A new method for determining oxygen solubility in molten carbonates and carbonate-chloride mixtures using the oxidation of UO2 to uranate reaction

Journal of Nuclear Materials

Volumn 282, Issue 2-3, 2000, Pages 152-158

  Volkovich, Vladimir A ^a,e   Griffiths, Trevor R ^b   Fray, Derek J ^c   Thied, Robert C ^d  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

^b UNIVERSITY OF LEEDS   (United Kingdom)

^c UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^d SELLAFIELD LTD   (United Kingdom)

^e URAL FEDERAL UNIVERSITY   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

CARBONATES; CERAMIC MATERIALS; CHLORINE COMPOUNDS; DISSOLUTION; MOLTEN MATERIALS; OXIDATION; OXYGEN; PARTIAL PRESSURE; PEROXIDES; SOLUBILITY; URANIUM DIOXIDE;

CHLORIDES; URANATE;

NUCLEAR FUELS;

EID: 0034508152     PISSN: 00223115     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-3115(00)00427-X     Document Type: Article

References (28)

1. V.A. Volkovich, T.R. Griffiths, D.J. Fray, M. Fields, P.D. Wilson, J. Chem. Soc. Faraday Trans. 92 (1996) 5059.
2. V.A. Volkovich, T.R. Griffiths, D.J. Fray, M. Fields, J. Chem. Soc. Faraday Trans. 93 (1997) 3819.
3. V.A. Volkovich, T.R. Griffiths, D.J. Fray, M. Fields, J. Nucl. Mater. 256(1998) 131.
4. V.A. Volkovich, T.R. Griffiths, D.J. Fray, M. Fields, R.C. Thied, J. Chem. Soc. Faraday Trans. 94 (1998) 2623.
5. V.A. Volkovich, T.R. Griffiths, D.J. Fray, R.C. Thied, Phys. Chem. Chem. Phys. 1 (1999) 3297.
6. V.A. Volkovich, T.R. Griffiths, D.J. Fray, R.C. Thied, Phys. Chem. Chem. Phys. 2 (2000) 3029.
7. A.I. Kryukova, O.V. Pechenevskaya, O.V. Skiba, Radiokhomiya 32(1990) 105.
8. A.J. Appleby, C. Van Drunen, J. Electrochem. Soc. 127 (1980) 1655.
9. M. Cassir, G. Moutiers, J. Devynck, J. Electrochem. Soc. 140(1993) 3114.
10. T. Nishina, Y. Masuda, I. Uchida, in: M.-L. Saboungi, H. Kojima, J. Duruz, D. Shores (Eds.), Molten Salts Chemistry and Technology, The Electrochemical Society Proceedings Series 93-9, Pennington, NJ, 1993, p. 424.
11. M. Schenke, G.H.J. Broers, J.A.A. Ketelaar, J. Electro-chem. Soc. 113 (1966)404.
12. S.W. Smith, W.M. Vogel, S. Kasperin, J. Electrochem. Soc. 129 (1982) 1668.
13. W.M. Vogel, S.W. Smith, L.J. Bregoli, J. Electrochem. Soc. 130(1983) 574.
14. P. Tomczyk, G. Mordarski, J. Electroanal. Chem. 304 (1991)85.
15. P. TomczykL, K. Bienoasz, J. Electroanal. Chem. 304 (1991) 111.
16. G. Mordarski, J. Electroanal. Chem. 304 (1991) 123.
17. G. Moutierss, M. Cassir, C. Piolet, J. Devynek, Electrochim. Acta 36(1991) 1063.
18. B.B. Dave, R.E. White, A.J. Appleby, in: C.L. Hussey, S.N. Flengas, J.S. Wilkes, Y. Ito (Eds.), Molten Salts, The Electrochemical Society Proceedings Series 90-17, Pennington, NJ, 1990, p. 726.
19. K. Yamada, T. Nishina, I. Uchida, Electrochim. Acta 40 (1995) 1927.
20. H.C. Maru, in: R.J. Gale, D.G. Lovering (Eds.), Molten Salt Techniques, vol. 2, Plenum, New York, 1984, p. 24.
21. G.J. Janz, Molten Salts Handbook, Academic Press, NewYork, 1967.
22. H.-D. Jakubke, H. Jeschkeit (Eds.), Concise Encyclopaedia Chemistry, Walter de Gruyter, Berlin, 1994, p. 486.
23. G.J. Janz, R.P.T. Tomkins, J. Phys. Chem. Ref. Data 9 (1980)831.
24. N.S. Novoshinskaya, I.P. Vyrodov, V.K. Yunoshev, Zh. Prikl. Khim. 49 (1976) 1190.
25. N.S. Novoshinskaya, I.P. Vyrodov, V.K. Yunoshev, Tr. Krasnodar. Politekh. Inst. 63 (1974) 71.
26. R.W. Reeve, A.C.C. Tseung, J. Electroanal. Chem. 403 (1996) 69.
27. P. Claes (Catholic University of Louvian), personal communications.
28. 3 eutectic mixture at 973 K', presented at the Christmas Meeting of the Molten Salts Discussion Group, London, 1996.