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Volumn 33, Issue 26, 2000, Pages 9740-9746

Linear dynamics of end-functionalized polymer melts: linear chains, stars, and blends

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL RELAXATION; FUNCTIONAL POLYMERS; MOLECULAR STRUCTURE; MOLECULAR WEIGHT; POLYMER BLENDS; RHEOLOGY; VISCOELASTICITY;

EID: 0034514486     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma000741k     Document Type: Article
Times cited : (44)

References (37)
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    • note
    • It is also noted that concerning ZWl, the slow terminal relaxation, attributed to structural rearrangements of the self-organized hyperstar structures (ref 3) and detected Theologically only in ZW1-15, is strongly strain dependent; this suggests a rather delicate and easily disrupted structure, in harmony with earlier findings (ref 1b). However, these types of structures are also characterized by a remarkable thermal stability of the zwitterionic interactions (ref 3).
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    • The melts were obtained from the homogeneous solutions by slowly evaporating the solvent over the course of 3 days under vacuum at room temperature (25 °C)
    • The melts were obtained from the homogeneous solutions by slowly evaporating the solvent over the course of 3 days under vacuum at room temperature (25 °C).
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    • e is estimated to be around 2000 g/mol, which is very reasonable for polybutadiene
    • e is estimated to be around 2000 g/mol, which is very reasonable for polybutadiene.
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    • Such an idea is currently being considered theoretically, in treelike low functionality star polymers for different applications, resembling however the hyperbranched assemblies of ZW1 (McLeish, T. C. B., personal communication, 1999).
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    • Because of the high molecular weights, the linear chains were not appropriate for SAXS measurements in order to obtain direct structural information from the present ZW-L samples
    • Because of the high molecular weights, the linear chains were not appropriate for SAXS measurements in order to obtain direct structural information from the present ZW-L samples.
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    • note
    • g's (Table 1); because of the limited segmental data available, this was not possible for all samples investigated. However, the qualitative trends discussed in this work remain unchanged, as demonstrated for the cases where the segmental time is available (Table 3).
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.