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Volumn 39, Issue 9, 2000, Pages 1669-1672

Reaction of organic selenocyanates with hydroxides: The one-pot synthesis of dialkyl diselenides from alkyl bromides

Author keywords

Cyanides; Diselenides; Selenium

Indexed keywords

BROMINE DERIVATIVE; CYANIC ACID DERIVATIVE; HYDROXIDE; SELENIDE; SELENIUM DERIVATIVE;

EID: 0034595326     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(20000502)39:9<1669::AID-ANIE1669>3.0.CO;2-6     Document Type: Article
Times cited : (74)

References (53)
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    • d) The Chemistry of Organic Selenium and Tellurium Compounds, Vol. 2 (Eds.: S. Patai, Z. Rappoport), Wiley, Chichester, 1987; A. Toshimitsu, S. Uemura in The Chemistry of Organic Selenium and Tellurium Compounds, Vol. 2 (Eds.: S. Patai, Z. Rappoport), Wiley, Chichester, 1987, pp. 541-590, chap. 14;
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    • b) J. Baker, W. G. Moffitt, J. Chem. Soc. 1930, 1722; P. L. N. Rao, J. Indian Chem. Soc. 1941, 18, 1;
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    • d) L. Hagelberg, Ber. Dtsch. Chem. Ges. 1890, 23, 1083; L. Pichat, M. Herbert, M. Thiers, Tetrahedron 1961, 12, 1;
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    • g) L.-B. Agenäs, Arkiv Kemi 1969, 31, 159; W. Jenny, Helv. Chim. Acta 1952, 35, 1429;
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    • g) L.-B. Agenäs, Arkiv Kemi 1969, 31, 159; W. Jenny, Helv. Chim. Acta 1952, 35, 1429;
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    • 1642608527 scopus 로고    scopus 로고
    • The reaction proceeds similarly if carried oui in DMF instead
    • The reaction proceeds similarly if carried oui in DMF instead.
  • 49
    • 1642639601 scopus 로고    scopus 로고
    • We have demonstrated that ethanol does not react with selenocyanates
    • We have demonstrated that ethanol does not react with selenocyanates.
  • 50
    • 1642624021 scopus 로고    scopus 로고
    • Merck Cyanid Test reference No. 1.10044-0001 (Merck. Darmstadt. Germany)
    • Merck Cyanid Test reference No. 1.10044-0001 (Merck. Darmstadt. Germany).
  • 51
    • 1642608528 scopus 로고    scopus 로고
    • note
    • The same reactions have been carried out with one equivalent of NaOH and also provide the corresponding diselenides.
  • 52
    • 1642639602 scopus 로고    scopus 로고
    • note
    • Similar or even better results are observed if these reactions are performed with cesium carbonate. This work will he described in a full paper.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.