Boron trifluoride-etherate induced rearrangement of bicyclo[2.2.2]octenediones: An efficient synthesis of bicyclo[3.2.1]octenediones

Tetrahedron

Volumn 56, Issue 23, 2000, Pages 3735-3741

  Nair, Vijay ^a   Maliakal, Davis ^a   Treesa, P M ^a   Anilkumar, Gopinathan ^a   Vairamani, M ^b   Prabhakar, S ^b   Rath, Nigam P ^c  

^a REGIONAL RESEARCH LABORATORY CSIR   (India)

^b INDIAN INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

^c UNIVERSITY OF MISSOURI ST LOUIS   (United States)

Author keywords

Bicyclic aliphatic compounds; Diones; Rearrangements

Indexed keywords

ALKADIENE; BICYCLO COMPOUND; BORON DERIVATIVE; ETHER DERIVATIVE;

ARTICLE; CHEMICAL MODIFICATION; CHEMICAL REACTION; CONFORMATIONAL TRANSITION; CRYSTAL STRUCTURE; PRIORITY JOURNAL; REACTION ANALYSIS; SYNTHESIS;

EID: 0034595773     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(00)00275-1     Document Type: Article

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28. 3) of 15: δ 7.12-7.27 (m, 4H), 6.15 (d, J=2 Hz, 1H), 3.68-3.65 (m, 1H), 3.50-3.30 (dd, J=10.0, 6.1 Hz, 1H), 2.88-2.60 (m, 1H), 1.95-1.70 (m, 1H), 1.21 (s, 18H).