Synthesis and X-ray analysis of Mn-Mo mixed metal oxide cluster with cubic framework

Chemistry Letters

Volumn , Issue 11, 2000, Pages 1342-1343

  Nishikawa, Koji ^a   Kinoshita, Isamu ^a   Nishioka, Takanori ^a   Isobe, Kiyoshi ^a  

^a Osaka Prefecture University   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0034554197     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2000.1342     Document Type: Article

References (18)

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11. When the synthetic reaction was carried out under an argon atmosphere, cluster 1 was not formed: the aerobic conditions are required for the oxidation of Mn(III) to Mn(IV) to form 1.
12. -1).
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15. Reaction conditions: hydrogen peroxide (15 μmol), PC dye (15 μmol), and the catalyst (1.5 μmol) in water (10 mL) at 25 °C.
16. -1. (Formula Presented) ORTEP drawing of complex 2. All hydrogen atoms and crystalline water molecules were omitted for clarity. Selected bond distances (Å) and angles (deg): Rh1-O1: 2.029(3), Mo1-O1: 1.757(2), Mo1-O2: 1.732(3), O1-Rh1-O1': 88.9(1), O1-Rh1-N1: 93.4(1), O1-Rh1-N1': 91.9(1),O1-Rh1-N1": 177.7(1).
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