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Volumn 39, Issue 20, 2000, Pages 4625-4629

Competitive reaction of axial ligands during biomimetic oxygenations

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE; IMIDAZOLE DERIVATIVE; METALLOPORPHYRIN; PYRIDINE DERIVATIVE;

EID: 0034596888     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic000071z     Document Type: Article
Times cited : (52)

References (88)
  • 42
    • 0342582270 scopus 로고    scopus 로고
    • note
    • The two following references concern the synthesis of μ-oxo dimers.
  • 49
    • 0343887981 scopus 로고    scopus 로고
    • note
    • The newer polyhalogenated porphyrin ligands which contain halogens on the β-pyrrolic positions as well as on the meso-ary\ groups are not susceptible to dimerization because the porphyrin macrocycle is ruffled or saddle-shaped, rather than planar.
  • 84
    • 0343016485 scopus 로고    scopus 로고
    • note
    • The concentration of pentafluoropyridine remains constant when mixed in solution with the catalyst and iodosylbenzene, under reaction conditions analogous to both those used for the oxidation of pyridine and those used for the competitive oxidation of pyridine and hydrocarbon substrate.
  • 85
    • 0343887950 scopus 로고    scopus 로고
    • note
    • It should be noted that at 1 M, pentafluoropyridine comprises about 10% of the total reaction volume. Thus, a solvent effect may be an alternate explanation for the change in reaction rates.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.