The general expression of gas phase basicity of aliphatic amine, alcohol and ether

Chinese Journal of Organic Chemistry

Volumn 20, Issue 2, 2000, Pages 258-262

  Cao, Chen Zhong ^a  

^a Xiangtan Teacher's College   (China)

Author keywords

Alcohol; Amine; Ether; Polarizability effect index; Proton affinity energy

Indexed keywords

EID: 0034355387     PISSN: 02532786     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (13)

1. R L Martin and D A Shirley. The Relation of Core - Level Binding Energy Shifts to Proton Affinity and Lewis Basicity, J. Am. chem. Soc., 1974, 96 (17), 5299
2. B E Mills, R L Martin, D A and Shirley. Further Studies of the Core Binding Energy - Proton Affinity Correlation in Molecules, J. Am. Chem. Soc. , 1976, 98 (9), 2380
3. C Z Cao. Quantifying the Subsitituent Effect with Penetrating -Shielding Constant: Substituent Effect of Alkyl Group, Kexue Tongbau (in Chinese), 1992, 37 (24), 2239
4. D H Aue, H M Webb, and M T Bowers, Quantitative Proton Affinities, Ionization Potentials, and Hydrogen Alkylamines, J. Am. Chem. Soc., 1976, 98 (21), 311
5. J Gasteiger and M G Hutchings, Quantitative models of Gas -Phase Proton - Transfer Reactions Involving Alcohols, Ethers, and Their Thio Analogues. Correlation Analyses Based on Residual Electronegativity and Effective Polarizability, J. Am. Chem. Soc., 1984, 706 (22), 6489
6. C Z Cao, Relation between the Polarizability Effect Index and the Gas Phase Basicity of Fatty Amine, Alcohol and Ether. Chen. J. Org. Chem. ( Youji Huaxue ), 1995, 15 (6), 642 (in Chinese)
7. R W Taft and R D Topsom, The Nature and Analysis of Subsitituent Electronic Effects, Prog. Phys. Org. Chem., 1987, 16, 1
8. R D Topsom, Some Theoretical Studies of Electrionic Substituent Effects in Organic Chemistry, Prog. Phys. Org. Chem., 1987, 16, 125
9. F Mo, Z Wang and Y Jiang, CNDO/2 Calculation on Gas -phase Basicities of Amines, Alcohols and Ethers, Acta Chimica Sinica, 1983, 41 (4), 302 (in Chinese)
10. J M Abboud, J Elguero, D Liotard, M Essefar, M EI Mouhtadi and R W Taft, A Theoretical Study of the Proton Affinities of Water, Alcohols, and Ethers, Absolute versus Relative Basicities, J. Chem. Soc. Perkin Trans. 2, 1992, 565
11. C Z Cao. Study on the Polarizability Effect of Alkyl Substituent, Huaxue Tongbao, 1995, (10), 48 (in Chinese)
12. J Xu, G Xu and X Wang, The Orbital Energy in Neutral Atom, Huaxue Tongbao, 1986, (3), 46 (in Chinese)
13. S G Lias, J F Liebman and R D Levin, Evaluated Gas Phase Basicity and Proton Affinities of Molecules; Heats of Formation of Protonated Molecules, J. Phys. Chem. Ref., Data, 1984, 13 (3), 695