Intramolecular vibrational redistribution in aromatic molecules. I. Eigenstate resolved CH stretch first overtone spectra of benzene

Journal of Chemical Physics

Volumn 113, Issue 23, 2000, Pages 10583-10596

  Callegari, A ^a,b   Merker, U ^a,c   Engels, P ^a,c,d   Srivastava, H K ^a   Lehmann, K K ^a   Scoles, G ^a  

^a PRINCETON UNIVERSITY   (United States)

^b EPFL   (Switzerland)

^c INSTITUT FÜR ANGEWANDTE PHYSIK   (Germany)

^d INSTITUT FÜR QUANTENOPTIK   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EIGENVALUES AND EIGENFUNCTIONS; GAS LASERS; INFRARED SPECTROSCOPY; MOLECULES; SPECTRUM ANALYSIS;

INFRARED-INFRARED DOUBLE RESONANCE SPECTROSCOPY;

BENZENE;

EID: 0034508073     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1319875     Document Type: Article

References (89)

1. N. B. Slater, Theory of Unimolecular Reactions (Cornell University Press, Ithaca, NY, 1959).
2. R. A. Marcus and O. K. Rice, J. Phys. Colloid Chem. 55, 894 (1951).
3. R. A. Marcus and O. K. Rice, J. Chem. Phys. 20, 359 (1952).
4. H. M. Rosenstock, M. B. Wallenstein, A. L. Wahrhaftig, and H. Eyring, Proc. Natl. Acad. Sci. U.S.A. 38, 667 (1952).
5. T. Baer and W. L. Hase, Unimolecular Reaction Dynamics (Oxford University Press, New York, 1996).
6. K. A. Holbrook, M. J. Pilling, and S. H. Robertson, Unimolecular Reactions, 2nd ed. (Wiley, Chichester, 1996).
7. E. J. Heller, J. Chem. Phys. 92, 1718 (1990).
8. A. M. de Souza, D. Kaur and D. S. Perry, J. Chem. Phys. 88, 4569 (1988).
9. G. A. Bethardy and D. S. Perry, J. Chem. Phys. 98, 6651 (1993).
10. K. von Puttkamer, H.-R. Dübal, and M. Quack, Faraday Discuss. Chem. Soc. 75, 197 (1983).
11. Quack, Annu. Rev. Phys. Chem. X, 839 (1990).
12. M. Quack and J. Stohner, J. Phys. Chem. 97, 12 574 (1993).
13. K. K. Lehmann, B. H. Pate, and G. Scoles, J. Chem. Phys. 93, 2152 (1990).
14. K. K. Lehmann, B. H. Pate, and G. Scoles, in Mode Selective Chemistry, edited by J. Jortner et al. (Kluwer Academic, Dordrecht, 1991), pp. 17-23.
15. E. R. T. Kerstel, K. K. Lehmann, T. F. Mentel, B. H. Pate, and G. Scoles, J. Phys. Chem. 95, 8282 (1991).
16. J. E. Gambogi, K. K. Lehmann, B. H. Pate, G. Scoles, and X. Yang, J. Chem. Phys. 98, 1748 (1993).
17. A. A. Stuchebrukhov and R. A. Marcus, J. Chem. Phys. 98, 6044 (1993).
18. M. Bixon and J. Jortner, J. Chem. Phys. 48, 715 (1968).
19. K. G. Kay, J. Chem. Phys. 64, 2112 (1976).
20. K. G. Kay, J. Chem. Phys. 61, 5205 (1974).
21. F. J. Dyson, J. Math. Phys. 3, 140 (1962).
22. E. W.-G. Diau, J. L. Herek, Z. H. Kim, and A. H. Zewail, Science 279, 847 (1998).
23. M. Gruebele and R. Bigwood, Int. Rev. Phys. Chem. 17, 91 (1998).
