Structural transitions in methane+ethane gas hydrates - Part II: Modeling beyond incipient conditions

Chemical Engineering Science

Volumn 55, Issue 23, 2000, Pages 5773-5782

  Ballard, A L ^a   Sloan Jr , E D ^a  

^a Department of Geology and Geological Engineering   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AZEOTROPES; COMPOSITION EFFECTS; CRYSTAL STRUCTURE; ETHANE; MATHEMATICAL MODELS; METHANE; PHASE DIAGRAMS; PHASE EQUILIBRIA; PRESSURE EFFECTS; REGRESSION ANALYSIS; STATISTICAL MECHANICS; THERMAL EFFECTS;

PLATTEEUW MODEL; VAN DER WAALS MODEL;

GAS HYDRATES;

GAS HYDRATE;

EID: 0034353068     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-2509(00)00163-9     Document Type: Article

References (19)

1. Avlonitis, D. A. (1992). Thermodynamics of gas hydrate equilibria. Ph.D. thesis, Heriot-Watt University, Edinburgh, Scotland.
2. Ballard, A. L., & Sloan Jr., E. D. (2000). Optimizing thermodynamic parameters to match methane and ethane structural transition in natural gas hydrate equilibria. Proceedings of the third international conference on natural gas hydrates (pp. 702-13). New York: New York Academy of Sciences.
3. Bishnoi, P. R., Gupta, A. K., Englezos, P., & Kalogerakis, N. (1989). Multiphase equilibrium flash calculations for systems containing gas hydrates. Fluid Phase Equilibria, 53, 97-104.
4. Deaton, W. M., & Frost, E. M. (1946). Gas hydrates and their relationship to the operation of natural gas pipelines. U.S. Bureau of Mines Monograph 8.
5. Gupta, A. K. (1990). Steady state simulation of chemical processes. Ph.D. thesis, University of Calgary, Calgary, Canada.
6. Gupta, A. K., Bishnoi, P. R., & Kalogerakis, N. (1991). A method for the simultaneous phase equilibria and stability calculations for multi-phase reacting and non-reacting systems. Fluid Phase Equilibria, 63, 65-89.
7. Hendriks, E. M., Edmonds, B., Moorwood, R. A. S., & Szczepanski, R. (1996). Hydrate structure stability in simple and mixed hydrates. Fluid Phase Equilibria, 117, 193-200.
8. Holder, G. D., Corbin, G., & Papadopoulos, K. D. (1980). Thermodynamic and molecular properties of gas hydrates from mixtures containing methane, argon and krypton. Industrial and Engineering Chemistry Fundamentals, 19(3), 282.
9. Holder, G. D., & Grigoriou, G. C. (1980). Hydrate dissociation pressures of methane + ethane + water. Existence of a locus of minimum pressures. Journal of Chemical Thermodynamics, 12, 1093-1104.
10. Holder, G. D., & Hand, J. H. (1982). Multiple-phase equilibria in hydrates from methane, ethane, propane and water mixtures. A.I.Ch.E. Journal, 25(3), 440.
11. Krichevsky, I. R., & Kasarnovsky, J. S. (1935). Thermodynamical calculations of solubilities of nitrogen and hydrogen in water at high pressures. Journal of the American Chemical Society, 57, 2168.
12. Marshall, D. R., Saito, S., & Kobayashi, R. (1964). Hydrates at high pressure: Part I, methane-water, argon-water and nitrogen-water systems. A.I.Ch.E. Journal, 10(2), 202.
13. Menten, P. D., Parrish, W. R., & Sloan Jr., E. D. (1981). Effect of inhibitors on hydrate formation. Industrial and Engineering Chemical Process Design and Development, 20, 399.
14. Michelsen, M. L. (1994). Calculation of multiphase equilibrium. Computers in Chemical Engineering, 18(1), 545-550.
15. Parrish, W. R., & Prausnitz, J. M. (1972). Dissociation pressures of gas hydrates formed by gas mixtures. Industrial and Engineering Chemical Process Design and Development, 11(1), 26.
16. Soave, G. (1972). Equilibrium constants from a modified RedlichKwong equation of state. Chemical Engineering Science, 27(6), 1197.
17. Stackelberg, M. von., & Jahns, W. (1954). Feste gashydrate VI: Die gitteraufweitungsarbeit. Zeitschrift fuer Elektrochemie, 58, 162.
18. Subramanian, S., Kini, R., Dec, S. F., & Sloan Jr., E. D. (2000). Evidence of structure II hydrate formation from methane + ethane mixtures. Chemical Engineering Science, 55(11), 1981-1999.
19. van der Waals, J. H., & Platteeuw, J. C. (1959). Clathrate solutions. Advances in Physical Chemistry, 2, 1-57.