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0342311418
-
-
note
-
If the MAO used contains an estimated 10% of TMA, about 2 mmol of TMA is present in the reaction mixture. After 30 min, an estimated 0.8 mmol of isopropyl-terminated chains has been produced, such that almost half of the initially present TMA has been consumed and the probability of polymeryl exchange with a Me-Al unit is accordingly diminished.
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0342746316
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note
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23
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0032186998
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0342311415
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note
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3 ([Al]:[Zr] 20:1).
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32
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0343616316
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Reinmuth, A. Dissertation Universität Konstanz, 1992; p 115
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Al-mediated polymeryl transfer between the R and S isomers of a racemic zirconocene catalyst is expected to enhance the formation of stereoerrors of the mmrm type compared to a reaction system containing only one of the catalyst enantiomers. Experimental results in this regard are controversial: Reinmuth, A. Dissertation Universität Konstanz, 1992; p 115. Song, W.; Yu, Z.; Chien, J. C. W. J. Organomet. Chem. 1996, 572, 131. Song, W.; Chien, J. C. W. J. Organomet. Chem. 1998, 558, 223. Busico, V.; Brita, D.; Caporaso, L.; Cipullo, R.; Vacatello, M. Macromolecules 1997, 30, 3971. Busico, V.; Cipullo, R. J. Organomet. Chem. 1998, 558, 219.
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33
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0030593209
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Al-mediated polymeryl transfer between the R and S isomers of a racemic zirconocene catalyst is expected to enhance the formation of stereoerrors of the mmrm type compared to a reaction system containing only one of the catalyst enantiomers. Experimental results in this regard are controversial: Reinmuth, A. Dissertation Universität Konstanz, 1992; p 115. Song, W.; Yu, Z.; Chien, J. C. W. J. Organomet. Chem. 1996, 572, 131. Song, W.; Chien, J. C. W. J. Organomet. Chem. 1998, 558, 223. Busico, V.; Brita, D.; Caporaso, L.; Cipullo, R.; Vacatello, M. Macromolecules 1997, 30, 3971. Busico, V.; Cipullo, R. J. Organomet. Chem. 1998, 558, 219.
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Song, W.1
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0342311413
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Al-mediated polymeryl transfer between the R and S isomers of a racemic zirconocene catalyst is expected to enhance the formation of stereoerrors of the mmrm type compared to a reaction system containing only one of the catalyst enantiomers. Experimental results in this regard are controversial: Reinmuth, A. Dissertation Universität Konstanz, 1992; p 115. Song, W.; Yu, Z.; Chien, J. C. W. J. Organomet. Chem. 1996, 572, 131. Song, W.; Chien, J. C. W. J. Organomet. Chem. 1998, 558, 223. Busico, V.; Brita, D.; Caporaso, L.; Cipullo, R.; Vacatello, M. Macromolecules 1997, 30, 3971. Busico, V.; Cipullo, R. J. Organomet. Chem. 1998, 558, 219.
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0031190605
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Al-mediated polymeryl transfer between the R and S isomers of a racemic zirconocene catalyst is expected to enhance the formation of stereoerrors of the mmrm type compared to a reaction system containing only one of the catalyst enantiomers. Experimental results in this regard are controversial: Reinmuth, A. Dissertation Universität Konstanz, 1992; p 115. Song, W.; Yu, Z.; Chien, J. C. W. J. Organomet. Chem. 1996, 572, 131. Song, W.; Chien, J. C. W. J. Organomet. Chem. 1998, 558, 223. Busico, V.; Brita, D.; Caporaso, L.; Cipullo, R.; Vacatello, M. Macromolecules 1997, 30, 3971. Busico, V.; Cipullo, R. J. Organomet. Chem. 1998, 558, 219.
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Busico, V.1
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Vacatello, M.5
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36
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0342311408
-
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Al-mediated polymeryl transfer between the R and S isomers of a racemic zirconocene catalyst is expected to enhance the formation of stereoerrors of the mmrm type compared to a reaction system containing only one of the catalyst enantiomers. Experimental results in this regard are controversial: Reinmuth, A. Dissertation Universität Konstanz, 1992; p 115. Song, W.; Yu, Z.; Chien, J. C. W. J. Organomet. Chem. 1996, 572, 131. Song, W.; Chien, J. C. W. J. Organomet. Chem. 1998, 558, 223. Busico, V.; Brita, D.; Caporaso, L.; Cipullo, R.; Vacatello, M. Macromolecules 1997, 30, 3971. Busico, V.; Cipullo, R. J. Organomet. Chem. 1998, 558, 219.
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Busico, V.1
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38
-
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0343616309
-
-
note
-
A small hexane-soluble fraction gave the same atactic pentad distribution as the ether fraction.
-
-
-
-
40
-
-
0342746307
-
-
note
-
The polymer products are slightly sticky powders of homogeneous appearance.
-
-
-
-
42
-
-
0342311407
-
-
note
-
With some effects being probably due also to increasing molar masses, cf. ref 22.
-
-
-
-
43
-
-
0343616307
-
-
note
-
2-supported rather than homogeneously dissolved metallocene catalysts, which might have different reactivities.
-
-
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-
44
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0343180975
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note
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2 did not show any transfer of the labeled methyl group between these complexes either.
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45
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0000163629
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In this respect, methyl-polymeryl exchange between Zr and Al differs from methyl-Cl exchange, which is strongly affected by differences in Zr electron deficiencies: Beck, S.; Brintzinger, H. H. Inorg. Chim. Acta 1998, 270, 376.
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(1998)
Inorg. Chim. Acta
, vol.270
, pp. 376
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Beck, S.1
Brintzinger, H.H.2
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46
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2142683225
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Similar observations were made in studies with different allyl-zirconocene complexes: Lieber, S.; Prosenc, M. H.; Brintzinger, H. H. Organometallics 2000, 19, 377.
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(2000)
Organometallics
, vol.19
, pp. 377
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Lieber, S.1
Prosenc, M.H.2
Brintzinger, H.H.3
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47
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0000121258
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Wiesenfeldt, H.; Reinmuth, A.; Barsties, E.; Evertz, K.; Brintzinger, H. H. J. Organomet. Chem. 1989, 369, 359.
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(1989)
J. Organomet. Chem.
, vol.369
, pp. 359
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Wiesenfeldt, H.1
Reinmuth, A.2
Barsties, E.3
Evertz, K.4
Brintzinger, H.H.5
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