Solid-Gas Hydrogenation of Hex-3-yne and 1,4-Cyclohexadiene in the Presence of the Clusters Ru3(CO)12, H4Ru4(CO)12, H2Ru4(CO)13, and H2FeRu3(CO)13 Supported on Inorganic Materials. Infrared Evidence for Surface Organometallic Reactions

Journal of Cluster Science

Volumn 11, Issue 2, 2000, Pages 307-326

  Bonelli, Barbara ^a   Brait, Sabrina ^a   Deabate, Stefano ^a   Garrone, Edoardo ^a   Giordano, Roberto ^a   Sappa, Enrico ^a,b   Verre, Francesco ^a  

^a UNIVERSITY OF TURIN   (Italy)

^b UNIVERSITY OF EASTERN PIEDMONT   (Italy)

Author keywords

Heterogeneous hydrogenation catalysis; Inorganic oxides; Ruthenium carbonyl clusters; Solid gas reactions; Surface organometallic chemistry

Indexed keywords

EID: 0034372986     PISSN: 10407278     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1009041621528     Document Type: Article

References (32)

1. (a) R. Giordano and E. Sappa (1993). J. Organomet. Chem. 448, 157;
2. (b) D. Cauzzi, R. Giordano, E. Sappa, A. Tiripicchio, and M. Tiripicchio Camellini (1993). J. Cluster Sci. 4, 279;
3. (c) R. Giordano, E. Sappa, and S. A. R. Knox (1996). J. Cluster Sci. 7, 179;
4. (d) S. Deabate, R. Giordano, and E. Sappa (1997). J. Cluster Sci. 8, 407.
5. M. Castiglioni, R. Giordano, and E. Sappa (1995). J. Organomet. Chem. 491, 111.
6. See, e.g., (a) R. Giordano, E. Sappa, and G. Predieri, in L. J. Farrugia (ed.), The Synergy Between Dynamics and Reactivity at Clusters and Surfaces, Nato ASI Series C, No. 465 (Kluwer, Dordrecht, 1995). (b) M. Castiglioni, S. Deabate, E. Garrone, R. Giordano, E. Sappa, B. Onida, G. Predieri, and E. Sappa (1997). J. Cluster Sci. 8, 381.
7. See, e.g., (a) R. Giordano, E. Sappa, and G. Predieri, in L. J. Farrugia (ed.), The Synergy Between Dynamics and Reactivity at Clusters and Surfaces, Nato ASI Series C, No. 465 (Kluwer, Dordrecht, 1995). (b) M. Castiglioni, S. Deabate, E. Garrone, R. Giordano, E. Sappa, B. Onida, G. Predieri, and E. Sappa (1997). J. Cluster Sci. 8, 381.
8. See, e.g., (a) J.-M. Basset and A. Choplin (1983). J. Mol. Catal. 21, 95; (b) A. Choplin, B. Besson, L. D'Ornelas, R. Sanchez-Delgado, and J. M. Basset (1988). J. Am. Chem. Soc. 110, 2783, and references therein. For more recent examples see (c) D. Roberto, R. Psaro, and R. Ugo (1993). Organometallics 12, 2292; (d) E. Cariati, P. Recanati, D. Roberto, and R. Ugo (1998). Organometallics 17, 1266, and references therein.
9. See, e.g., (a) J.-M. Basset and A. Choplin (1983). J. Mol. Catal. 21, 95; (b) A. Choplin, B. Besson, L. D'Ornelas, R. Sanchez-Delgado, and J. M. Basset (1988). J. Am. Chem. Soc. 110, 2783, and references therein. For more recent examples see (c) D. Roberto, R. Psaro, and R. Ugo (1993). Organometallics 12, 2292; (d) E. Cariati, P. Recanati, D. Roberto, and R. Ugo (1998). Organometallics 17, 1266, and references therein.
10. See, e.g., (a) J.-M. Basset and A. Choplin (1983). J. Mol. Catal. 21, 95; (b) A. Choplin, B. Besson, L. D'Ornelas, R. Sanchez-Delgado, and J. M. Basset (1988). J. Am. Chem. Soc. 110, 2783, and references therein. For more recent examples see (c) D. Roberto, R. Psaro, and R. Ugo (1993). Organometallics 12, 2292; (d) E. Cariati, P. Recanati, D. Roberto, and R. Ugo (1998). Organometallics 17, 1266, and references therein.
