Preparation of 2,5-diamino-3,6-dinitropyrazine (ANPZ-i): a novel candidate high energy insensitive explosive

Propellants, Explosives, Pyrotechnics

Volumn 25, Issue 6, 2000, Pages 302-306

  Philbin, Simon P ^a   Millar, Ross W ^a   Coombes, Robert G ^b  

^a WS3 Chemical Technology Department   (United Kingdom)

^b BRUNEL UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ISOMERS; MOLECULAR STRUCTURE; MOLECULES; NITRATION; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; SYNTHESIS (CHEMICAL);

HIGH ENERGY INSENSITIVE EXPLOSIVE; NITRONIUM TETRAFLUOROBORATE; SULPHOLANE;

EXPLOSIVES;

EID: 0034478783     PISSN: 07213115     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-4087(200012)25:6<302::AID-PREP302>3.0.CO;2-W     Document Type: Article

References (7)

1. For precursor syntheses see: G. W. H. Chesseman and R. A. Goodwin, J. Chem. Soc. C, 2974 (1971); Russian Patent SU1703645A1. For PZO preparation: P. Pagoria (personal communication to R. W. Millar).
2. K. W. Blake, A. E. A. Porter, and P. G. Sammes, J. Chem. Soc. Perkin Trans 1, 2494 (1972).
3. U. Groth, T. Huhn, B. Porsch, C. Schmeck, and U. Schollkopf, Liebigs Ann. Chem. 7, 715 (1993).
4. I. L. Yudin, A. B. Sheremetev, O. P. Shotov, and V. A. Tartovskii, Mendeleev Commun. 196 (1995).
5. R. W. Murray, R. Jeyaraman, and L. Mohan, Tetrahedron Lett. 27, 21, 2335 (1986).
6. N-oxides have been shown to give a characteristic orange/red colouration when added to aqueous ferric chloride solutions.
7. H. Meerwein, Org. Synth. 46, 113 (1966).