Evaluation of equilibria with a use of artificial neural networks (ANN): I. Artificial neural networks and experimental design as a tool in electrochemical data evaluation for fully inert metal complexes

Electroanalysis

Volumn 12, Issue 18, 2000, Pages 1481-1492

  Cukrowski, Ignacy ^b   Havel, Josef ^a  

^a MASARYK UNIVERSITY   (Czech Republic)

^b UNIVERSITY OF THE WITWATERSRAND   (South Africa)

Author keywords

Artificial neural networks; Experimental design; Ion selective electrodes; Metal complexes; Metal ligand equilibria; Polarography; Stability constants

Indexed keywords

ERRORS; HYDROLYSIS; IONIC STRENGTH; LIGANDS; METAL IONS; NEURAL NETWORKS; POLAROGRAPHIC ANALYSIS; STABILITY; STATISTICS;

DATA EVALUATION; ELECTROCHEMICAL DATA; EQUILIBRIUM STUDY; INERT METALS; ION-SELECTIVE ELECTRODE; METAL LIGAND SYSTEMS; METAL LIGANDS; METAL-LIGAND EQUILIBRIUM; METALS IONS; STABILITY CONSTANTS; METAL-LIGAND EQUILIBRIAY;

METAL COMPLEXES;

LIGAND; METAL COMPLEX; METAL ION;

ARTIFICIAL NEURAL NETWORK; COMPLEX FORMATION; ELECTROCHEMICAL ANALYSIS; HYDROLYSIS; IONIC STRENGTH; METHODOLOGY; POLAROGRAPHY; REVIEW;

EID: 0034526780     PISSN: 10400397     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-4109(200012)12:18<1481::AID-ELAN1481>3.0.CO;2-4     Document Type: Article

References (15)

1. A.E. Martell, R.D. Hancock, in Metal Complexes in Aqueous Solutions, Modern Inorganic Chemistry Series (Ed: J.P. Fackler, Jr.) Plenum Press, New York 1996.
2. M. Meloun, J. Havel, E. Högfeldt, in Computation of Solution Equilibria, Ellis Horword, Chichester 1985.
3. Computational Methods for the Determination of Formation Constants, (Ed: D.J. Leggett), Plenum Press, New York 1985.
4. I. Cukrowski, Anal. Chim. Acta 1996, 336, 23.
5. I. Cukrowski, Electroanalysis 1997, 9, 1167.
6. I. Cukrowski, S. Loader, Electroanalysis 1998, 10, 877.
7. G. Schwarzenbach, H. Ackermann, Helv. Chim. Acta 1952, 35, 486.
8. G. Schwarzenbach, R. Gut, G. Anderegg, Helv. Chim. Acta 1954, 37, 937.
9. Schwarzenbach, R. Gut, Helv. Chim. Acta 1956, 37, 1589.
10. R. Crow, in Polarography of A Metal Complexes, Academic Press, London 1969, p. 64.
11. I. Cukrowski, R.C. Luckay, Anal. Chim. Acta 1998, 372, 323.
12. I. Cukrowski, Electroanalysis 1999, 11, 606.
13. M. Torres, J.M. Diaz-Cruz, C. Ariño, B.S. Grabarić, R. Tauler, M. Esteban, Anal. Chim. Acta 1998, 371, 23.
14. I. Cukrowski, J. Electroanal. Chem. 1999, 460, 197.
15. NIST Standard Reference Database 46, NIST Critically Selected Stability Constants of Metal Complexes Database, Version 3.0. Data collected and selected by R.M. Smith and A.E. Martell. US Department of Commerce, National Institute of Standards and Technology 1997.