11. See, e.g., (a) J.-M. Basset and A. Choplin (1983). J. Mol. Catal. 21, 95; (b) A. Choplin, B. Besson, L. D'Ornelas, R. Sanchez-Delgado, and J. M. Basset (1988). J. Am. Chem. Soc. 110, 2783, and references therein. For more recent examples see (c) D. Roberto, R. Psaro, and R. Ugo (1993). Organometallics 12, 2292; (d) E. Cariati, P. Recanati, D. Roberto, and R. Ugo (1998). Organometallics 17, 1266, and references therein.
12. (a) S. Aime, W. Dastrù, R. Gobetto, J. Krause, and E. Sappa (1995). Organometallics 14, 3224;
13. (b) D. Campagnola, M. Castiglioni, W. Dastrù, S. Deabate, R. Giordano, P. J. King, and E. Sappa (1997). Inorg. Chim. Acta 262, 157.
14. Finnigan Mat ITD Instrument (Dipartimento di Chimica Generale ed Organica Applicata, Universitá di Torino, Torino).
15. Servizio di Spettrometria di Massa (Dipartimento di Scienza e Technologia del Farmaco, Universitá di Torino, Torino).
16. M. Castiglioni, S. Deabate, E. Garrone, R. Giordano, B. Onida, G. Predieri, and E. Sappa (1997). J. Cluster Sci. 8, 381.
17. J. B. Keister and C. C. O Onyeso (1988). Organometallics 7, 2364.
18. (a) G. M. Zanderighi, C. Dossi, R. Ugo, R. Psaro, A. Theolier, A. Choplin, L. D'Ornelas, and J. M. Basset (1985). J. Organomet. Chem. 296, 127;
19. (b) J. Evans and G. S. McNulty (1984). J. Chem. Soc. Dalton Trans., 1123;
20. (c) N. Binsted, J. Evans, G. N. Greaves, and R. J. Price (1989). Organometallics 8, 613.
21. K. Tanabe, M. Misono, Y. Ono, and H. Hattori, in B. Delmon and J. T. Yates (eds.), New Solid Acids and Bases. Their Catalytic Properties, Studies in Surface Science and Catalysis, Vol. 51, (Elsevier, Tokyo, 1989).
22. 2).
23. See, e.g., (a) A. Choplin, L. Huang, A. Theolier, P. Gallezot, J. M. Basset, U. Siriwardane, S. G. Shore, and R. Mathieu (1986). J. Am. Chem. Soc. 108, 4224; (b) R. Psaro, R. Ugo, G. M. Zanderighi, B. Besson, A. K. Smith, and J. M. Basset (1981). J. Organomet. Chem. 213, 215.
24. See, e.g., (a) A. Choplin, L. Huang, A. Theolier, P. Gallezot, J. M. Basset, U. Siriwardane, S. G. Shore, and R. Mathieu (1986). J. Am. Chem. Soc. 108, 4224; (b) R. Psaro, R. Ugo, G. M. Zanderighi, B. Besson, A. K. Smith, and J. M. Basset (1981). J. Organomet. Chem. 213, 215.
25. See, e.g., (a) B. F. G. Johnson, R. D. Johnston, J. Lewis, B. H. Robinson, and G. Wilkinson (1968). J. Chem. Soc. (A) 2856;
26. (b) C. R. Eady, B. F. G. Johnson, and J. Lewis (1997). J. Chem. Soc. Dalton Trans. 477.
27. (a) O. Gambino, E. Sappa, and G. Cetini (1972). J. Organomet. Chem. 44, 185;
28. (b) D. Cauzzi, R. Giordano, E. Sappa, A. Tiripicchio, and M. Tiripicchio Camellini (1993). J. Cluster Sci. 4, 279.
29. K. Asaka, K.-K. Bando, and Y. Iwasawa (1990). J. Chem. Soc. Faraday Trans. 86, 2645.
30. A. Zecchina, E. Guglielminotti, A. Bossi, and M. Camia (1982). J. Catal. 74, 225, 240, 252.
31. S. Dobos, I. Borszomenyi, J. Mink, and L. Guczi (1986). Inorg. Chim. Acta 120, 135, 145.
32. V. L. Kuznetsov, A. T. Bell, and Y. I. Yermakov (1980). J. Catal. 65, 374.