24. J. Segall, R. N. Zare, H. R. Dübal, M. Lewerenz, and M. Quack, J. Chem. Phys. 86, 634 (1987).
25. L. Lubich, O. V. Boyarkin, R. D. F. Settle, D. S. Perry, and T. R. Rizzo, Faraday Discuss. 102, 167 (1995).
26. O. V. Boyarkin and T. R. Rizzo, J. Chem. Phys. 105, 6285 (1996).
27. D. J. Nesbitt and R. W. Field, J. Phys. Chem. 100, 12 735 (1996).
28. K. K. Lehmann and G. Scoles, Annu. Rev. Phys. Chem. 45, 241 (1994).
29. T. Uzer, Phys. Rep. 199, 73 (1991).
30. T. Guhr, A. Müller-Groeling, and H. A. Weidenmüller, Phys. Rep. 299, 189 (1998).
31. K. F. Freed, Faraday Discuss, Chem. Soc. 67, 231 (1979).
32. K. F. Freed and A. Nitzan, J. Chem. Phys. 73, 4765 (1980).
33. C. Iung and R. E. Wyatt, J. Chem. Phys. 99, 2261 (1993).
34. T. J. Minehardt and R. E. Wyatt, Chem. Phys. Lett. 295, 373 (1998); 312, 485 (1999).
35. T. J. Minehardt and R. E. Wyatt, Chem. Phys. Lett. 295, 373 (1998); 312, 485 (1999).
36. T. J. Minehardt and R. E. Wyatt, J. Chem. Phys. 109, 8330 (1998).
37. T. J. Minehardt, J. D. Adcock, and R. E. Wyatt, Chem. Phys. Lett. 303, 537 (1999).
38. T. J. Minehardt, J. D. Adcock, and R. E. Wyatt, J. Chem. Phys. 110, 3326 (1999).
39. T. J. Minehardt, J. D. Adcock, R. E. Wyatt, and C. Iung, Chem. Phys. Lett. 303, 347 (1999).
40. S. Rashev, M. Stamova, and L. Kancheva, J. Chem. Phys. 109, 585 (1998).
41. E. L. Sibert III, W. P. Reinhardt, and J. T. Hynes, J. Chem. Phys. 81, 1115 (1984).
42. R. E. Wyatt, C. Iung, and C. Leforestier, J. Chem. Phys. 97, 3477 (1992).
43. R. E. Wyatt and C. Iung, J. Chem. Phys. 98, 5191 (1993).
44. R. E. Wyatt and C. Iung, J. Chem. Phys. 98, 3577 (1993).
45. R. E. Wyatt and C. Iung, J. Chem. Phys. 98, 6758 (1993).
46. R. E. Wyatt, J. Chem. Phys. 109, 10 732 (1998).
47. Y. Zhang and R. A. Marcus, J. Chem. Phys. 97, 5283 (1992).
48. Y. Zhang and R. A. Marcus, J. Chem. Phys. 96, 6065 (1992).
49. M. Quack, in Mode Selective Chemistry, edited by J. Jortner et al. (Kluwer Academic Publisher, Dordrecht, 1991), pp. 47-65.
50. P. Esherick, A. Owywong, and J. Pliva, J. Chem. Phys. 83, 3311 (1985).
51. J. Pliva and A. S. Pine, J. Mol. Spectrosc. 126, 82 (1987).
52. H. Hollenstein, S. Piccirillo, M. Quack, and M. Snels, Mol. Phys. 71, 759 (1990).
53. J. Domenech, M.-L. Junttila, and A. S. Pine, J. Mol. Spectrosc. 149, 391 (1991).
54. M. L. Junttila, J. L. Domenech, G. T. Fraser, and A. S. Pine, J. Mol. Spectrosc. 147, 513 (1991).
55. M. Snels, A. Beil, H. Hollenstein, and M. Quack, Chem. Phys. 225, 107 (1997).
56. R. G. Bray and M. J. Berry, J. Chem. Phys. 71, 4909 (1979).
57. S. Shi and W. H. Miller, Theor. Chim. Acta 68, 1 (1989).
58. K. V. Reddy, D. F. Heller, and M. J. Berry, J. Chem. Phys. 76, 2814 (1982).
