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Volumn 122, Issue 30, 2000, Pages 7390-7391

The first catalytic sulfoxidation of saturated. Hydrocarbons with SO2/O2 by a vanadium species [3]

Author keywords

[No Author keywords available]

Indexed keywords

HYDROCARBON; VANADIUM;

EID: 0034596352     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja000333w     Document Type: Letter
Times cited : (52)

References (24)
  • 13
    • 0342735315 scopus 로고
    • Trost, B. M., Ed.; Pergamon Press: New York, and references therein
    • (c) Crabtree, R. H.; Habib, A. Comprehensive Organic Synthesis; Trost, B. M., Ed.; Pergamon Press: New York, 1991; Vol 7., p 14 and references therein.
    • (1991) Comprehensive Organic Synthesis , vol.7 , pp. 14
    • Crabtree, R.H.1    Habib, A.2
  • 15
    • 0343605336 scopus 로고    scopus 로고
    • note
    • 2 (0.5 atm). The mixture was stirred at 40°C for 2 h and then extracted with ethyl acetate. The aqueous layer was concentrated by evaporation, and the solid obtained was recyrystallized carefully with ethyl acetate.
  • 16
    • 0343605337 scopus 로고    scopus 로고
    • note
    • 4S: C, 51.26; H, 7.74. Found: C, 51.11, H, 7.55.
  • 18
    • 9444263106 scopus 로고    scopus 로고
    • A review for the modern synthesis using vanadium species as a catalyst has been reported: Hirao, T. Chem. Rev. 1997, 97, 2707-2724.
    • (1997) Chem. Rev. , vol.97 , pp. 2707-2724
    • Hirao, T.1
  • 19
    • 0343605334 scopus 로고    scopus 로고
    • note
    • The octane sulfonic acids formed were difficult to isolate each isomer, and were found to consist of about a 1:1:1 regioisomeric mixture of 2, 3, and 4-octane sulfonic acids by the LC and NMR measurements.
  • 20
    • 0342300276 scopus 로고    scopus 로고
    • note
    • 2 (3 mg) in AcOH (5 mL) at 60°C for 36 h.
  • 21
    • 0342300275 scopus 로고    scopus 로고
    • note
    • The generation of an alkyl radical by the hydrogen atom abstraction from an alkane by V(V) ion has been suggested as an alternative possibility by a reviewer.
  • 22
    • 0038408167 scopus 로고
    • Graf, R. Ann. 1952, 578, 50-82.
    • (1952) Ann. , vol.578 , pp. 50-82
    • Graf, R.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.