Ultrafast electrochromic windows based on redox-chromophore modified nanostructured semiconducting and conducting films

Journal of Physical Chemistry B

Volumn 104, Issue 48, 2000, Pages 11449-11459

  Cummins, David ^a   Boschloo, Gerrit ^a   Ryan, Michael ^a   Corr, David ^a   Nagaraja Rao, S ^a   Fitzmaurice, Donald ^a  

^a UNIVERSITY COLLEGE DUBLIN   (Ireland)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMISORPTION; CHROMOPHORES; CONDUCTIVE FILMS; ELECTROCHROMISM; ELECTRODES; LITHIUM COMPOUNDS; MONOLAYERS; NANOSTRUCTURED MATERIALS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REDOX REACTIONS; SEMICONDUCTING ANTIMONY COMPOUNDS; TITANIUM DIOXIDE;

BISPHOSPHONOETHYL BIPYRIDINIUM DICHLORIDE; CONDUCTING GLASS; PHENOTHIAZYL PROPOXYPHOSPHONIC ACID; ULTRAFAST ELECTROCHROMIC WINDOWS;

SEMICONDUCTING FILMS;

EID: 0034499003     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp001763b     Document Type: Article

References (33)

1. (a) Lamport, C. Sol. Energy Mater. Solar Cells 1984, 11, 1.
2. (b) Large-Area Chromogenics: Materials and Devices for Transmittance Control; Lampert, C., Granqvist, C., Eds.; SPIE Optical Engineering Press: Washington, DC, 1990.
3. (c) Greenberg, C. Thin Solid Films 1994, 257, 81.
4. O'Regan, B.; Grützel, M. Nature 1991, 353, 737.
5. Hagfeldt, A.; Vlachopoulos, N.; Grützel, M. J. Electrochem. Soc. 1994, 14, L82.
6. Marguerettaz, X.; O'Neill, R.; Fitzmaurice, D. J. Am. Chem. Soc. 1994, 116, 2629.
7. (a) Cinnsealach, R.; Boschloo, G.; Rao, S. N.; Fitzmaurice, D. Sol. Energy Mater. Sol. Ceils 1998,55,215.
8. (b) Cinnsealach, R.; Boschloo, G.; Rao, S. N.; Fitzmaurice, D. Sol. Energy Mater. Sol. Cells 1999, 57, 107.
9. Fitzmaurice, D.; Rao, S. N.; Cinnseleach, R.; Enright, B. Eur. Pat. Appl. 98/9032735.
10. Cummins, D.; Boschloo, G.; Ryan, M.; Corr, D.; Rao, S. N.; Fitzmaurice, D. Science, paper submitted.
11. Fitzmaurice, D.; Rao, S. N.; Cummins, D.; Corr, D.; Boschloo, G. Irish Pat. Appl. 1999.
12. Boschloo, G.; Fitzmaurice, D. J. Phys. Cliem. B 1999, 103, 3093.
13. (a) Kölle, U.; Moser, J.; Grätzel, M. Inorg. Chem. 1985, 24, 2253.
14. (b) Frei, H.; Fitzmaurice, D.; Grätzel, M. Langmuir 1990,6, 198.
15. (c) Moser, J.; Punchihewa, S.; Infelta, P.; Grätzel, M. Langmuir 1991, 7, 3012.
16. (d) Redmond, G.; Fitzmaurice, D.; Grätzel, M. J. Phys. Chem. 1993,97,6951.
17. (e) Moser, J.; Grätzel, M. Chem. Phys. 1993, 176, 493.
18. (a) Péchy, P.; Rotzinger, F.; Nazeeruddin, M.; Kohle, O.; Zakeeruddin, M.; Humphry-Baker, R.; Grätzel, M. J. Chem. Soc., Chem. Commun. 1995, 65.
19. (b) Yan, S.; Hupp, J. J. Phys. Chem. 1996, 700, 6867.
20. (a) Hunig, S.; Berneth, H. Top. Girr. Chem. 1980, 92, 1.
21. (b) Bird, C.; Kühn, A.; Chem. Soc. Rev. 1981, 10, 49.
22. (a) Kok, B.; Rurainski, H.; Owens, O. Biochim. Biophys. Ada 1965, 709, 347.
23. (b) Trudinger, P. Anal. Biochem. 1970, 36, 222.
24. Wantanabe, T.; Honda, K. J. Phys. Chem. 1982, 56, 2617.
25. Siripala, W.; Tomkiewics. M. J. Eleclrochem. Soc. 1982, 729, 1240.
26. The extinction coefficient of this compound was determined using standard spectroelectrochemical techniques.
27. Boshcloo, G.; Fitzmaurice, D. J. Phys. Chem. B 1999, 103, 7860.
28. Boehlehn, R.; Felderhoff, M.; Michalek, R.; Walder, L. Chem. Lett. 1998, 8, 815.
29. Campus, F.; Bonhote, P.; Grätzel, M.; Heinen, S.; Walder. L. Sol. Energy Mater. Sol. Cells 1999, 56, 281.
30. Bonhote, P.; Walder, L.; Grätzel, M. Ear. Pat. EP0886804.
31. Grätzel, M. Private communication.
32. Enright, B.; Redmond, G.; Fitzmaurice, D. J. Phys. Chem. 1994, 98, 6195.
33. These reduction and oxidation potentials were measured in the electrolyte used to fill the assembled EC window under test.