Insertion of terminal and internal acetylenes into the Zr-μ-methylene bond of the dinuclear cationic zirconium complex [{Zr(η5-C5H5)}2(μ-CH 2)(μ-Cl)(μ-η5-C5H 4-η5-C5H4)][BMe(C 6F5)3]

Organometallics

Volumn 19, Issue 26, 2000, Pages 5559-5567

  Royo, Eva ^a   Royo, Pascual ^a   Cuenca, Tomás ^a   Galakhov, Mikhail ^a  

^a UNIVERSITY OF ALCALÁ   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; COMPLEXATION; DERIVATIVES; HYDROGEN; INFRARED SPECTROSCOPY; ISOMERIZATION; MOLECULAR DYNAMICS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POSITIVE IONS; SOLUTIONS; STRUCTURE (COMPOSITION); THERMAL EFFECTS;

ALKYNES; DICHLOROMETHANE; DINUCLEAR CATIONIC ZIRCONIUM SPECIES; ELEMENTAL ANALYSIS; HYDROGEN MIGRATION; METHYLENE BONDS; MOLAR EQUIVALENT; SUPRAFACIAL MIGRATION;

ZIRCONIUM COMPOUNDS;

EID: 0034429286     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000664h     Document Type: Article

References (10)

1. (1)(a) Horton, A. D.; Orpen, A. G. Angew. Chem., Int. Ed. Engl. 1992, 31, 876.
2. (b) Bochmann, M.; Lancaster, S. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 1634.
3. (c) Yang, X.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1994, 116, 10015.
4. (d) Gómez, R.; Green, M. L. H.; Haggitt, J. L. J. Chem. Soc., Chem. Commun. 1994, 2607.
5. (e) Röttger, D.; Erker, G.; Fröhlich, R.; Grehl, M.; Silverio, S. J.; Hyla-Kryspin, I.; Gleiter, R. J. Am. Chem. Soc. 1995, 117, 10503.
6. (f) Tajden, E. B.; Swenson, D. L.; Jordan, R. F.; Petersen J. L. Organometallics 1995, 14, 371.
7. (g) Spaether, W.; Erker, G.; Rump, M.; Krüger, C.; Kuhnigk, J. Organometallics 1995, 14, 2621.
8. (h) Bochmann, M.; Lancaster, S. J.; Robinson, O. B. J. Chem. Soc., Chem. Commun. 1995, 2081.
9. Lancaster, S. J.; Robinson, O. B.; Bochmann, M.; Coles, S. J.; Hursthouse, M. B. Organometallics 1995, 14, 2456.
10. (j) Röttger, D.; Schmuck, S.; Erker, G. J. Organomet. Chem. 1996, 508, 263.