Hydrogenation of silyl-substituted alkynes using diimide: Application to the synthesis of saturated sila-macrocycles

Chemistry Letters

Volumn , Issue 12, 2000, Pages 1416-1417

  Kwon, Eunsang ^a   Sakamoto, Kenkichi ^a   Kabuto, Chizuko ^a   Kira, Mitsuo ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0034560185     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2000.1416     Document Type: Article

References (14)

1. For a recent review, see: D. J. Pasto and R. T. Taylor, Org. React., 40, 91 (1991).
2. R. S. Dewey and E. E. von Tamelene, J. Am. Chem. Soc., 83, 3729 (1961); T. N. Mitchell and B. Kowall, J. Organomet. Chem., 481, 137 (1994).
3. R. S. Dewey and E. E. von Tamelene, J. Am. Chem. Soc., 83, 3729 (1961); T. N. Mitchell and B. Kowall, J. Organomet. Chem., 481, 137 (1994).
4. 3, Pd/C, Pt/C, etc.) was unsuccessful.
5. N. V. Komarov and O. G. Yarosh, Zh. Obshch. Khim., 37, 264 (1967).
6. T. Matsuo, K. Uchida, and A. Sekiguchi, Chem. Commun., 1999, 1799.
7. 4: 310.1425. Found: 310.1421.
8. Yu. E. Ovchinnikov, V. E. Shklover, Yu. T. Struchkov, Yu. P. Polyakov, and L. E. Guselnikov, Makromol. Chem., 187, 2011 (1986).
9. 6: C, 79.94; H, 6.71%; Found: C, 79.72; H, 6.72%.
10. R. Bortolin, B. Parbhoo, and S. S. D. Brown, J. Chem. Soc., Chem. Commun., 1988, 1079; M. Unno, T. Saito, and H. Matsumoto, Chem. Lett., 1999, 1235.
11. R. Bortolin, B. Parbhoo, and S. S. D. Brown, J. Chem. Soc., Chem. Commun., 1988, 1079; M. Unno, T. Saito, and H. Matsumoto, Chem. Lett., 1999, 1235.
12. w = 0.074) for 4329 independent reflections [I > 5.00σ(I)].
13. Compound 12 was obtained previously by the hydrosilylation of diphenylbis(2-diphenylsilylethyl)silane with diphenylbis[2-diphenyl-(vinyl)silylethyl]silane under highly dilute conditions in 1.8% yield; M. Ichinohe, Y. Hayashi, and M. Kira, 73th Annual Meeting of the Chemical Society of Japan, Morioka, September 1997, Abstr., No. 3D801.
14. 6: 564.0302. Found: 564.0325.