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Atomic coordinates of the structures of 3 and 6 have been deposited with the Cambridge Crystallographic Data Centre. These are available, on request, from the Director, Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EK, U.K.
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Atomic coordinates of the structures of 3 and 6 have been deposited with the Cambridge Crystallographic Data Centre. These are available, on request, from the Director, Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EK, U.K.
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note
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1H NMR spectrum reveals it to be 3 together with five included benzophenone molecules. We have not as yet been able to obtain a single crystal suitable for X-ray structure determination.
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19
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Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Eds.; Oxford University Press: Oxford
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0343656573
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19-23 Sep, Perth, Australia
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Recently, it has been reported that some calixarenes can act as inverse phase-transfer catalysts showing typical enzyme-like effects on Pd-catalyzed Stille coupling reactions: Schatz J.; Schildbach, R.; Baur, M. In Abstracts of The Fifth International Conference on Calixarene Chemistry; 19-23 Sep, 1999, Perth, Australia.
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Abstracts of the Fifth International Conference on Calixarene Chemistry
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Schatz, J.1
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Baur, M.3
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See, e.g., a recent communication: Cotter, W. D.; Barbour, L.; McNamara, K. L.; Hechter, R.; Lachicotte, R. J. J. Am. Chem. Soc. 1998, 120, 11016-11017. This communication reports the first direct observation and spectroscopic characterization of a triflato-Pd(II) intermediate en route to transmetalation in a Stille coupling reaction.
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