Novel oxyfunctionalized phosphonite ligands for the hydroformylation of isomeric n-olefins

Angewandte Chemie - International Edition

Volumn 39, Issue 9, 2000, Pages 1639-1641

  Selent, Detlef ^a   Wiese, Klaus Diether ^b   Röttger, Dirk ^b   Börner, Armin ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

^b Industriepark Marl   (Germany)

Author keywords

Homogeneous catalysis; Hydroformylations; Isomerizations; Phosphonites; Rhodium

Indexed keywords

ALDEHYDE; ALKENE DERIVATIVE; LIGAND; PHOSPHONIC ACID DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL MODIFICATION; CHEMICAL STRUCTURE; ISOMERISM;

EID: 0034595318     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(20000502)39:9<1639::AID-ANIE1639>3.0.CO;2-C     Document Type: Article

References (22)

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13. As ligands in asymmetric hydrogenation: a) M. T. Reetz, A. Gosberg, R. Goddard, S.-H. Kyung, Chem. Commun. 1998, 2077-2078; b) D. Haag, J. Runsink, H.-D. Scharf, Organometallics, 1998, 17, 398-409; as ligands in hydroformylation; c) H. Urata, Y. Wada (Mitsubishi Chemical Corp.) WO-A 9843935, 1998 [Chem. Abstr. 1998, 129, 289879b].
14. As ligands in asymmetric hydrogenation: a) M. T. Reetz, A. Gosberg, R. Goddard, S.-H. Kyung, Chem. Commun. 1998, 2077-2078; b) D. Haag, J. Runsink, H.-D. Scharf, Organometallics, 1998, 17, 398-409; as ligands in hydroformylation; c) H. Urata, Y. Wada (Mitsubishi Chemical Corp.) WO-A 9843935, 1998 [Chem. Abstr. 1998, 129, 289879b].
15. As ligands in asymmetric hydrogenation: a) M. T. Reetz, A. Gosberg, R. Goddard, S.-H. Kyung, Chem. Commun. 1998, 2077-2078; b) D. Haag, J. Runsink, H.-D. Scharf, Organometallics, 1998, 17, 398-409; as ligands in hydroformylation; c) H. Urata, Y. Wada (Mitsubishi Chemical Corp.) WO-A 9843935, 1998 [Chem. Abstr. 1998, 129, 289879b].
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17. All new compounds were comprehensively characterized. Experimental details are described in the Supporting Information.
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22. The phosphonites 6-(2-tert-butyl-4-methoxyphenyl)dibenz[c,e]-1,2-oxaphosphorine and di(2,4-di-tert-butylphenyl)phenylphosphonite derived from simple phenols gave n-selectivities of 37.1 and 32.3%, respectively, under the conditions described in Table 4 and with a Rh:P ratio of 1:10.