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Volumn , Issue 4, 2000, Pages 368-369

Highly efficient generation of ammonium eneselenolates, their reactions and electronic properties

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EID: 0034341161     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2000.368     Document Type: Article
Times cited : (10)

References (19)
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    • S. Kato, T. Komuro, T. Kanda, H. Ishihara, and T. Murai, J. Am. Chem. Soc., 115, 3000 (1993); T. Murai, M. Fujii, and S. Kato, Chem. Lett., 1997, 545; T. Murai, H. Endo, M. Ozaki, and S. Kato, J. Org. Chem., 64, 2130 (1999).
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  • 10
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    • note
    • 2O as eluent to give the corresponding ketene selenothioacetals 3.
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    • ed by E. W. Abel, F. G. A. Stone, and G. Wilkinson, Pergamon, Oxford
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    • note
    • All new compounds gave satisfactory spectral and microanalytical data.
  • 13
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    • note
    • The high reactivity of the ammonium eneselenolate 2a toward alkyl halides is in sharp contrast to the reactivity of lithium eneselenolates generated from 1a and LDA. The methylation of lithium eneselenolates gave 3a only in low yields.
  • 14
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    • note
    • 8 (0.8 mL).


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