Solid state intercalation of 4,4'-bipyridine into the interlayer space of montmorillonites

Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

Volumn 341, Issue , 2000, Pages 351-356

  Khaorapapong, Nithima ^a   Kuroda, Kazuyuki ^a   Hashizume, Hideo ^b   Ogawa, Makoto ^a,c  

^a WASEDA UNIVERSITY   (Japan)

^b NATIONAL INSTITUTE FOR MATERIALS SCIENCE   (Japan)

^c JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

4,4 bipyridine; Intercalation; Montmorillonite; Solid solid reaction

Indexed keywords

COMPLEXATION; INFRARED SPECTROSCOPY; INTERCALATION COMPOUNDS; ORGANOMETALLICS; THERMOANALYSIS; X RAY CRYSTALLOGRAPHY;

MONTMORILLONITES; SOLID STATE INTERCALATION;

CLAY MINERALS;

EID: 0034548602     PISSN: 1058725X     EISSN: None     Source Type: Journal    
DOI: 10.1080/10587250008026165     Document Type: Article

References (7)

1. B.K.G. Theng, "The Chemistry of Clay-Organic Reactions", Adam Hilger, London (1974).
2. M. Ogawa and K. Kuroda, Chem. Rev., 95, 399 (1995).
3. M. Ogawa, T. Hashizume, K. Kuroda and C. Kato, Inorg. Chem., 30, 584 (1991).
4. See for example, R.V. Slone, J.T. Hupp, C.L. Stern and T.E. Albrecht-Schmitt, Inorg. Chem., 35, 4096 (1996).
5. See detailed experimental set up, H. Hashizume, S. Shimomura, H. Yamada, T. Fujita and H. Nakazawa, Powder Diffraction, 11, 288 (1996).
6. The polarizing power is defined as Z/R, where Z and R denote charge and ionic radius of interlayer cation, respectively, and it has a direct relation to the strength of the electrostatic field around the cations.
7. H. Gudbjartson, K. Biradha, K. Poirier and M.J. Zaworotko, J. Am. Chem. Soc., 121, 2599 (1999).