could serve as inverse phase-transfer catalysts through their ability to form inclusion complexes; S. Shimizu, K. Kito, Y. Sasaki, C. Hirai, Chem. Commun. 1997, 1629-1630.
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    • and references therein
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    • note
    • 2] complex showed two doublets at δ = 45.2 (J(P,Rh) = 173 Hz) and 45.7 (J(P,Rh) = 174 Hz).
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    • DMCD may form inclusion complexes with TPPTS, which are capable of transferring into the organic phase. An analogous formation of inclusion complexes between unmodified β- and γ-CDs and TPPTS has been proved: E. Monflier, G. Fremy, Y. Castanet, A. Mortreux, New J. Chem. 1999, 23, 469-472. Consequently, it is possible to leach out rhodium from the aqueous phase.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.