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0346948503
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note
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Compound 13 is available from Aldrich in an impure form. We found the procedure in ref. 11, followed by column chromatography, to work best for the preparation of 13.
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42
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0346948496
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note
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The application of the AB., principle to Scheme 7 requires the assumption that secondary alcohol substituents do not participate in the polymerization event.
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43
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85087227340
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note
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3 reaction, monomer conversion was estimated to be about 807, in GPC runs taken 1-2 h before the gel point.
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0343167396
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Emrick, T.; Chang, H.-T.; Fréchet, J. M. J. Macromolecules 1999, 32, 6380.
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Macromolecules
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Emrick, T.1
Chang, H.-T.2
Fréchet, J.M.J.3
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0348209119
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The characterization of materials with GPC-estimated molecular weights greater than about 25,000 was not feasible because of the onset of gelation
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The characterization of materials with GPC-estimated molecular weights greater than about 25,000 was not feasible because of the onset of gelation.
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46
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0347579294
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The recovery of the material lost in the fractionation step showed the presence of both diepoxide monomer and low molecular weight polymer and oligomers
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The recovery of the material lost in the fractionation step showed the presence of both diepoxide monomer and low molecular weight polymer and oligomers.
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47
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0347579296
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note
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This downfield trend in the chemical shift with increasing triol substitution is consistent with the chemical shifts of the methyl groups in 11, dialkylated 12, and trialkylated 13.
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50
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0346318537
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note
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A measured dn/dc of 0.96 was used for the molecular weight data processing. THF was used for both dn/dc and light scattering measurements.
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