Reduction of molybdenum(V) chloride with various reducing metals: Reactivity correlations with the descendant Lewis acids

Chemistry Letters

Volumn , Issue 2, 2000, Pages 140-141

  Hara, Ryuichiro ^a   Guo, Qiaoxia ^a   Takahashi, Tamotsu ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0034347114     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2000.140     Document Type: Article

References (19)

1. The group 6 metal complexes whose charges on the metal centers are from -2 to +6 are widely covered, see "Comprehensive Organometallic Chemistry," ed by G. Wilkinson, F. G. A. Stone, E. W. Abel, Pergamon, Oxford (1982), Vol. 3, Chap. 27.1-27.2, pp. 1079-1253; "Comprehensive Organometallic Chemistry II," ed by E. W. Abel, F. G. A. Stone, G. Wilkinson, Pergamon, Oxford (1995), Vol. 5, Chap. 3-8, pp. 155-549; "Comprehensive Coordination Chemistry," ed by G. Wilkinson, R. D. Gillard, J. A. McCleverty, Pergamon, Oxford (1987), Vol. 3, Chap. 36.1-36.6, pp. 1229-1444.
2. The group 6 metal complexes whose charges on the metal centers are from -2 to +6 are widely covered, see "Comprehensive Organometallic Chemistry," ed by G. Wilkinson, F. G. A. Stone, E. W. Abel, Pergamon, Oxford (1982), Vol. 3, Chap. 27.1-27.2, pp. 1079-1253; "Comprehensive Organometallic Chemistry II," ed by E. W. Abel, F. G. A. Stone, G. Wilkinson, Pergamon, Oxford (1995), Vol. 5, Chap. 3-8, pp. 155-549; "Comprehensive Coordination Chemistry," ed by G. Wilkinson, R. D. Gillard, J. A. McCleverty, Pergamon, Oxford (1987), Vol. 3, Chap. 36.1-36.6, pp. 1229-1444.
3. The group 6 metal complexes whose charges on the metal centers are from -2 to +6 are widely covered, see "Comprehensive Organometallic Chemistry," ed by G. Wilkinson, F. G. A. Stone, E. W. Abel, Pergamon, Oxford (1982), Vol. 3, Chap. 27.1-27.2, pp. 1079-1253; "Comprehensive Organometallic Chemistry II," ed by E. W. Abel, F. G. A. Stone, G. Wilkinson, Pergamon, Oxford (1995), Vol. 5, Chap. 3-8, pp. 155-549; "Comprehensive Coordination Chemistry," ed by G. Wilkinson, R. D. Gillard, J. A. McCleverty, Pergamon, Oxford (1987), Vol. 3, Chap. 36.1-36.6, pp. 1229-1444.
4. For general reviews on cyclotrimerization reactions, see N. E. Schore, "[2+2+2] Cycloadditions," in "Comprehensive Organic Synthesis," ed by B. M. Trost, I. Fleming, Pergamon, Oxford (1991), Vol. 5, pp. 1129; D. B. Grotjahn, "Transition Metal Alkyne Complexes: Transition Metal-catalyzed Cyclotrimerization" in "Comprehensive Organometallic Chemistry II," ed by E. W. Abel, F. G. A. Stone, G. Wilkinson, Pergamon, Oxford (1995), Vol. 12, pp. 741.
5. For general reviews on cyclotrimerization reactions, see N. E. Schore, "[2+2+2] Cycloadditions," in "Comprehensive Organic Synthesis," ed by B. M. Trost, I. Fleming, Pergamon, Oxford (1991), Vol. 5, pp. 1129; D. B. Grotjahn, "Transition Metal Alkyne Complexes: Transition Metal-catalyzed Cyclotrimerization" in "Comprehensive Organometallic Chemistry II," ed by E. W. Abel, F. G. A. Stone, G. Wilkinson, Pergamon, Oxford (1995), Vol. 12, pp. 741.
6. Al, Sn, Zn: powder; In: small particles; Mg: turnings; Li: slices.
7. 2: -0.02, +0.09, +0.13, +0.03.
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11. S. A. R. Knox, R. F. D. Stansfield, F. G. A. Stone, M. J. Winter, and P. Woodward. J. Chem. Soc., Chem. Commun., 1978, 221; S. Slater and E. L. Muetterties, Inorg. Chem., 19, 3337 (1980); S. Slater and E. L. Muetterties, Inorg. Chem., 20, 946 (1981); M. Green, P. A. Kale, and R. J. Mercer, J. Chem. Soc., Chem. Commun., 1987, 375; M. J. Chetcuti, L. A. DeLiberato, P. E. Fanwick, and B. E. Grant, Inorg. Chem., 29, 1295 (1990).
12. S. A. R. Knox, R. F. D. Stansfield, F. G. A. Stone, M. J. Winter, and P. Woodward. J. Chem. Soc., Chem. Commun., 1978, 221; S. Slater and E. L. Muetterties, Inorg. Chem., 19, 3337 (1980); S. Slater and E. L. Muetterties, Inorg. Chem., 20, 946 (1981); M. Green, P. A. Kale, and R. J. Mercer, J. Chem. Soc., Chem. Commun., 1987, 375; M. J. Chetcuti, L. A. DeLiberato, P. E. Fanwick, and B. E. Grant, Inorg. Chem., 29, 1295 (1990).
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16. F. A. Cotton, J. L. Hubbard, D. L. Lichtenberger, and I. Shim, J. Am. Chem. Soc., 104, 679 (1982); P. A. Agaskar, F. A. Cotton, D. R. Derringer, G. L. Powell, D. R. Root, and T. J. Smith, Inorg. Chem., 24, 2786 (1985); F. L. Campbell, III, F. A. Cotton, and G. L. Powell, Inorg. Chem., 24, 4384 (1985); P. A. Agaskar and F. A. Cotton, Inorg. Chem., 25, 15 (1986).
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19. F. A. Cotton, J. L. Hubbard, D. L. Lichtenberger, and I. Shim, J. Am. Chem. Soc., 104, 679 (1982); P. A. Agaskar, F. A. Cotton, D. R. Derringer, G. L. Powell, D. R. Root, and T. J. Smith, Inorg. Chem., 24, 2786 (1985); F. L. Campbell, III, F. A. Cotton, and G. L. Powell, Inorg. Chem., 24, 4384 (1985); P. A. Agaskar and F. A. Cotton, Inorg. Chem., 25, 15 (1986).