59. L. Halonen, Chem. Phys. Lett. 87, 221 (1982).
60. R. H. Page, Y. R. Shen, and Y. T. Lee, J. Chem. Phys. 88, 4621 (1988).
61. R. H. Page, Y. R. Shen, and Y. T. Lee, J. Chem. Phys. 88, 5362 (1988).
62. M. Scotoni, A. Boschetti, N. Oberhofer, and D. Bassi, J. Chem. Phys. 94, 971 (1991).
63. F. Iachello and S. Oss, J. Mol. Spectrosc. 153, 225 (1992).
64. J. A. Nicholson and W. D. Lawrance, Chem. Phys. Lett. 236, 336 (1995).
65. A. Callegari, H. K. Srivastava, U. Merker, K. K. Lehmann, G. Scoles, and M. Davis, J. Chem. Phys. 106, 432 (1997).
66. S. Rashev, M. Stamova, and S. Djambova, J. Chem. Phys. 108, 4797 (1998).
67. P. Pulay, G. Fogarasi, and J. E. Boggs, J. Chem. Phys. 74, 3999 (1981).
68. L. Goodman, A. G. Ozkabak, and S. N. Thakur, J. Phys. Chem. 95, 9044 (1991).
69. C. J. O'Brien, "Improvement to an infrared laser-molecular beam spectrometer for IVR studies," Senior thesis, Princeton University, 1994.
70. J. E. Gambogi, M. Becucci, C. J. O'Brien, K. K. Lehmann, and G. Scoles, Ber. Bunsenges. Phys. Chem. 99, 548 (1995).
71. K. Chen and E. S. Yeung, J. Chem. Phys. 69, 43 (1978).
72. G. Herzberg, Molecular Spectra and Molecular Structure (Van Nostrand, New York, 1945), Vol. II. Infrared and Raman spectra of polyatomic molecules.
73. D. Romanini and K. K. Lehmann, J. Chem. Phys. 98, 6437 (1993).
74. B. Pate, K. Lehmann, and G. Scoles, J. Chem. Phys. 95, 3891 (1991).
75. M. Quack, J. Chem. Phys. 82, 3277 (1985).
76. W. Lawrence and A. Knight, J. Phys. Chem. 89, 917 (1985).
77. E. J. Heller and R. L. Sundberg, in Chaotic Behavior in Quantum Systems, Vol. 120 of NATO ASI, edited by G. Casati (Plenum, Como, Italy, 1985), pp. 255-292.
78. F. J. Dyson and M. L. Mehta, J. Math. Phys. 4, 701 (1963).
79. K. K. Lehmann and S. L. Coy, J. Chem. Phys. 87, 5415 (1987).
80. P. E. Bevington and D. K. Robinson, Data Reduction and Error Analysis for the Physical Sciences, 2nd ed. (McGraw-Hill, New York, 1992).
81. S. Brandt, Statistical and Computational Methods in Data Analysis (North-Holland, Amsterdam, 1970).
82. M. Robnik, Prog. Theor. Phys. Suppl. 116, 331 (1994).
83. K. K. Lehmann and S. L. Coy, Ber. Bunsenges. Phys. Chem. 92, 306 (1988).
84. T. Oka, J. Chem. Phys. 47, 5410 (1967).
85. C. S. Parmenter, Faraday Discuss. Chem. Soc. 75, 7 (1983).
86. D. Madsen, R. Pearman, and M. Gruebele, J. Chem. Phys. 106, 5874 (1997).
87. R. Pearman and M. Gruebele, J. Chem. Phys. 108, 6561 (1998).
88. M. Quack, in Femtosecond Chemistry, edited by J. Manz and L. Wöste (Verlag Chemie, Weinheim, 1994), pp. 781-818.
89. S. Mukamel, J. Sue, and A. Pandey, Chem. Phys. Lett. 105, 134 (1984).