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Two mechanisms are consistent with the observed broadening. Either an exchange process arising from the dynamic on - off ligation involving N3 leading to an average broad resonance or quadrupolar broadening effects due to changes in the electric field gradient at N3 as a consequence of metal ion co-ordination.
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53
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85037459518
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note
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Two mononuclear guanine complexes have been characterised to date both contain metal-carbon bonds and involve N7 protonation. A. Houlton, unpublished results.
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54
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85037473966
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note
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One example of an N3-co-ordinated guanine derivative has been isolated which will be described elsewhere, A. Houlton, unpublished results.
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